High early strength pozzolan cement blends

• US 7,972,432 B2
• Filed: 08/02/2010
• Issued: 07/05/2011
• Est. Priority Date: 10/10/2008
• Status: Active Grant

• Current Assignee: Roman Cement, LLC
• Original Assignee: Roman Cement, LLC
• Inventors: Guynn, John M., Hansen, Andrew S.
• Primary Examiner(s): MARCANTONI, PAUL D
• Application Number:
  US12/848,945
• Publication Number:
  US 20100313795A1
• Time in Patent Office: 337 Days
• Field of Search: 106/705, 106/713, 106/DIG.1
• US Class Current: 106/705
• CPC Class Codes: C04B 14/14 Minerals of vulcanic origin granite C04B14/048
• CPC Class Codes: C04B 18/08 Flue dust , i.e. fly ash
• CPC Class Codes: C04B 20/0076 characterised by the grain distribution
• CPC Class Codes: C04B 20/008 Micro- or nanosized fillers, e.g. micronised fillers with particle size smaller than that of the hydraulic binder colloidal silica C04B14/062 ; silica fume C04B18/146
• CPC Class Codes: C04B 2103/0088 Compounds chosen for their latent hydraulic characteristics, e.g. pozzuolanes
• CPC Class Codes: C04B 2103/10 Accelerators; Activators
• CPC Class Codes: C04B 2103/20 Retarders
• CPC Class Codes: C04B 2103/302 Water reducers
• CPC Class Codes: C04B 2103/44 Thickening, gelling or viscosity increasing agents
• CPC Class Codes: C04B 22/064 of the alkaline-earth metals
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 28/18 containing mixtures of the silica-lime type
• CPC Class Codes: C04B 7/02 Portland cement
• CPC Class Codes: Y02W 30/91 Use of waste materials as fillers for mortars or concrete
• CPC Class Codes: Y10S 106/01 Fly ash

Abstract

A high early strength pozzolan cement includes larger sized pozzolan particles blended with smaller sized hydraulic cement particles containing tricalcium silicate and/or dicalcium silicate (e.g., Portland cement). Excess calcium release from the hydraulic cement when mixed with water forms calcium hydroxide available for reaction with the pozzolan. The fineness of the hydraulic cement particles is substantially greater than the fineness of the pozzolan particles (e.g., about 1.25 to about 50 times greater). Reducing or eliminating coarse hydraulic cement particles that cannot fully hydrate but include unreacted cores reduces or eliminates wasted cement normally found in concrete. Replacing some or all of the coarse cement particles with pozzolan particles provides a pozzolan cement composition having significantly lower water demand compared to the hydraulic cement by itself.

Claims

1. A pozzolan cement composition comprising:

a hydraulic cement fraction comprised of a distribution of differently sized hydraulic cement particles at least partially comprised of tricalcium silicate and/or dicalcium silicate that provide excess calcium hydroxide, when mixed with water, that is available for reaction with a pozzolan, the hydraulic cement fraction having a Blaine fineness greater than about 500 m²/kg; and

a pozzolan fraction comprised of a distribution of differently sized pozzolan particles that react with calcium hydroxide in the presence of water, including calcium hydroxide provided by the hydraulic cement particles when mixed with water, in order to form solid hydration products having cementitious properties, the pozzolan fraction having a Blaine fineness that is less than the Blaine fineness of the hydraulic cement fraction,

wherein a majority of the combined hydraulic cement and pozzolan particles above 20 μ

m are pozzolan particles and a majority of the combined hydraulic cement and pozzolan particles below 20 μ

m are hydraulic cement particles.

2. A pozzolan cement composition as in claim 1, wherein the Blaine fineness of the hydraulic cement fraction is about 1.25 times to about 50 times greater than the Blaine fineness of the pozzolan fraction.

3. A pozzolan cement composition as in claim 1, wherein the Blaine fineness of the hydraulic cement fraction is about 1.5 times to about 30 times greater than the Blaine fineness of the pozzolan fraction.

4. A pozzolan cement composition as in claim 1, wherein the Blaine fineness of the hydraulic cement fraction is about 1.75 times to about 20 times greater than the Blaine fineness of the pozzolan fraction.

5. A pozzolan cement composition as in claim 1, wherein the Blaine fineness of the hydraulic cement fraction is about 2 times to about 15 times greater than the Blaine fineness of the pozzolan fraction.

6. A pozzolan cement composition as in claim 1, wherein the Blaine fineness of the hydraulic cement fraction is greater than about 650 m²/kg.

7. A pozzolan cement composition as in claim 1, wherein the Blaine fineness of the hydraulic cement fraction is greater than about 800 m²/kg.

8. A pozzolan cement composition as in claim 1, wherein the hydraulic cement fraction has a fineness so as to qualify as Type III Portland cement but with a slower set time and lower water demand as a result of being blended with the pozzolan fraction.

9. A pozzolan cement composition as in claim 1, wherein the pozzolan cement composition has a set time similar to that of Type I or Type II Portland cement according to ASTM C-150.

10. A pozzolan cement composition as in claim 1, wherein the Blaine fineness of the pozzolan fraction is less than about 325 m²/kg.

11. A pozzolan cement composition as in claim 1, wherein the Blaine fineness of the pozzolan fraction is less than about 300 m²/kg.

12. A pozzolan cement composition as in claim 1, wherein the hydraulic cement fraction and pozzolan fraction have a combined Blaine fineness in a range of about 280 m²/kg to about 600 m²/kg.

13. A pozzolan cement composition as in claim 1, wherein the hydraulic cement fraction and pozzolan fraction have a combined Blaine fineness fineness in a range of about 300 m²/kg to about 500 m²/kg.

14. A pozzolan cement composition as in claim 1, wherein the hydraulic cement particles have a D₈₅ less than about 20 μ

m, and wherein at least about 65% of the combined pozzolan and cement particles larger than about 20 μ

m comprise pozzolan particles and less than about 35% of the combined pozzolan and cement particles larger than about 20 μ

m comprise hydraulic cement particles.

15. A pozzolan cement composition as in claim 1, wherein the hydraulic cement particles having a D₉₀ less than about 20 μ

m, and wherein at least about 75% of the combined pozzolan and cement particles larger than about 20 μ

m comprise pozzolan particles and less than about 25% of the combined pozzolan and cement particles larger than about 20 μ

m comprise hydraulic cement particles.

16. A pozzolan cement composition as in claim 1, wherein the hydraulic cement particles have a D₉₀ less than about 15 μ

m, and wherein at least about 75% of the combined pozzolan and cement particles larger than about 15 μ

m comprise pozzolan particles and less than about 25% of the combined pozzolan and cement particles larger than about 15 μ

m comprise hydraulic cement particles.

17. A pozzolan cement composition as in claim 1, wherein the pozzolan particles comprise at least 30% by volume of combined pozzolan and hydraulic cement particles and the hydraulic cement particles comprise up to 70% by volume of the combined pozzolan and hydraulic cement particles.

18. A pozzolan cement composition as in claim 1, wherein the hydraulic cement fraction and pozzolan fraction form a dry blend of particles with no added water.

19. A pozzolan cement composition as in claim 1, wherein the pozzolan particles comprise at least one component selected from the group consisting, pulverized fuel ash, of ash produced from coal combustion, class F fly ash, class C fly ash, ground slag, materials of volcanic origin, trass, and diatomaceous earth, burnt clays, burnt shales, spent oil shales, burnt gaize, and burnt moler.

20. A pozzolan cement composition as in claim 1, wherein the dry blend further includes at least one component selected from the group consisting of fine aggregates, coarse aggregates, inert fillers, lime, lye, water reducing admixtures, accelerants, retardants, hydration stabilizers, and rheology-modifying agents.

21. A pozzolan cement composition as in claim 1, further comprising water so as to form a fresh cementitious composition.

22. A pozzolan cement composition as in claim 21, wherein the fresh cementitious composition is fresh concrete that further includes fine aggregate, coarse aggregate and at least one of inert filler, lime, lye, water reducing admixture, accelerant, retardant, hydration stabilizer, or rheology-modifying agent.

23. A pozzolan cement composition as in claim 22, wherein the fresh concrete has a Vicat initial set time in a range of about 45-375 minutes and a maximum autoclave expansion of about 0.8%.

24. A method of manufacturing the pozzolan cement composition of claim 1, comprising:

obtaining the hydraulic cement fraction;

obtaining the pozzolan fraction; and

combining the hydraulic cement fraction and the pozzolan fraction to yield the pozzolan cement composition.

25. A method as in claim 24, wherein the hydraulic cement fraction is combined with the pozzolan fraction in a manner so as to yield a dry blend of particles.

26. A method as in claim 25, further comprising combining the dry blend of particles with water to form a fresh cementitious composition selected from the group consisting of concrete, mortar, grout, and molding compositions.

27. A method as in claim 26, wherein forming the fresh cementitious composition includes adding fine aggregate, coarse aggregate and at least one of inert filler, lime, lye, water reducing admixture, accelerant, retardant, hydration stabilizer, or rheology-modifying agent to form fresh concrete.

28. A method as in claim 24, wherein the hydraulic cement fraction is combined with the pozzolan fraction and water in situ to yield a fresh cementitious composition selected from the group consisting of concrete, mortar, grout, and molding compositions.

29. A method as in claim 28, wherein forming the fresh cementitious composition includes adding fine aggregate, coarse aggregate and at least one of inert filler, lime, lye, water reducing admixture, accelerant, retardant, hydration stabilizer, or rheology-modifying agent to form fresh concrete.

30. A method as in claim 28, further comprising pre-treating at least a portion of the pozzolan fraction with an aqueous base prior to exposing the hydraulic cement fraction to water.

31. A pozzolan cement composition comprising:

a Portland cement fraction comprised of a distribution of differently sized Portland cement particles having a chemistry and a Blaine fineness so that the Portland cement fraction either qualifies as a Type III Portland cement under ASTM C-150 or is finer than a Type III Portland cement under ASTM C-150; and

a pozzolan fraction comprised of a distribution of differently sized pozzolan particles blended but not interground with the Portland cement particles and that react with calcium hydroxide in the presence of water, including calcium hydroxide provided by the hydraulic cement particles when mixed with water, in order to form solid hydration products having cementitious properties, the pozzolan fraction having a Blaine fineness,

wherein the Blaine fineness of the Portland cement fraction is about 1.25 times to about 50 times greater than the Blaine fineness of the pozzolan fraction,

wherein a majority of the combined hydraulic cement and pozzolan particles above 20 μ

m are pozzolan particles and a majority of the combined hydraulic cement and pozzolan particles below 20 μ

m are hydraulic cement particles.

32. A pozzolan cement composition as in claim 31, wherein the Blaine fineness of the Portland cement fraction is greater than about 500 m²/kg.

33. A pozzolan cement composition as in claim 31, wherein the Blaine fineness of the Portland cement fraction is greater than about 650 m²/kg.

34. A pozzolan cement composition as in claim 31, wherein the Blaine fineness of the Portland cement fraction is greater than about 800 m²/kg.

35. A pozzolan cement composition as in claim 31, wherein the pozzolan fraction comprises at least one of class F fly ash, class C fly ash, ground slag, or natural pozzolan.

36. A pozzolan cement composition as in claim 31, further comprising water, fine aggregate, coarse aggregate and at least one of inert filler, lime, lye, water reducing admixture, accelerant, retardant, hydration stabilizer, or rheology-modifying agent so as to form fresh concrete.

37. A pozzolan cement composition as in claim 36, wherein the fresh concrete has a Vicat initial set time in a range of about 45 to 375 minutes and a maximum autoclave expansion of about 0.8%.

38. A method of manufacturing the pozzolan cement composition of claim 31, comprising:

obtaining the Portland cement fraction;

obtaining the pozzolan fraction; and

combining the Portland cement fraction and the pozzolan fraction to yield the pozzolan cement composition.

39. A method as in claim 38, further comprising adding water to form a fresh cementitious composition selected from the group consisting of concrete, mortar, grout, and molding compositions.

40. A method as in claim 39, wherein forming the fresh cementitious composition includes adding fine aggregate, coarse aggregate and at least one of inert filler, lime, lye, water reducing admixture, accelerant, retardant, hydration stabilizer, or rheology-modifying agent to form fresh concrete.

41. A method of manufacturing a pozzolan cement composition, comprising:

obtaining a hydraulic cement fraction comprised of a distribution of differently sized hydraulic cement particles at least partially comprised of tricalcium silicate and/or dicalcium silicate that provide excess calcium hydroxide, when mixed with water, that is available for reaction with a pozzolan, the hydraulic cement fraction having a Blaine fineness greater than about 500 m²/kg and/or having a chemistry and a Blaine fineness so that it qualifies as a Type III Portland cement under ASTM C-150;

obtaining a pozzolan fraction that is initially separate from the hydraulic cement fraction and comprised of a distribution of differently sized pozzolan particles that react with calcium hydroxide in the presence of water in order to form solid hydration products having cementitious properties, the pozzolan fraction having a Blaine fineness that is less than the Blaine fineness of the hydraulic cement fraction, the Blaine fineness of the Portland cement fraction being about 1.25 times to about 50 times greater than the Blaine fineness of the pozzolan fraction, a majority of the combined hydraulic cement and pozzolan particles above 20 μ

m being pozzolan particles and a majority of the combined hydraulic cement and pozzolan particles below 20 μ

m being hydraulic cement particles; and

combining the hydraulic cement fraction and the pozzolan fraction without intergrinding to yield the pozzolan cement composition.

42. A method as in claim 41, wherein the hydraulic cement fraction is combined with the pozzolan fraction in a manner so as to yield a dry blend of particles.

43. A method as in claim 42, further comprising combining the dry blend of particles with water to form a fresh cementitious composition selected from the group consisting of concrete, mortar, grout, and molding compositions.

44. A method as in claim 43, wherein forming the fresh cementitious composition includes adding fine aggregate, coarse aggregate and at least one of inert filler, lime, lye, water reducing admixture, accelerant, retardant, hydration stabilizer, or rheology-modifying agent to form fresh concrete.

45. A method as in claim 43, further comprising placing the fresh cementitious composition and then allowing it to harden.

46. A method as in claim 41, wherein the hydraulic cement fraction is combined with the pozzolan fraction and water in situ to yield a fresh cementitious composition selected from the group consisting of concrete, mortar, grout, and molding compositions.

47. A method as in claim 46, wherein forming the fresh cementitious composition includes adding fine aggregate, coarse aggregate and at least one of inert filler, lime, lye, water reducing admixture, accelerant, retardant, hydration stabilizer, or rheology-modifying agent to form fresh concrete.

48. A method as in claim 47, further comprising placing the fresh concrete and then allowing it to harden.

49. A method as in claim 41, wherein the hydraulic cement fraction and the pozzolan fraction are blended together at a ready mix concrete plant.