Signal activated decontaminating coating

• US 7,993,495 B2
• Filed: 06/21/2006
• Issued: 08/09/2011
• Est. Priority Date: 06/21/2005
• Status: Expired due to Fees

• Current Assignee: Crosslink Polymer Research
• Original Assignee: Crosslink Polymer Research
• Inventors: Bashkin, James K., Ding, Yiwei, Kinlen, Patrick J., Hou, Shifeng
• Primary Examiner(s): Mayes; Melvin C
• Assistant Examiner(s): DAVIS, SHENG HAN
• Application Number:
  US11/471,877
• Publication Number:
  US 20070114121A1
• Time in Patent Office: 1,875 Days
• Field of Search: None
• US Class Current: 204/175
• CPC Class Codes: A61L 2/03 Electric current
• CPC Class Codes: A61L 2/16 using chemical substances
• CPC Class Codes: A61L 2/232 layered or coated
• CPC Class Codes: A62D 2101/02 Chemical warfare substances, e.g. cholinesterase inhibitors
• CPC Class Codes: A62D 2203/10 Apparatus specially adapted for treating harmful chemical agents; Details thereof
• CPC Class Codes: A62D 3/38 by oxidation; by combustion
• CPC Class Codes: B01J 2231/70 Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
• CPC Class Codes: B01J 2531/72 Manganese
• CPC Class Codes: B01J 2531/842 Iron
• CPC Class Codes: B01J 31/006 comprising organic radicals, e.g. TEMPO
• CPC Class Codes: B01J 31/0208 Ketones or ketals
• CPC Class Codes: B01J 31/184 mixed aromatic/aliphatic ring systems, e.g. indoline
• CPC Class Codes: C01B 15/00 Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
• CPC Class Codes: C01B 15/01 Hydrogen peroxide
• CPC Class Codes: C01B 15/0295 by electrical discharge
• CPC Class Codes: C09D 105/04 Alginic acid; Derivatives thereof

Abstract

A method is provided for decontaminating a surface that is susceptible to contamination by a contaminant by applying to the surface a coating which produces a decontaminating agent for the contaminant in response to a signal, connecting the electroactive coating to a source of a signal, and when the surface is contaminated, applying the signal to the electroactive coating, thereby producing one or more decontaminating agents which neutralize or destroy the contaminant. Coatings for practicing the method and articles that have been protected by the novel coatings are also provided.

Claims

1. A coating for a surface, wherein the coating comprises

a peroxide activating catalyst in an electrically or ionically conductive durable matrix, the durable matrix comprising a polymer layer or a gel where the catalyst is chemically linked to the polymer layer or gel and contains water and/or oxygen;

and

a signal activated peroxide system comprising a positive electrode and a negative electrode which are interconnected by the electrically or ionically conductive durable matrix.

2. The coating according to claim 1, wherein the durable matrix comprises a material that is water insoluble and is sufficiently adherent to the surface to remain on the surface during normal usage.

3. The coating according to claim 1, wherein signal activated peroxide producing system produces hydrogen peroxide.

4. The coating according to claim 1, wherein the system further comprises a positive electrode lead that interconnects the positive electrode with the positive pole of a source of an electrical potential and a negative electrode lead that interconnects the negative electrode with the negative pole of a source of an electrical potential.

5. The coating according to claim 4, further comprising a switch located in the positive electrode lead or the negative electrode lead and which can control whether an electrical potential is applied to the electrodes.

6. The coating according to claim 1, wherein the signal activated peroxide producing system further comprises a mediator which is involved in the transfer of electrons and hydrogen ions to oxygen in the formation of hydrogen peroxide.

7. The coating according to claim 6, wherein the mediator comprises a compound that can be reversibly oxidized and reduced and can transfer hydrogen ions and electrons in a chemical reaction.

8. The coating according to claim 7, wherein the mediator comprises at least one compound that is selected from the group consisting of quinones, anthraquinones, and mixtures thereof.

9. The coating according to claim 1, wherein peroxide activating catalyst comprises at least one compound that is selected from the group consisting of complexes of ethylenediaminetetraacetic acid with metals, EDTA/Fe complexes, tetraaminomacrocyclic ligand complexes with metals, tetraaminomacrocylic ligand/Fe complexes, manganese gluconate, sodium hypochlorite, N-[4-(triethylammoniomethyl)benzoyl]-caprolactam chloride, nonanoyloxybenzene sulfonate, porphyrins, phthalocyanines, ruthenium oxide, indium oxide, and quinones.

10. The coating according to claim 1, wherein the electrode at which hydrogen peroxide formation occurs comprises a material that is selected from metals, platinum, gold, metal oxides, indium tin oxide, conductive metal salts, carbon, carbon/metal composites, intrinsically conductive polymers, materials that include carbon nanotubes, and mixtures of any of these materials.

11. The coating according to claim 2, wherein the coating comprises a gel structure.

12. The coating according to claim 2, wherein the coating is sufficiently permeable to activated hydrogen peroxide to permit the diffusion of activated hydrogen peroxide to a surface of the coating, whereby the activated hydrogen can contact a contaminant that is present on the surface.

13. The coating according to claim 1, comprising:

a positive electrode and a negative electrode;

which are interconnected by

a water insoluble matrix which is electrically conductive or ionically conductive;

a mediator that is selected from quinone or anthraquinone and which is present in the matrix or bound to an electrode;

a peroxide activating catalyst that is selected from EDTA/Fe complex or tetraaminomacrocylic ligand/metal complex; and

electrode leads for interconnecting the positive electrode and the negative electrode with a source of electrical potential.