Polymer coated nanoparticle activation of oxidants for remediation and methods of use thereof

• US 7,963,720 B2
• Filed: 09/26/2008
• Issued: 06/21/2011
• Est. Priority Date: 09/26/2007
• Status: Expired due to Fees

• Current Assignee: Ethical Solutions, LLC
• Original Assignee: The United States of America As Represented By The Secretary of Agriculture, Verutek Incorporated
• Inventors: Nadagouda, Mallikarjuna N., Varma, Rajender S., Hoag, George E., Collins, John B.
• Primary Examiner(s): KRECK, JOHN J
• Application Number:
  US12/680,103
• Publication Number:
  US 20100232883A1
• Time in Patent Office: 998 Days
• Field of Search: 405/128.75, 977/810, 977/903
• US Class Current: 405/128.75
• CPC Class Codes: B09C 1/002 involving in-situ ground water treatment
• CPC Class Codes: B09C 1/08 chemically
• CPC Class Codes: Y10S 977/81 Of specified metal or metal alloy composition
• CPC Class Codes: Y10S 977/903 for conversion, containment, or destruction of hazardous material

Abstract

Methods of decreasing the amount of one or more contaminants in contaminated soil comprise introducing polymer-coated nanoparticles into the contaminated soil, optionally with other reagents. The polymer-coated nanoparticles exhibit an enhanced ability to migrate through the soil and provide greater control of the rate of activation of other chemicals, such as oxidants, in the contaminated soil.

Claims

1. A method for decreasing the amount of one or more contaminants in contaminated soil, comprising:

obtaining polymer-coated nanoparticles comprising a biodegradable polymer coating, and

introducing the polymer-coated nanoparticles into the contaminated soil in an amount effective to decrease the amount of one or more contaminants in the soil, wherein the contaminated soil contains contaminants comprising a non-aqueous phase liquid and wherein the polymer coated nanoparticles partition into the non-aqueous phase liquid.

2. The method of claim 1, comprising also introducing an oxidant into the contaminated soil, wherein the nanoparticles activate the oxidant.

3. The method of claim 2, wherein the oxidant is persulfate.

4. The method of claim 2, wherein the activated oxidant oxidizes one or more contaminants in the contaminated soil, thereby decreasing the amount of one more contaminants present in the contaminated soil.

5. The method of claim 1, wherein the polymer-coated nanoparticles create a reducing environment in the contaminated soil.

6. The method of claim 5, wherein the reducing environment promotes the growth and metabolism of anaerobic microorganisms, and wherein the anaerobic microorganisms decrease the amount of one or more contaminants present in the contaminated soil.

7. The method of claim 1, wherein the polymer-coated nanoparticles comprise zero-valent iron and/or zero-valent manganese, and wherein the polymer-coated nanoparticles have a diameter no greater than about 1 micron.

8. The method of claim 1, wherein the biodegradable polymer is selected from the group consisting of xanthan polysaccharide, polyglucomannan polysaccharide, emulsan, an alginate biopolymer, hydroxypropyl methylcellulose, carboxy-methyl cellulose, ethyl cellulose, chitin, chitosan, polyvinyl alcohol, polyvinyl esters, polyvinyl amides, copolymers of polylactic acid, and combinations thereof.

9. The method of claim 1, wherein the biodegradable polymer composition comprises carboxymethyl cellulose.

11. The method of claim 1, wherein the polymer-coated nanoparticles remain able to activate an oxidant in a location in need of remediation for at least as long as an oxidant capable of oxidizing contaminant remains in the location.

12. The method of claim 11, wherein the nanoparticles travel as far through the location as does the oxidant.

13. The method of claim 1, wherein the polymer coating is selected from the group consisting of a partitioning polymer, a surfactant material, a material capable of conducting an electric current, a hydrophobic material, a water-insoluble material, an oil-insoluble material, a material permeable to an atomic or molecular species selected from the group consisting of persulfate, sulfate, peroxide, hydroperoxide, oxygen, and hydroxyl, and combinations.

14. The method of claim 1, wherein the polymer coating degrades over the duration of a remediation process.

10. A method for decreasing the amount of one or more contaminants in contaminated soil, comprising:

obtaining polymer-coated nanoparticles comprising a polymer coating;

obtaining an oxidant; and

introducing the polymer-coated nanoparticles and the oxidant into the contaminated soil in amounts effective to decrease the amount of one or more contaminants in the soil, wherein the polymer coating comprises a polymer selected from the group consisting of polymethyl methacrylate, polystyrene, polyethylene glycol, polyurethane, and combinations thereof.

17. The method of claim 10, further comprising:

obtaining non-coated nanoparticles;

including in a permeable reactive barrier the non-coated nanoparticles;

including in the permeable reactive barrier the polymer-coated nanoparticles; and

applying to the permeable reactive barrier a removing agent, thereby removing the polymer coating from the polymer-coated nanoparticles at the end of the useful life of the non-coated nanoparticles, thereby extending the useful life of the permeable reactive barrier.

15. A method of using polymer-coated nanoparticles to treat a soil comprising a contaminant, comprising:

emulsifying the nanoparticles with an emulsifier selected from the group consisting of a surfactant, a cosolvent, and a mixture of a surfactant and a cosolvent, to form an emulsified treatment component;

blending a plant product selected from the group consisting of a plant oil, a plant extract, and a combination of a plant oil and a plant extract, to form a blended treatment component; and

introducing the emulsified treatment component and the blended treatment component into a subsurface of the soil or spreading the emulsified treatment component and the blended treatment component on the surface of the soil to create a reduction zone.

16. The method of claim 15, wherein the emulsified treatment component and the blended treatment component are simultaneously injected into the subsurface or simultaneously spread on the surface of the soil.