Fabrication of dichroic guest-host polarizer

• US 7,978,302 B2
• Filed: 06/23/2006
• Issued: 07/12/2011
• Est. Priority Date: 06/27/2005
• Status: Active Grant

• Current Assignee: Sumitomo Chemical Company Limited
• Original Assignee: Sumitomo Chemical Company Limited
• Inventors: Broer, Dirk Jan, Peeters, Emiel
• Primary Examiner(s): Hahm; Sarah
• Application Number:
  US11/993,594
• Publication Number:
  US 20100045900A1
• Time in Patent Office: 1,845 Days
• Field of Search: None
• US Class Current: 349/194
• CPC Class Codes: C09K 19/54 Additives having no specific mesophase characterised by their chemical composition
• CPC Class Codes: C09K 19/60 Pleochroic dyes
• CPC Class Codes: C09K 2019/526 Gelling agents
• CPC Class Codes: G02B 5/3016 involving passive liquid crystal elements optical properties of liquid crystals G02F1/0063; polarising elements associated with active liquid crystal devices G02F1/133528

Abstract

A method for the manufacture of a polarizer is provided. The method comprises providing a liquid crystal composition comprising a liquid crystal host and a viscosity enhancer; providing a thin film of said composition on a substrate; orienting said liquid crystal host to obtain an aligned film in a first liquid crystal mesophase, wherein the liquid crystal host is aligned planar to said substrate; gelating said viscosity enhancer to congeal said film; and obtaining a second liquid crystal state in said congealed film. By the use of a viscosity enhancer in the composition, homeotropic alignment of the liquid crystal host can be suppressed.

Claims

1. A method for the manufacture of a polarizer, comprising:

providing a liquid crystal composition comprising a liquid crystal host and a viscosity enhancer;

providing a thin film of said composition on a substrate;

orienting said liquid crystal host to obtain an aligned film in a first liquid crystal mesophase, wherein the liquid crystal host is aligned planar to said substrate;

gelating said viscosity enhancer to congeal said film; and

obtaining a second liquid crystal state in said congealed film.

2. The method according to claim 1, wherein said liquid crystal host is polymerizable and said method further comprises polymerizing said liquid crystal host in said second liquid crystal state in said congealed film.

3. The method according to claim 1, wherein a dichroic light-absorbing guest is dispersed in said liquid crystal composition.

4. The method according to claim 1, wherein said viscosity enhancer forms fibrillar aggregates in said film upon gelation.

5. The method according to claim 1, wherein said viscosity enhancer is an organic gelator.

6. The method according to claim 5, wherein said organic gelator is chosen from the group consisting of fatty acid derivatives, steroid derivatives, anthryl derivates, gelators containing steroidal and condensed aromatic rings, azobenzene steroid-based gelators, amino-acid type organogelators, organometallic compounds, macrocyclic gelators, sorbitol and polyol derivatives, cellobiose octa(decanoat), n-alkanes, partially fluorinated n-alkanes, two-component systems and cyclic and linear bis-urea compounds and combinations of two or more thereof.

7. The method according to claim 1, wherein the orientation in said first liquid crystal state is or corresponds to a nematic phase or a smectic phase Sy, wherein Y is A or C.

8. The method according to claim 1, wherein said first liquid crystal state is obtained at a temperature above the gelating temperature for said viscosity enhancer.

9. The method according to claim 1, wherein the orientation in said second liquid crystal state is or corresponds to a smectic phase S_x, wherein X is not A or C.

10. The method according to claim 1, wherein said second liquid crystal state is obtained at a temperature below the gelating temperature for said viscosity enhancer.

11. The method according to claim 1, wherein said liquid crystal host comprises a polymerizable liquid crystal of formula (I):

U—

V—

W—

X—

Y—

X′

—

Y′

—

X″

—

W′

—

V′

—

U′

 

 

(I)

wherein

X, X′ and

X″

independently is substituted or un-substituted Ph or Cyc, where Ph is a 1,4-phenylene unit and Cyc is a trans-1,4-cyclohexene unit;

Y and Y′

independently is —

CH₂CH₂—

, —

CH₂O—

, —

OCH₂—

, —

OCO—

, —

COO—

, —

N═

N—

, —

C═

C—

, —

C≡

C—

—

C═

N—

;

U and U′

independently is a polymerizable group, or U is a polymerizable group and U′

═

H, or U═

H and U′

is a polymerizable group;

V and V′

independently is a spacer; and

W and W′

independently is a direct bond, —

O—

, —

S—

, —

COO—

, or —

OCO—

.

12. The method according to claim 1, wherein said dichroic light-absorbing guest comprises an azo dye.

13. A polarizer obtained by the method according to any of the claims 1 to 12.

14. A polarizer obtained by the method according to claim 1, said polarizer comprising an oriented film including an oriented liquid crystal host, a dichroic light-absorbing guest dispersed in and oriented with said host, and a gelated viscosity enhancer.

15. The polarizer according to claim 14, wherein said oriented liquid crystal host is in planar alignment.

16. The polarizer according to claim 14, wherein said viscosity enhancer forms fibrillar aggregates in said film.

17. The polarizer according to claim 14, wherein said viscosity enhancer is an organic gelator.

18. The polarizer according to claim 17, wherein said organic gelator is selected from the group consisting of fatty acid derivatives, steroid derivatives, anthryl derivates, gelators containing steroidal and condensed aromatic rings, azobenzene steroid-based gelators, amino-acid type organogelators, organometallic compounds, macrocyclic gelators, sorbitol and polyol derivatives, cellobiose octa(decanoat), n-alkanes, partially fluorinated n-alkanes, two-component systems and cyclic and linear bis-urea compounds and combinations of two or more thereof

19. The polarizer according to claim 14, wherein the orientation of said oriented liquid crystal host is or corresponds to the orientation of a smectic phase S_x, wherein X is not A or C.

20. The polarizer according to claim 14, wherein said oriented liquid crystal host is a polymerized liquid crystal host.

21. The polarizer according to claim 20 wherein said polymerized liquid crystal host comprises polymerized liquid crystals of formula (I)

U—

V—

W—

X—

Y—

X′

—

Y′

—

X″

—

W′

—

V′

—

U′

 

 

(I)

wherein

X, X′ and

X″

independently is substituted or un-substituted Ph or Cyc, where Ph is a 1,4-phenylene unit and Cyc is a trans-1,4-cyclohexene unit;

Y and Y′

independently is —

CH₂CH₂—

, —

CH₂O—

, —

OCH₂—

, —

OCO—

, —

COO—

, —

N═

N—

,—

C═

C—

,—

C≡

C—

, —

C═

N—

;

U and U′

independently is a polymerizable group, or U is a polymerizable group and U′

═

H, or U═

H and U′

is a polymerizable group;

V and V′

independently is a spacer; and

W and W′

independently is a direct bond, —

O—

, —

S—

, —

COO—

, or —

OCO—

.

22. The polarizer according to claim 14, wherein said dichroic light-absorbing guest comprises an azo dye.

23. A composition for use in the manufacture of the polarizer according to claim 1, comprising a liquid crystal host, a dichroic light-absorbing guest and a viscosity enhancer.

24. The according to claim 23, wherein said viscosity enhancer forms fibrillar aggregates in said composition upon gelation.

25. The composition according to claim 23, wherein said viscosity enhancing agent is an organic gelator.

26. The composition according to claim 25, wherein said organic gelator is selected from the group consisting of fatty acid derivatives, steroid derivatives, anthryl derivates, gelators containing steroidal and condensed aromatic rings, azobenzene steroid-based gelators, amino-acid type organogelators, organometallic compounds, macrocyclic gelators, sorbitol and polyol derivatives, cellobiose octa(decanoat), n-alkanes, partially fluorinated n-alkanes, two-component systems and cyclic and linear bis-urea compounds and combinations of two or more thereof.

27. The composition according to claim 25, wherein the gelation temperature of said organic gelator is below the phase transition temperature of the liquid crystal composition from isotropic phase to a first liquid crystal phase and above the transition temperature of the liquid crystal composition from a first liquid crystal phase to a second liquid crystal phase, where said first liquid crystal phase is nematic or smectic Sy, said second liquid crystal phase is S_x, Y is A or C and X is not A and not C.

28. The composition according to claim 23, wherein said liquid crystal host is a polymerizable liquid crystal host.

29. The according to claim 23, wherein said liquid crystal host comprises a polymerizable liquid crystal of formula (I)

U—

V—

W—

X—

Y—

X′

—

Y′

—

X″

—

W′

—

V′

—

U′

 

 

(I)

wherein

X, X′ and

X″

independently is substituted or un-substituted Ph or Cyc, where Ph is a 1,4-phenylene unit and Cyc is a trans-1,4-cyclohexene unit;

Y and Y′

independently is —

CH₂CH₂—

, —

CH₂O—

, —

OCH₂—

, —

OCO—

, —

COO—

, —

N═

N—

, —

C═

C—

, —

C≡

C—

, —

C═

N—

;

U and U′

independently is a polymerizable group, or U is a polymerizable group and U′

═

H, or U═

H and U′

is a polymerizable group;

V and V′

independently is a spacer; and

W and W′

independently is a direct bond, —

O—

, —

S—

, —

COO—

, or —

OCO—

.

30. The composition according to claim 23, wherein said dichroic light-absorbing guest comprises an azo dye.

31. A liquid crystal display comprising a polarizer according to claim 13.