Nanotextured super or ultra hydrophobic coatings

• US 7,943,234 B2
• Filed: 02/26/2008
• Issued: 05/17/2011
• Est. Priority Date: 02/27/2007
• Status: Active Grant

• Current Assignee: Innovative Surface Technologies, Inc.
• Original Assignee: Innovative Surface Technologies, Inc.
• Inventors: Guire, Patrick, Taton, Kristin, Lawin, Laurie R., Wen, Jie
• Primary Examiner(s): McNeil; Jennifer C
• Assistant Examiner(s): ROBINSON, LAUREN E
• Application Number:
  US12/037,520
• Publication Number:
  US 20080268233A1
• Time in Patent Office: 1,176 Days
• Field of Search: 428/323, 428/327, 428/423.1, 428/425.9, 524/442, 524/492
• US Class Current: 428/323
• CPC Class Codes: C08K 3/08 Metals
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 5/1525 Four-membered rings
• CPC Class Codes: C08K 9/06 with silicon-containing compounds
• CPC Class Codes: C09D 125/06 Polystyrene
• CPC Class Codes: C09D 125/10 with conjugated dienes
• CPC Class Codes: C09D 5/00 Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced electrically insulating plastics, resins or waxes H01B3/30; Filling pastes
• CPC Class Codes: C09D 7/62 modified by treatment with other compounds
• CPC Class Codes: C09D 7/67 Particle size smaller than 100 nm
• CPC Class Codes: C09D 7/68 Particle size between 100-1000 nm
• CPC Class Codes: C09D 7/69 Particle size larger than 1000 nm
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/254 Polymeric or resinous material
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31569 Next to natural rubber

Abstract

The invention describes compositions that include a polymer having a water contact angle of between about 120° and about 150° or greater adhered to a 1 nm to about a 25 micron diameter sized particle optionally with an oxide layer. In particular, the particle is a silica and one which has been pretreated with a silane.

Claims

1. An ultrahydrophobic or superhydrophobic coating composition selected from the group of a homopolymer or copolymer of a polyalkylene, a polyacrylate, a polymethacrylate, a polyester, a polyamide, a polyurethane, a polyvinylarylene, a polyvinyl ester, a polyvinylarylene/alkylene copolymer, a polyalkyleneoxide or mixtures thereof, as polymeric binder in combination with particles having a particle size of between about 1 nm to 25 microns and a radical-generating initiator compound,

wherein the polymer has less than 1 mole percent alkylenic reactive sites of unsaturation.

2. The coating composition of claim 1, wherein the coating exhibits a water contact angle of at least about 120°

.

3. The coating composition of claim 1, wherein the particles are selected from the group of aluminum oxides (alumina), titanium oxide, zirconium oxide, gold (treated with organo thiols), silver (organo thiol or silane treated), nickel, nickel oxide, iron oxide, and alloys (all treated with silane), polystyrene particles, (meth)acrylate particles, PTFE particles, silica particles, polyolefin particles, polycarbonate particles, polysiloxane particles, silicone particles, polyester particles, polyamide particles, polyurethane particles, ethylenically unsaturated polymer particles, polyanhydride particles, biodegradable particles, polycaprolactone (PCL), polylactideglycolide (PLGA), nanofibers, nanotubes, nanowires, or combinations thereof.

4. The coating composition of claim 3, wherein the particles can be silanized.

5. The coating composition of claim 1, wherein the polymeric binder has a surface tension of less than about 50 mN/m.

13. The coating composition of claim 1, wherein the radical generating initiator compound is selected from the group of a peroxide, peroxy compound, benzoin derivative, acetophenone derivative, benzilketal, α

-hydroxyalkylphenone, α

-aminoalkylphenone, O-acyl α

-oximinoketone, acylphosphine oxide, acylphosphonate, thiobenzoic S-ester, azo compound, azide compound, triazine, compound with at least one Si—

Si bond, biimidazole, quinone, benzophenone, xanthone, thioxanthone, ketocoumarin, aromatic 1,2 diketone, phenylglyoxylate, anthraquinone, anthrone, anthrone-like heterocycle, aryl ketone, acridone, redox reagent, organic hydroperoxide, metal alkyl, organometallic reagent or mixtures thereof.

6. A substrate coated with an ultrahydrophobic or a superhydrophobic composition comprising a polymer that is a homopolymer or copolymer selected from the group of a polyalkylene, a polyacrylate, a polymethacrylate, a polyester, a polyamide, a polyurethane, a polyvinylarylene, a polyvinyl ester, a polyvinylarylene/alkylene copolymer, a polyalkyleneoxide or mixtures thereof as a polymeric binder in combination with particles having a particle size of between about 1 nm to 25 microns and a radical-generating initiator compound,

wherein the polymer has less than 1 mole percent alkylenic reactive sites of unsaturation.

7. The substrate coated with an ultrahydrophobic or a superhydrophobic composition of claim 6, wherein the coating exhibits a water contact angle of at least about 120°

.

8. The substrate coated with an ultrahydrophobic or a superhydrophobic composition of claim 7, wherein the particles are selected from the group of aluminum oxides (alumina), titanium oxide, zirconium oxide, gold (treated with organo thiols), silver (organo thiol or silane treated), nickel, nickel oxide, iron oxide, and alloys (all treated with silane), polystyrene particles, (meth)acrylate particles, PTFE particles, silica particles, polyolefin particles, polycarbonate particles, polysiloxane particles, silicone particles, polyester particles, polyamide particles, polyurethane particles, ethylenically unsaturated polymer particles, polyanhydride particles biodegradable particles, polycaprolactone (PCL), polylactideglycolide (PLGA), nanofibers, nanotubes, nanowires, or combinations thereof.

9. The substrate coated with an ultrahydrophobic or a superhydrophobic composition of claim 8, wherein the particles are pretreated with a silane.

10. The substrate coated with an ultrahydrophobic or a superhydrophobic composition claim 6, wherein the polymeric binder has a surface tension of less than about 50 mN/m.

11. The substrate coated with an ultrahydrophobic or a superhydrophobic composition of claim 6, wherein the substrate is selected from the group of a plastic, a natural polymer, a glass, a wood, a paper, a ceramic, a metal, a composite or mixtures thereof.

12. The substrate of claim 6, wherein the surface can be pretreated to promote adhesion of the ultra hydrophobic ultrahydrophobic or superhydrophobic coating to the substrate.

14. The substrate of claim 11, wherein the substrate is a plastic comprising polypropylene or polystyrene.

15. The substrate of claim 11, wherein the substrate is a fabric.

16. The substrate coated with an ultrahydrophobic or superhydrophobic composition of claim 6, wherein the coating composition is crosslinked.

17. A cured ultrahydrophobic or superhydrophobic coating, composition selected from the group of a homopolymer or copolymer of a polyalkylene, a polyacrylate, a polymethacrylate, a polyester, a polyamide, a polyurethane, a polyvinylarylene, a polyvinyl ester, a polyvinylarylene/alkylene copolymer, a polyalkyleneoxide or mixtures thereof, as a cured polymeric binder in combination with particles having a particle size of between about 1 nm to 25 microns, wherein the curing was effected by a radical-generating initiator compound contained within the uncured polymeric binder and wherein the uncured polymeric binder had less than 1 mole percent alkylenic reactive sites of unsaturation.