Dry adhesion bonding

• US 7,947,148 B2
• Filed: 06/01/2007
• Issued: 05/24/2011
• Est. Priority Date: 06/01/2006
• Status: Expired due to Fees

• Current Assignee: Board of Regents of the University of Michigan (University of Michigan)
• Original Assignee: Board of Regents of the University of Michigan (University of Michigan)
• Inventors: Chen, Hsien-Yeh, Lahann, Joerg
• Primary Examiner(s): Crispino; Richard
• Assistant Examiner(s): McNally; Daniel
• Application Number:
  US11/756,890
• Publication Number:
  US 20070281126A1
• Time in Patent Office: 1,453 Days
• Field of Search: 156/310, 156/272.2, 106/285, 106/287.23, 427/255.28, 427/585
• US Class Current: 156/310
• CPC Class Codes: B05D 1/60 Deposition of organic layers from vapour phase vapour phase deposition in general C23C14/00, C23C16/00
• CPC Class Codes: B05D 5/10 to obtain an adhesive surface
• CPC Class Codes: C09J 5/04 involving separate application of adhesive ingredients to the different surfaces to be joined
• CPC Class Codes: Y10T 428/24 Structurally defined web or sheet [e.g., overall dimension, etc.]

Abstract

Methods for bonding include deposition an adhesion layer on at least one substrate using chemical vapor deposition. The two adhesion layers each have a reactive group that is complementary to the other, thus enabling strong adhesion between the bonded substrates. Devices include two substrates that can be adhered together by chemically depositing an adhesion layer on at least one substrate using chemical vapor deposition. The substrates each have a reactive group that is complementary to the other, thus enabling strong adhesion between the bonded substrates.

Claims

1. A method of bonding comprising:

a. providing a first substrate;

b. providing a second substrate;

c. depositing a first adhesion layer upon at least a portion of at least one of said first substrate using chemical vapor deposition, said first adhesion layer having a first reactive group;

d. depositing a second adhesion layer upon at least a portion of said second substrate to form a second adhesion layer, said second adhesion layer having a second reactive group, wherein said first reactive group is distinct from said second reactive group and said first reactive group is complementary with said second reactive group, wherein at least one of said first adhesion layer or said second adhesion layer comprises poly(p-xylylene); and

e. contacting said first adhesion layer with said second adhesion layer causing a reaction between said first reactive group and said second reactive group to form an adhesion bond between said first substrate and said second substrate, thereby providing an adhered article.

2. The method according to claim 1, wherein said depositing said second adhesion layer upon at least a portion of said second substrate comprises chemical vapor deposition of said second adhesion layer, wherein each of said first and second adhesion layers comprise poly(p-xylylene) with said first reactive group and said second reactive group, respectively.

3. The method according to claim 2, wherein said poly(p-xylylene) of said first adhesion layer, said second adhesion layer, or both said first adhesion layer and said second adhesion layer, is selected from the group consisting of poly(4-methanamine-p-xylylene-co-p-xylylene), poly(4-formyl-p-xylylene-co-p-xylylene), poly(p-xylylene carboxylic acid pentafluorophenol ester-co-p-xylylene), poly(p-xylylene-2,3-dicarboxylic acid anhydride) and combinations thereof.

4. The method according to claim 2, wherein said first reactive group, said second reactive group, or both said first and second reactive groups are selected from the group consisting of:

H, NH₂, (CH₂)_nNH₂, OH, SH, NH—

NH₂, CO—

NH—

NH₂, CCH, N₃, OSO₂CF₃, (CH₂)_n)SO₂CF₃, OSO₂C₅F₅, (CH₂)_n)SO₂C₅F₅, CH₂OCH₂, COOX, CH₃(COO)₂X, CHO, (CH₂)_nCHO, CF₃, C_nF_2n+1, azlactone, NHS, and combinations thereof.

5. The method according to claim 1, further comprising placing a spacer between at least a portion of said first adhesion layer and said second adhesion layer.

6. The method according to claim 5, wherein said placing a spacer between at least a portion of said first adhesion layer and second adhesion layer comprises placing a spacer selected from the group consisting of an adhesive, a carbon nanotube, a hydrogel, a paste, a composite material and combinations thereof.

7. The method according to claim 1, wherein said first reactive group and said second distinct reactive group are selected from the group consisting of:

hydrogen, amino, aldehyde, ketone, ester, amine, amide, alcohol, thiol, thioisocyanate, isocyanate, hydrazine, hydrazide, phosphonate, phosphate, alcohol, hydroxyl, methoxyl, benzoyl, epoxide, acetate, carboxymethyl, anhydride, lactone, pentafluorophenol ester, trifluoroacetate, trifluoromethyl ketone, trifuoromethanesulfonate, alkyl tosylate, mesylate, brosylate, nosylate, nonaflate, triflate, or tresylate salts, thiosemicarbazido, semicarbazido, maleimido N-Hydroxysuccinimide ester (NHS) and combinations thereof.

8. The method according to claim 7, wherein said first reactive group is an amino and said second reactive group is an aldehyde.

9. The method according to claim 1, wherein said contacting said first layer with said second adhesion layer causing a reaction between said first reactive group and said second reactive group comprises contacting said first adhesion layer with said second adhesion layer causing a chemical bond selected from the group consisting of a covalent bond, an ionic bond, a hydrogen bond, a metal coordination bond and combinations thereof between said first reactive group and said second reactive group.

10. The method according to claim 1, further comprising pretreating at least one of said first substrate and said second substrate with any one or more of:

cold gas plasmas, such as oxygen, hydrogen, nitrogen, ammonia, carbon dioxide, ethylene, acetylene, propylenes, butylenes, ethanol, acetone, sulfur dioxide or mixtures thereof.

11. The method according to claim 1, further comprising heating said adhered article for a period of time ranging from about 0.5 hours to about 24 hours in an oven set to a temperature ranging from about 50°

C. to about 300°

C.

12. The method according to claim 1, further comprising applying an energy source to said adhered article said energy source selected from the group consisting of:

ambient light, monochromatic light, actinic radiation and combinations thereof.

13. The method according to claim 1, wherein said first adhesion layer is a surface of said first substrate.

14. The method according to claim 1, wherein depositing an adhesion layer upon at least a portion of said second substrate to form a second adhesion layer comprises depositing an adhesion layer upon at least a portion of said second substrate using chemical vapor deposition to form said second adhesion layer.

15. The method according to claim 1, wherein said first substrate and said second substrate are each selected from the group consisting of plastic, thermoplastics polyalkylterephthalates, polysiloxanes, metals, minerals, ceramics, membranes, gels, glasses and combinations thereof.

16. The method according to claim 1, wherein said first substrate comprises PDMS and said second substrate comprises glass.

17. The method according to claim 1, wherein at least one of the first adhesion layer or the second adhesion layer further comprises a polarity modifying component.

18. The method according to claim 1, wherein said first reactive group is selected from a hydrazine and/or hydrazide group and said second reactive group is an aldehyde, wherein said reaction is reversible.

19. A method of bonding substrates, the method comprising:

a. depositing via chemical vapor deposition a first adhesion layer to at least a portion of a first substrate, wherein said first adhesion layer comprises poly(p-xylylene) comprising a first reactive group;

b. depositing via chemical vapor deposition a second adhesion layer to at least a portion of a second substrate, wherein said second adhesion layer comprises poly(p-xylylene) comprising a second reactive group that is distinct from said first reactive group and said first and said second reactive groups are complementary with one another;

c. contacting said first adhesion layer with said second adhesion layer so that said first reactive group interacts with said second reactive group to form an adhesion bond having a bond strength that is greater than or equal to a fracture strength of either of said first substrate or said second substrate.

20. A method of bonding substrates, the method comprising:

a. depositing via chemical vapor deposition a first adhesion layer to at least a portion of a first substrate, wherein said first adhesion layer comprises a first reactive group selected from the group consisting of;

amine, alcohol, and thiol;

b. depositing via chemical vapor deposition a second adhesion layer to at least a portion of a second substrate, wherein said second adhesion layer comprises a second reactive group that is complementary with said first reactive group, wherein said second reactive group is selected from the group consisting of;

alkyl carbodiimide-activated ester, bromoacetamide, carboxyl, chloroacetamide, cyclic carboxylic anhydride, 9-fluorenylmethoxycarbonyl, N-hydroxysuccinimide ester, isocyanate, isothiocyanate, phosphate, phosphonate, sulfonate, alkyl carbodiimide-activated ester, ester, maleimido, semicarbazido, thiosemicarbazido, and alkyl tosylate, mesylate, brosylate, nosylate, nonaflate, triflate, or tresylate salts;

c. contacting said first adhesion layer with said second adhesion layer so that said first reactive group interacts with said second reactive group to form an adhesion bond between said first substrate and said second substrate.