Phase change memory device and method of fabricating the same
First Claim
1. A phase change memory device, comprising:
- a phase change material layer formed of Ge2Sb2+xTe5 (x>
0) which is a germanium (Ge)-antimony (Sb)-tellurium (Te)-based material, whereinan excess (x) of antimony is added to Ge2Sb2Te5 to compose the Ge2Sb2+xTe5,the excess ranges from 0.22 to 0.32, andthe phase change material layer directly transitions from an amorphous phase to a stable hcp crystalline phase without transitioning through a metastable fcc crystalline phase.
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Abstract
A phase change memory device and a method of fabricating the same are provided. A phase change material layer of the phase change memory device is formed of germanium (Ge)-antimony (Sb)-Tellurium (Te)-based Ge2Sb2+xTe5 (0.12≦x≦0.32), so that the crystalline state is determined as a stable single phase, not a mixed phase of a metastable phase and a stable phase, in phase transition between crystalline and amorphous states of a phase change material, and the phase transition according to increasing temperature directly transitions to the single stable phase from the amorphous state. As a result, set operation stability and distribution characteristics of set state resistances of the phase change memory device can be significantly enhanced, and an amorphous resistance can be maintained for a long time at a high temperature, i.e., around crystallization temperature, and thus reset operation stability and rewrite operation stability of the phase change memory device can be significantly enhanced.
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Citations
19 Claims
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1. A phase change memory device, comprising:
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a phase change material layer formed of Ge2Sb2+xTe5 (x>
0) which is a germanium (Ge)-antimony (Sb)-tellurium (Te)-based material, whereinan excess (x) of antimony is added to Ge2Sb2Te5 to compose the Ge2Sb2+xTe5, the excess ranges from 0.22 to 0.32, and the phase change material layer directly transitions from an amorphous phase to a stable hcp crystalline phase without transitioning through a metastable fcc crystalline phase. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8)
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9. A method of fabricating a phase change memory device, comprising:
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forming a phase change material layer using Ge2Sb2+xTe5 (x>
0) which is a germanium (Ge)-antimony (Sb)-tellurium (Te)-based material, whereinan excess (x) of antimony is added to Ge2Sb2Te5 to compose the Ge2Sb2+xTe5, the excess ranges from 0.22 to 0.32 and the phase change material layer directly transitions from an amorphous phase to a stable hcp crystalline phase without transitioning through a metastable fcc crystalline phase. - View Dependent Claims (10, 11, 12, 13, 14, 15, 16, 17, 18)
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19. A phase change memory device, comprising:
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a phase change material layer formed of Ge2Sb2+xTe5 (0.27≦
x≦
0.32) which is a germanium (Ge)-antimony (Sb)-tellurium (Te)-based material, whereinthe phase change material layer directly transitions from an amorphous phase to a stable hcp crystalline phase without transitioning through a metastable fcc crystalline phase.
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Specification