Robust window for infrared energy

• US 7,978,402 B2
• Filed: 06/28/2007
• Issued: 07/12/2011
• Est. Priority Date: 06/28/2007
• Status: Active Grant

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Sweeney, Sean Michael, Yosenick, Timothy James, Zhong, Dalong, Venkataramani, Venkat Subramaniam, Loureiro, Sergio Paulo Martins, Manoharan, Mohan, Brun, Milivoj Konstantin
• Primary Examiner(s): NGUYEN, THONG Q
• Application Number:
  US11/769,913
• Publication Number:
  US 20100027105A1
• Time in Patent Office: 1,475 Days
• Field of Search: 359/599, 359350-361, 359577-590
• US Class Current: 359/350
• CPC Class Codes: C04B 2111/00405 Materials with a gradually increasing or decreasing concentration of ingredients or property from one layer to another
• CPC Class Codes: C04B 2111/805 Transparent material
• CPC Class Codes: C04B 35/01 based on oxide ceramics
• CPC Class Codes: C04B 41/009 characterised by the material treated
• CPC Class Codes: C04B 41/4529 applied from the gas phase
• CPC Class Codes: C04B 41/5031 Alumina
• CPC Class Codes: C04B 41/5059 Silicon carbide
• CPC Class Codes: C04B 41/87 Ceramics
• CPC Class Codes: G02B 1/105 Protective coatings
• CPC Class Codes: G02B 1/14 Protective coatings, e.g. hard coatings
• CPC Class Codes: G02B 5/208 for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation

Abstract

Articles transparent to infrared radiation and resistant to impact and wear are provided. The article comprises a substrate and a composite coating disposed over the substrate and extending from an interface with the substrate to an external surface. The composite coating comprises a first phase and a second phase. The second phase has a higher resistance to erosive wear than the first phase. The coating comprises a compositional gradient proceeding from a first composition at the interface of the coating with the substrate to a second composition at the external surface, the first composition comprising a higher concentration of the first phase than that of the second composition.

Claims

1. An article comprising:

a substrate; and

a composite coating disposed over the substrate and extending from an interface with the substrate to an external surface, the composite coating comprising a first phase and a second phase, the second phase having a higher resistance to erosive wear than the first phase;

wherein the coating comprises a compositional gradient proceeding from a first composition at the interface of the coating with the substrate to a second composition at the external surface, the first composition comprising a higher concentration of the first phase than that of the second composition;

wherein the first phase has at least one property selected from the group consisting of

a) a coefficient of thermal expansion (CTE) that is within about plus or minus 3 parts per million per degree centigrade of a CTE of the substrate, and

b) an index of refraction that is within a range from as high as about 0.1 plus the index of refraction of the substrate to as low as about the square root of the index of refraction of the substrate;

wherein the coating and the substrate are capable of transmitting infrared radiation.

2. The article of claim 1, wherein the second composition comprises up to about 15 volume percent of the first phase and at least about 85 volume percent of the second phase.

3. The article of claim 1, wherein the second composition comprises up to about 10 volume percent of the first phase and at least about 90 volume percent of the second phase.

4. The article of claim 1, wherein the first composition comprises at least about 85 volume percent of the first phase and up to about 15 volume percent of the second phase.

5. The article of claim 4, wherein the second composition comprises up to about 15 volume percent of the first phase and at least about 85 volume percent of the second phase.

6. The article of claim 1, wherein the first phase comprises a material selected from the group consisting of magnesium aluminate spinel, yttrium aluminate garnet, cubic zirconium oxide, yttrium oxide, magnesium oxide, alpha aluminum oxide, aluminum oxynitride, and rare earth oxides.

7. The article of claim 1, wherein the second phase comprises a material selected from the group consisting of cubic boron nitride, silicon carbide, silicon nitride, diamond-like carbon, diamond, and boron phosphide.

8. The article of claim 1, wherein the substrate comprises a material selected from the group consisting of glass, magnesium aluminate spinel, yttrium aluminate garnet, cubic zirconium oxide, yttrium oxide, magnesium oxide, alpha aluminum oxide, aluminum oxynitride, and rare earth oxides.

9. The article of claim 1, wherein the substrate comprises a composite material.

10. The article of claim 9, wherein the composite comprises a matrix material and particles of a nano-dispersoid, wherein the particles of the nano-dispersoid are less than about 100 nm in at least one dimension.

11. The article of claim 10, wherein the matrix material is selected from the group consisting of magnesium aluminate spinet, yttrium aluminate garnet, cubic zirconium oxide, yttrium oxide, magnesium oxide, alpha aluminum oxide, aluminum oxynitride, rare earth oxides, and combinations thereof.

12. The article of claim 10, wherein the particles of the nano-dispersoid comprise a material selected from the group consisting of cubic boron nitride, silicon carbide, and silicon nitride.

13. The article of claim 1, wherein the second phase is present as a plurality of particles dispersed in the first phase, wherein the particles of the second phase are less than about 100 nm in at least one dimension.

14. The article of claim 1, wherein the coating has a thickness in the range from about 0.5 micrometers to about 200 micrometers.

15. The article of claim 14, wherein the thickness is in the range from about 2 micrometers to about 30 micrometers.

16. The article of claim 1, wherein the article is an infrared dome or a nose cone.

17. The article of claim 1, wherein the article is a window or a lens.

18. The article of claim 1, wherein the coating and substrate together cause scattering of up to about 5 percent of incident infrared radiation.

19. The article of claim 1, wherein the coating and substrate together cause scattering of up to about 0.5 percent of incident infrared radiation.

20. The article of claim 1, wherein the coating and substrate have a combined infrared absorption coefficient of less than about 0.5 per centimeter.

21. The article of claim 1, wherein the coating and substrate have a combined infrared absorption coefficient of less than about 0.1 per centimeter.

22. An article comprising:

a composite substrate comprising a matrix material and particles of a nano-dispersoid dispersed within the matrix material, wherein the particles of the nano-dispersoid are less than about 100 nm in at least one dimension; and

a composite coating disposed over the substrate and extending from an interface with the substrate to an external surface, the composite coating comprising a first phase and a second phase, the second phase having a higher resistance to erosive wear than the first phase;

wherein the coating comprises a compositional gradient proceeding from a first composition at the interface of the coating with the substrate to a second composition at the external surface, the first composition comprising a higher concentration of the first phase than that of the second composition;

wherein the first phase comprises a material selected from the group consisting of magnesium aluminate spinel, yttrium aluminate garnet, cubic zirconium oxide, yttrium oxide, magnesium oxide, alpha aluminum oxide, aluminum oxynitride, and rare earth oxides;

wherein the second phase comprises a material selected from the group consisting of cubic boron nitride, silicon carbide, silicon nitride, diamond-like carbon, diamond, and boron phosphide;

wherein the coating and substrate together cause scattering of up to about 5 percent of incident infrared radiation.

23. The article of claim 22, wherein the matrix material is selected from the group consisting of MgAl₂O₄, Y₃Al₅O₁₂, cubic-ZrO₂, Y₂O₃, MgO, and combinations thereof, and wherein the particles of the nano-dispersoid comprise a material selected from the group consisting of cubic boron nitride, silicon carbide, and silicon nitride.