Process for increasing liquid extraction from fabrics

• US 7,954,190 B2
• Filed: 06/10/2004
• Issued: 06/07/2011
• Est. Priority Date: 06/19/2003
• Status: Active Grant

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Santamarina, Vicente, Zhang, Shulin Larry, Heatherly, Joseph Dean
• Primary Examiner(s): Kornakov; Michael
• Assistant Examiner(s): BLAN, NICOLE R
• Application Number:
  US10/865,123
• Publication Number:
  US 20040255395A1
• Time in Patent Office: 2,553 Days
• Field of Search: 815/9, 134/42
• US Class Current: 8/159
• CPC Class Codes: D06M 13/513 with at least one carbon-silicon bond
• CPC Class Codes: D06M 15/643 containing silicon in the main chain
• CPC Class Codes: D06M 15/647 containing polyether sequences
• CPC Class Codes: D06M 23/00 Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process

Abstract

The present invention relates to a process of increasing liquid extraction from fabrics having a first liquid content through the use of a mechanical extraction means and a liquid extraction agent.

Claims

1. A process for increasing liquid extraction from a consumer bundle of fabrics during a washing cycle in a washing machine, the process comprising:

delivering to a predetermined volume of liquid in the washing machine during a washing stage or a rinse stage of the washing cycle an amount of a liquid extraction agent having a critical micelle concentration of from about 10 ppm to about 1500 ppm in the liquid, such that the predetermined volume of liquid contains from about 10 ppm to about 3000 ppm by weight of the liquid extraction agent, based on the weight of the predetermined volume of liquid, the liquid extraction agent comprising a nonionic silicone surfactant selected from polyalkylene oxide polysiloxanes of formula (I);

R¹—

(CH₃)₂SiO—

[(CH₃)₂SiO]_a—

[(CH₃)(R¹)SiO]_b—

Si(CH₃)₂—

R¹ 

 

(I),

 

where

a+b is from about 1 to about 50;

each group R¹ is selected from the group consisting of methyl and a poly(ethyleneoxide/propyleneoxide) copolymer group of formula (II);

—

(CH₂)_nO(C₂H₄O)_c(C₃H₆O)_dR² 

 

(II),

 

where

n is 3 or 4,

c is from 6 to about 100 for all polyalkyleneoxy side groups,

c+d is from about 6 to about 150 for all polyalkyleneoxy side groups, and

each R² is independently selected from the group consisting of hydrogen, an alkyl having 1 to 4 carbon atoms, and an acetyl group;

at least one group R¹ in each polyalkylene oxide polysiloxane of formula (I) is a poly(ethyleneoxide/propyleneoxide) copolymer group of formula (II); and

each polyalkylene oxide polysiloxane has a weight-average molecular weight of from about 2,000 daltons to about 10,000 daltons,

contacting the consumer bundle of fabrics with the liquid in the washing machine such that an effective amount of the liquid extraction agent distributes throughout the consumer bundle of fabrics, and such that the consumer bundle of fabrics acquires a first liquid content consisting of an amount of trapped liquid held interstitially in fabric weaves or void spaces of individual fabrics of the consumer bundle of fabrics, the trapped liquid having a surface tension of 40 mN/m or less; and

subjecting the consumer bundle of fabrics to a mechanical extraction to remove at least a portion of the trapped liquid from the consumer bundle of fabrics, such that after said mechanical extraction the consumer bundle of fabrics has a reduced second liquid content, the reduced second liquid content being less than an extraction-only liquid content achievable by performing the same amount of mechanical extraction in the absence of the liquid extraction agent.

2. The process of claim 1, wherein the liquid extraction agent is contacted with the fabric during the rinse stage of the washing cycle and the liquid extraction agent is not deposited on or attached to surfaces or fibers of the fabrics after the rinse stage.

3. The process of claim 1, wherein the liquid extraction agent has a critical micelle concentration of from about 10 ppm to about 300 ppm in the liquid, and the predetermined volume of liquid in the washing machine contains from about 10 ppm to about 300 ppm by weight of the liquid extraction agent, based on the weight of the predetermined volume of liquid.

4. The process of claim 1, wherein the liquid extraction agent further comprises a non-surfactant suds suppressor selected from the group consisting of high molecular-weight hydrocarbons, N-alkylated aminotriazines, monostearyl phosphates, silicone suds suppressors, secondary alcohols, and mixtures of secondary alcohols with silicone oils.

5. The process of claim 4, wherein non-surfactant suds suppressor is a silicone suds suppressor.

6. The process of claim 4, wherein the liquid extraction agent further comprises an additional surfactant selected from the group consisting of anionic surfactants, cationic surfactants, nonionic surfactants, zwitterionic surfactants, fluorosurfactants, and any combination thereof.

7. The process of claim 4, wherein the liquid extract agent further comprises additional agents selected from the group consisting of perfumes, softening agents, anti-wrinkle agents, buffers, enzymes, dispersants, builders, dyes, brighteners, bleaches and any mixture thereof.

8. The process of claim 1, wherein the liquid extraction agent further comprises a liquid extraction agent adjunct for improving packing of the liquid extraction agent at a water-air interface, the liquid extraction agent adjunct comprising an alkyl alcohol.

9. The process of claim 1, wherein c+d of formula (II) is from about 6 to about 100 and the weight-average molecular weight of each polyalkylene oxide polysiloxane is from about 2,000 daltons to about 8,000 daltons.

10. The process of claim 9, wherein d of formula (II) is zero, such each polyalkylene oxide polysiloxane is free of propyleneoxy groups.

11. The process of claim 9, wherein the ratio of ethylene oxide units to propylene oxide units in the nonionic silicone surfactant is from 40/60 to 50/50.

12. The process of claim 1, wherein the nonionic silicone surfactant has a weight average molecular weight of 8,000 daltons and ratio of ethylene oxide units to propylene oxide units of 50/50.

13. The process of claim 1, wherein the liquid extraction agent is contacted with the consumer bundle of fabric immediately prior to the subjecting of the consumer bundle of fabric to the mechanical extraction.

14. The process of claim 1, wherein the liquid extraction agent is delivered in a single dose.