Method of enhancing an aromatization catalyst

• US 7,932,425 B2
• Filed: 07/20/2007
• Issued: 04/26/2011
• Est. Priority Date: 07/28/2006
• Status: Active Grant

• Current Assignee: Chevron Phillips Chemical Company LP (Chevron Corp.)
• Original Assignee: Chevron Phillips Chemical Company LP (Chevron Corp.)
• Inventors: Knorr, Daniel B. Jr., Hasenberg, Daniel M., Holtermann, Dennis L., Glova, David J., Blessing, Christopher D., Brown, Scott H., Cheung, Tin-Tack Peter, Khare, Gyanesh P.
• Primary Examiner(s): DANG, THUAN D
• Application Number:
  US11/780,693
• Publication Number:
  US 20080027255A1
• Time in Patent Office: 1,376 Days
• Field of Search: 585/419, 585/418, 208/139, 208/138
• US Class Current: 585/419
• CPC Class Codes: C10G 2300/4081 Recycling aspects
• CPC Class Codes: C10G 2400/30 Aromatics
• CPC Class Codes: C10G 35/095 containing crystalline alumino-silicates, e.g. molecular sieves C10G35/065 takes precedence

Abstract

A hydrocarbon aromatization process comprising adding a nitrogenate, an oxygenate, or both to a hydrocarbon stream to produce an enhanced hydrocarbon stream, and contacting the enhanced hydrocarbon stream with an aromatization catalyst, thereby producing an aromatization reactor effluent comprising aromatic hydrocarbons, wherein the catalyst comprises a non-acidic zeolite support, a group VIII metal, and one or more halides. Also disclosed is a hydrocarbon aromatization process comprising monitoring the presence of an oxygenate, a nitrogenate, or both in an aromatization reactor, monitoring at least one process parameter that indicates the activity of the aromatization catalyst, modifying the amount of the oxygenate, the nitrogenate, or both in the aromatization reactor, thereby affecting the parameter.

Claims

1. A hydrocarbon aromatization process comprising:

adding an oxygenate, to a hydrocarbon stream to produce an enhanced hydrocarbon stream containing from about 2 ppm to 12 ppm water;

contacting the enhanced hydrocarbon stream with an aromatization catalyst in a reaction zone, wherein the catalyst comprises a non-acidic L-zeolite support, platinum, and one or more halides; and

recovering an effluent comprising aromatic hydrocarbons.

2. The process of claim 1 further comprising separating a hydrogen recycle stream from the effluent, wherein the hydrogen recycle stream has a water content of from about 1 ppmv to about 100 ppmv.

3. The process of claim 2 further comprising drying the hydrogen recycle stream to produce a dried hydrogen recycle stream having a water content of less than about 1 ppmv and feeding the dried hydrogen recycle stream to the hydrocarbon stream or the enhanced hydrocarbon stream.

4. The process of claim 1 further comprising controlling the addition of the oxygenate to the hydrocarbon stream to maintain one or more process parameters within a desired range.

5. The process of claim 1 further comprising controlling the addition of the oxygenate to the hydrocarbon stream to increase the production of one or more aromatic compounds in the reaction zone effluent by at least about 1 percent over pre-addition levels.

6. The process of claim 1 further comprising controlling the addition of the oxygenate to the hydrocarbon stream to increase the catalyst selectivity to benzene in the reaction zone effluent by at least about 1 percent over pre-addition levels.

7. The process of claim 1 further comprising prior to the addition of the oxygenate, treating the hydrocarbon stream to remove all or a portion of any oxygenates therein to produce a treated hydrocarbon stream.

8. The process of claim 7 wherein the oxygenate removed from the hydrocarbon stream comprises water, and wherein the treated hydrocarbon stream has a water content of less than about 1 ppmv.

9. The process of claim 1 wherein the aromatization process comprises a plurality of reactors, and the oxygenate is added to one or more of the reactors.

10. The process of claim 1 wherein the oxygenate comprises oxygen, oxygen-containing compounds, water, carbon dioxide, hydrogen peroxide, an alcohol, ozone, carbon monoxide, ketones, esters, aldehydes, carboxylic acids, lactones, or combinations thereof.

11. The process of claim 1 wherein the oxygenate comprises methanol, ethanol, propanol, isopropanol, butanol, t-butanol, pentanol, amyl alcohol, hexanol, cyclohexanol, phenol, or combinations thereof.

12. A hydrocarbon aromatization process comprising:

adding an oxygenate to a hydrocarbon stream to produce an enhanced hydrocarbon stream containing from about 2 ppm to 12 ppm water, to a hydrogen recycle stream to produce an enhanced recycle stream containing from about 2 ppm to 12 ppm water, or to both;

contacting the enhanced hydrocarbon stream alone or in combination with the enhanced recycle stream with an aromatization catalyst, wherein the catalyst comprises a non-acidic L-zeolite support, platinum, and one or more halides;

recovering an effluent comprising aromatic hydrocarbons; and

controlling the addition of the oxygenate to the hydrocarbon stream, the recycle stream, or both in order to maintain one or more process parameters within a desired range.

13. The process of claim 12 wherein the oxygenate is controlled to maintain a T_eq across one or more reactors in the process.

14. The process of claim 13 wherein the T_eq in the one or more reactors is decreased in comparison to a T_eq that occurs in the absence of the oxygenate.

15. The process of claim 12 wherein the T_eq decreases from about 0.1 percent to about 25 percent.

16. A hydrocarbon aromatization process comprising:

monitoring the presence of an oxygenate in the aromatization process;

monitoring at least one parameter of the aromatization process that indicates the activity of an aromatization catalyst, wherein the catalyst comprises a non-acidic L-zeolite support, platinum, and one or more halides; and

modifying the amount of the oxygenate in the aromatization process to maintain the water content in the reaction zone from about 2 ppm to about 12 ppm, thereby affecting the parameter.

17. The process of claim 16 wherein the parameter is benzene production, and wherein upon the modification of the amount of oxygenate in the aromatization process, benzene production is increased by at least about 1 percent as compared to the benzene production prior to modifying the amount of the oxygenate.

18. The process of claim 16 wherein the parameter is a useful life of the aromatization catalyst, and wherein the useful life of the aromatization catalyst is increased by at least about 5 percent as compared to a similar catalyst in which the amount of oxygenate has not been modified.

19. The process of claim 16 wherein the modification comprises increasing an amount of oxygenate in the aromatization process to a first level, then decreasing the amount of oxygenate in the aromatization process to a second level.

20. The process of claim 19 wherein the parameter is a useful life of the aromatization catalyst, and wherein the modification increases the useful life of the aromatization catalyst as compared to either a first similar aromatization catalyst in which the amount of oxygenate is maintained at the first level or a second similar aromatization catalyst in which the amount of oxygenate is maintained at the second level.