Method for making high purity and free flowing metal oxides powder

• US 7,931,836 B2
• Filed: 10/23/2006
• Issued: 04/26/2011
• Est. Priority Date: 10/21/2005
• Status: Active Grant

• Current Assignee: Sulzer Metco Incorporated (Sulzer AG)
• Original Assignee: Sulzer Metco Incorporated (Sulzer AG)
• Inventors: Mueller, Michael, Xie, Liangde, Patel, Ashish, Dorfman, Mitchell
• Primary Examiner(s): Theisen; Mary Lynn F
• Application Number:
  US11/584,747
• Publication Number:
  US 20070110655A1
• Time in Patent Office: 1,646 Days
• Field of Search: None
• US Class Current: 264/15
• CPC Class Codes: B01J 19/088 giving rise to electric discharges for heating purposes H05B7/00; for the production of ozone C01B13/11, H01T19/00
• CPC Class Codes: B01J 2/04 in a gaseous medium if combined with suspending the material in a gas, e.g. fluidised beds B01J2/16
• CPC Class Codes: B01J 2219/0869 Feeding or evacuating the reactor
• CPC Class Codes: B01J 2219/0879 Solid
• CPC Class Codes: C01B 13/145 After-treatment of oxides or hydroxides, e.g. pulverising, drying, decreasing the acidity
• CPC Class Codes: C01B 13/16 Purification
• CPC Class Codes: C01F 17/218 Yttrium oxides or hydroxides
• CPC Class Codes: C01F 7/021 After-treatment of oxides or hydroxides
• CPC Class Codes: C01F 7/46 Purification of aluminium oxide, aluminium hydroxide or aluminates C01F7/028 takes precedence
• CPC Class Codes: C01P 2004/32 Spheres
• CPC Class Codes: C01P 2004/50 Agglomerated particles
• CPC Class Codes: C01P 2004/61 Micrometer sized, i.e. from 1-100 micrometer
• CPC Class Codes: C01P 2006/10 Solid density
• CPC Class Codes: C01P 2006/20 Powder free flowing behaviour
• CPC Class Codes: C01P 2006/40 Electric properties
• CPC Class Codes: C01P 2006/80 Compositional purity
• CPC Class Codes: C22B 4/005 using plasma jets smelting, remelting, refining of metals using a plasma as heat source C22B9/22; generating or handling plasma in general H05H1/00; gas-filled discharge tubes for processing materials in general H01J37/32
• CPC Class Codes: H05H 1/42 with provisions for introducing materials into the plasma, e.g. powder, liquid arc stabilising or constricting arrangements H05H1/3405; coaxial protecting fluids H05H1/341; electrostatic spraying, spraying apparatus with means for charging the spray electrically B05B5/00 ; cf. B23K9/324, B05B7/22

Abstract

According to aspects of the present invention, metal oxide powder, such as yttria and alumina powder (feed material), is processed using a plasma apparatus. The process generally consists of in-flight heating and melting of the feed material by the plasma apparatus. The plasma apparatus contains a plasma torch with required power supply and cooling systems, a powder feeder, a chamber to collect the powder and a dedusting system. The heated powder forms molten spherical droplets that are rapidly cooled under free fall conditions. The plasma densification process removes some impurity oxides, modifies the morphology of the particle and increases the apparent density of the powder.

Claims

1. A method of processing a metal oxide powder comprising the steps of:

injecting a powder feed material into a plasma stream;

melting the powder feed material with said plasma stream to form molten droplets; and

cooling said molten droplets under free-fall conditions so as to form frozen spherical droplets such that said molten droplets have ample time for complete in-flight solidification before reaching a collection chamber,

wherein said frozen spherical droplets have higher density and purity levels than the powder feed material.

2. The method of claim 1, further comprising the step of collecting in the collection chamber said frozen spherical droplets that are above a predetermined size.

3. The method of claim 2, wherein said step of collecting further comprises separating said frozen spherical droplets that are below the predetermined size.

4. The method of claim 3, wherein said frozen spherical droplets that are below the predetermined size are recovered in a dedusting filter.

5. The method of claim 1, wherein a particle size of the collected frozen spherical droplets is between about 5 μ

m and 150 μ

m.

6. The method of claim 1, wherein a duration of said free-fall conditions is varied depending on a size and apparent density of said molten droplets.

7. The method of claim 1, wherein the powder feed material is frozen spherical droplets from a previous densification process.

8. The method of claim 1, wherein the frozen spherical droplets have a purity of higher than 99% by weight, an apparent density of higher than about 1.5 g/cc, and a flowability of less than about 60 s/50 g.

9. The method of claim 1, wherein the powder feed material is a metal oxide powder produced using flame pyrolysis, agglomeration, fusing and crushing, chemical precipitation or a chemical process.

10. The method of claim 1, wherein a duration of said free-fall conditions are varied depending on a size and apparent density of said molten droplets, wherein the frozen spherical droplets collected in the collection chamber have a size equal or above a predefined size, and wherein the method further comprises:

separating finer frozen spherical droplets that are below the predefined size from the frozen spherical droplets collected in the collection chamber; and

recovering the finer frozen droplets downstream of the collection chamber.

11. The method of claim 1, wherein the metal oxide power comprises one of yttria and alumina.

12. A method of processing a metal oxide powder comprising:

injecting a powder feed material into a plasma stream;

melting the powder feed material with said plasma stream to form molten droplets; and

cooling said molten droplets under free-fall conditions so as to form frozen spherical droplets such that said molten droplets have ample time for complete in-flight solidification before reaching a collection chamber,

wherein said frozen spherical droplets have higher density and purity levels than the powder feed material, and

wherein the method forms a free-flowing powder having higher purity than the powder feed material.

13. The method of claim 12, further comprising collecting said frozen spherical droplets in the collection chamber that are above a predetermined size.

14. The method of claim 13, wherein said collecting further comprises separating said frozen spherical droplets that are below the predetermined size.

15. The method of claim 14, wherein said frozen spherical droplets that are below the predetermined size are recovered in a dedusting filter.

16. The method of claim 13, wherein a particle size of the collected frozen spherical droplets is between about 5 um and 150 μ

M.

17. The method of claim 12, wherein a duration of said free-fall conditions are varied depending on a size and apparent density of said molten droplets.

18. The method of claim 12, wherein the powder feed material is frozen spherical droplets from a previous densification process.

19. The method of claim 12, wherein the frozen spherical droplets have a purity of higher than 99% by weight, an apparent density of higher than about 1.5 g/cc, and a flowability of less than about 60s/50g.

20. The method of claim 12, wherein the powder feed material is a metal oxide powder produced using flame pyrolysis, agglomeration, fusing and crushing, chemical precipitation or a chemical process.

21. The method of claim 12, wherein a duration of said free-fall conditions are varied depending on a size and apparent density of said molten droplets, wherein the frozen spherical droplets collected in the collection chamber have a size equal or above a predefined size, and wherein the method further comprises:

separating finer frozen spherical droplets that are below the predefined size from the frozen spherical droplets collected in the collection chamber; and

recovering the finer frozen droplets downstream of the collection chamber.

22. The method of claim 12, wherein the metal oxide power comprises one of yttria and alumina.

23. A method of making a high-purity free-flowing powder comprising:

injecting a powder feed material into a plasma stream;

melting the powder feed material with said plasma stream to form molten droplets; and

cooling said molten droplets under free-fall conditions so as to form frozen spherical droplets,

wherein, during cooling, said molten droplets have ample time for complete in-flight solidification before reaching a collection chamber.

24. A powder in accordance with claim 23, wherein the frozen spherical droplets have a higher purity level than the powder feed material.

25. The method of claim 23, wherein the frozen spherical droplets have improved powder flow properties over those of the powder feed material.

26. The method of claim 23, wherein the frozen spherical droplets have decreased powder porosity than that of the powder feed material.

27. The method of claim 23, wherein an overall density of powder of the frozen spherical droplets is greater than a density of the powder feed material.

28. The method of claim 23, wherein a purity of the frozen spherical droplets is greater than 99%, a density of the frozen spherical droplets is greater than 1.0 g/cc, and a flowability of the frozen spherical droplets are less than 60s/50g.

29. The method of claim 23, wherein a duration of said free-fall conditions are varied depending on a size and apparent density of said molten droplets, wherein the frozen spherical droplets collected in the collection chamber have a size equal or above a predefined size, and wherein the method further comprises:

separating finer frozen spherical droplets that are below the predefined size from the frozen spherical droplets collected in the collection chamber; and

recovering the finer frozen droplets downstream of the collection chamber.