Use of flour consistency feedstock and improved hydrolyzing conditions in an ethanol production process

• US 7,935,370 B1
• Filed: 09/28/2005
• Issued: 05/03/2011
• Est. Priority Date: 01/13/1999
• Status: Expired due to Fees

• Current Assignee: Little Sioux Corn Processors, Lllp
• Original Assignee: Little Sioux Corn Processors, Lllp
• Inventors: Prevost, John E., Hammond, Neal A.
• Primary Examiner(s): WEIER, ANTHONY J
• Application Number:
  US11/162,942
• Time in Patent Office: 2,043 Days
• Field of Search: 426/46, 426/26, 426/29, 426/11
• US Class Current: 426/46
• CPC Class Codes: A23K 10/38 from distillers' or brewers' waste
• CPC Class Codes: C12P 7/06 Ethanol, i.e. non-beverage
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02P 60/87 Re-use of by-products of food processing for fodder production

Abstract

An improved process is shown wherein a carbohydrate-containing feedstock, such as corn, is milled to form a flour having a median particle size of less than about 100 microns. The flour is then hydrolyzed along with added vitamins and/or nutrients and/or enzymes. The hydrolyzed product is then mixed with a soy hull flour, also preferably having a median particle size of less than about 100 microns, and subjected to conventional fermentation to produce an ethanol containing product. The ethanol-containing product is then distilled to produce an ethanol enriched steam and a separate whole stillage. In preferred embodiments the process includes various filtration treatments of the whole stillage with and without added vitamins, nutrients, or other compounds to obtain value-added by-products.

Claims

1. A process for the production of ethanol and whole stillage from a carbohydrate-containing feedstock, comprising the steps of:

a) milling the carbohydrate-containing feedstock to produce a carbohydrate-containing flour having a median particle size of less than about 100 microns;

b) mixing water with the flour to produce a slurry solution;

c) fermenting the slurry solution under fermentation conditions to produce a fermented product stream; and

d) distilling the fermented product stream to produce an ethanol-rich stream and a separate whole stillage stream.

2. The process according to claim 1 wherein the slurry solution contains at least one enzyme in an amount of 0.5% to 1.5% by dry weight of the slurry solution;

and the process further comprises, prior to fermentation, hydrolyzing the slurry stream at temperatures between about 80 C. and about 130 C. for a period of time between about 45 to about 60 seconds to produce a hydrolyzed slurry stream and fermenting the hydrolyzed slurry stream.

3. The process according to claim 2 wherein the carbohydrate containing feedstock is corn and wherein a de-hulled soy flour having a median particle size of less than about 100 micros is added to the hydrolyzed slurry stream.

4. The process according to claim 2 wherein the slurry solution contains an additive selected from the group consisting of vitamins, minerals, amino acids, proteins, flavors, phytochemicals, pharmaceuticals, nutraceuticals, binders and fillers and mixtures thereof.

5. The process according to claim 1 wherein the slurry solution contains an additive selected from the group consisting of vitamins, minerals, amino acids, proteins, flavors, phytochemicals, pharmaceuticals, nutraceuticals, binders and filler, and mixtures thereof.

6. The process according to claim 1 wherein a de-hulled soy flour having a median particle size of less than about 100 microns is added to the slurry solution.

7. A process for the production of ethanol and whole stillage from a carbohydrate-containing feedstock, comprising the steps of:

a) milling the carbohydrate-containing feedstock to produce a milled feedstock having a median particle size of less than about 100 microns;

b) mixing water and enzymes with the milled feedstock to produce a slurry solution, the enzymes comprising about 0.5% to about 1.5% by dry weight of the slurry solution;

c) hydrolyzing the slurry solution;

d) fermenting the hydrolyzed slurry solution under fermentation conditions to produce a fermented product stream; and

e) distilling the fermented product steam to produce an ethanol-rich stream and a separate whole stillage stream.

8. The process according to claim 7 wherein the carbohydrate containing feedstock is corn and the hydrolyzing is for a period of time and under temperature and pressure conditions sufficient

a) to partially gelatinize the milled feedstock to form corn starch molecules having terminal amylose groups;

and

b) to cleave at least some of the terminal amylose groups from the corn starch molecules.

9. The process according to claim 8 wherein the period of time and the temperature and pressure conditions are sufficient to cleave at least 20% of the terminal amylose groups from the corn starch molecules.

10. The process according to claim 9 wherein the hydrolyzing is conducted for a period of about 45-60 seconds and under moderate pressure and temperatures between about 80°

C. and 130°

C.

11. The process according to claim 7 wherein a de-hulled soy flour having a median particle size of less than about 100 microns is added to the hydrolyzed slurry stream.

12. The process according to claim 7 wherein a de-hulled soy flour having a median particle size of less than about 100 microns is added to the slurry solution.

13. A process for the production of ethanol and whole stillage from a carbohydrate-containing feedstock, consisting essentially of:

a) milling the carbohydrate-containing feedstock to produce a carbohydrate-containing flour having a median particle size of less than about 100 microns;

b) mixing water with the flour to produce a slurry solution wherein the slurry solution contains at least one enzyme in an amount of 0.5% to 1.5% by dry weight of the slurry solution;

c) hydrolyzing the slurry stream at temperatures between about 80°

C. and about 130°

C. for a period of time between about 45 to about 60 seconds to produce a hydrolyzed slurry stream;

d) fermenting the slurry solution under fermentation conditions to produce a fermented product stream; and

e) distilling the fermented product stream to produce an ethanol-rich stream and a separate whole stillage stream.

14. A process for the production of ethanol and whole stillage from a carbohydrate containing feedstock that increases the rate of production and volume of ethanol produced comprising milling the carbohydrate-containing feedstock to a particle size of less than about 100 microns, reducing the time for heating during hydrolysis, and increasing the level of amylose groups cleaved from the carbohydrate.

15. The process of claim 14 wherein reducing the time for heating comprises reducing the time to between about 45 to about 60 seconds.

16. The process of claim 14 wherein a conventional ethanol production process requires about 15 minutes for heating during hydrolysis and said reducing the time for heating comprises a reduction in the range of 1/20 to 1/15 of the time required for said conventional ethanol production process.

17. The process of claim 16 wherein said process further comprises fermentation and said reducing of time for heating causes the increase in the level of cleavage of amylose groups, and said increase in the level of cleavage of amylose groups increases the level of fermentation resulting in an increase in the volume of ethanol.

18. The process of claim 16 wherein said process further comprises fermentation and said reducing the time for heating further comprises an addition of pressure of about 500 psi and results in an increase in the number of cleaved amylose groups and an increase in the efficiency of fermentation and produce an increase in the volume of ethanol.