Optical pH sensor

• US 7,961,327 B1
• Filed: 01/07/2010
• Issued: 06/14/2011
• Est. Priority Date: 01/07/2009
• Status: Active Grant

• Current Assignee: Bovaird & Company
• Original Assignee: Bovaird & Company
• Inventors: Bovaird, Brian, Sublette, Kerry L., LoPresti, Peter, Ashenayi, Kaveh
• Primary Examiner(s): Toatley; Gregory J
• Assistant Examiner(s): ALLI, IYABO
• Application Number:
  US12/683,885
• Time in Patent Office: 523 Days
• Field of Search: 356436-445, 356/36, 25055911-55929, 250/227.21
• US Class Current: 356/436
• CPC Class Codes: G01N 21/431 Dip refractometers, e.g. using optical fibres
• CPC Class Codes: G01N 21/55 Specular reflectivity

Abstract

A method to sense pH of a fluid and an optical pH sensor. The method includes the steps of supplying at least a portion of an optical source through an input fiber. The optical source is passed through a sensor head having a sapphire window to a fluid. Optical power reflected from the fluid is collected in a plurality of output fibers in the sensor head. The reflected optical power in the output fibers in the sensor head is thereafter converted to an electrical signal which is used to determine the pH of the fluid.

Claims

1. A method to sense pH of a fluid, said method comprising the steps of:

supplying an optical source through an input fiber;

passing said optical source at a range of predetermined input angles to a sensor head having a transparent window in contact with a fluid, wherein said window has a high refractive index, and wherein a side of said window in contact with said fluid is coated with a thin protein layer to prevent fouling of said window due to accumulation of fat, oil and/or grease within said fluid on said window;

forming a reflective boundary between said fluid and said side of said window in contact with said fluid,

collecting optical power reflected from said reflective boundary between said window and said fluid by a plurality of output fibers in said sensor head, wherein said output fibers are positioned with respect to said input fiber so as to collect optical power reflected from said reflective boundary at predetermined output angles; and

detecting a fouling of said sensor head based on reflected optical power collected by said output fibers;

if no fouling of said sensor head is detected, converting said reflected optical power collected by said output fibers to pH of said fluid.

2. A method as set forth in claim 1 wherein said step of supplying said optical source further comprises the step of periodically modulating said optical source from a light emitting diode with time in a sinusoidal manner around an average output value.

3. A method as set forth in claim 1 wherein said step of supplying said optical source further includes periodically modulating said optical source from a laser diode with a continuous tone around an average output value.

4. A method as set forth in claim 1 wherein said sensor head includes said input fiber centrally located surrounded by said plurality of said output fibers, and wherein said sensor head is constructed such that collecting said reflected optical power by said output fibers is dependent upon said reflected optical power reflected at said reflective boundary from said optical source supplied by said input fiber.

5. A method as set forth in claim 4 wherein said plurality of output fibers each have diameters larger than said input fiber.

6. A method as set forth in claim 1 including the additional step of splitting said optical source prior to delivery to said input fiber so that a small portion of said optical source is directed to a power monitoring circuit.

7. A method as set forth in claim 6 including the additional steps of dividing said reflected optical power by power from said power monitoring circuit to produce a ratiometric signal, and adjusting said ratiometric signal for temperatures of said fluid.

8. A method as set forth in claim 1 wherein said step of detecting a fouling of said sensor head based on said reflected optical power in said output fibers further comprises the steps of:

if said reflective optical power is above a predetermined expected upper reading, servicing said sensor head; and

if said reflective optical power is below a predetermined expected lower reading, servicing said sensor head.

9. A method as set forth in claim 1 wherein said step of converting said reflected optical power in said output fibers to pH of said fluid is accomplished with signal processing software.

14. A method as set forth in claim 1 wherein said transparent window is constructed of sapphire.

15. A method as set forth in claim 8 wherein said step of servicing said sensor head further comprises the steps of:

removing said sensor head from said fluid;

cleaning and/or reapplying said thin protein layer;

verifying said sensor head fouling is no longer occurring; and

returning said sensor head into said fluid.

10. An optical pH sensor which comprises:

an input fiber supplied with an optical source;

a sensor head in communication with said optical source;

a transparent window in said sensor head to permit passage of said optical source from said input fiber at a plurality of predetermined range of angles to a fluid to be tested, and said window constructed of a material having a high refractive index;

a thin protein layer coating an external surface of said window between said window and said fluid to be tested, and said thin protein layer constructed to prevent fouling of said window due to accumulation of fat, oil and/or grease within said fluid on said window;

a plurality of output fibers in said sensor head for collecting optical power reflected from a reflective boundary between said window and said fluid, said output fibers constructed in said sensor head with respect to said input fiber to collect optical power reflected from said reflective boundary at predetermined output angles, and said input fiber of said sensor head centrally located surrounded by said plurality of said output fibers;

a receiver unit for converting optical output power to electrical voltage in order to determine pH of said fluid; and

a sensor fouling detection and servicing unit for determining fouling of said sensor head due to accumulation of fat, oil and/or grease within said fluid on said window of said sensor head and/or deterioration of said thin protein layer.

11. An optical pH sensor as set forth in claim 10 wherein said optical source emanates from a light emitting diode which is periodically modulated with time in a sinusoidal manner around an average output value.

12. An optical pH sensor as set forth in claim 10 wherein said optical source emanates from a laser diode which is periodically modulated with time and at a continuous tone around an average output value.

13. An optical pH sensor as set forth in claim 10 wherein said output fibers each have diameters larger than said input fiber.

16. An optical pH sensor as set forth in claim 10 wherein said transparent window is constructed of sapphire.