Gas diffusion anode and CO2 cathode electrolyte system

• US 7,993,500 B2
• Filed: 08/13/2009
• Issued: 08/09/2011
• Est. Priority Date: 07/16/2008
• Status: Active Grant

• Current Assignee: Eleryc Incorporated
• Original Assignee: Calera Corporation
• Inventors: Kostowskyj, Michael, Decker, Valentin, Knott, Nigel Antony, Farsad, Kasra, Gilliam, Ryan J., Boggs, Bryan
• Primary Examiner(s): Neckel; Alexa D.
• Assistant Examiner(s): Smith; Nicholas A.
• Application Number:
  US12/541,055
• Publication Number:
  US 20100140103A1
• Time in Patent Office: 726 Days
• Field of Search: 204/263, 205/637
• US Class Current: 204/263
• CPC Class Codes: C02F 1/46109 Electrodes
• CPC Class Codes: C02F 1/68 by addition of specified substances, e.g. trace elements, for ameliorating potable water medicinal water A61K
• CPC Class Codes: C02F 2001/46166 Gas diffusion electrodes
• CPC Class Codes: C02F 2201/46115 Electrolytic cell with membranes or diaphragms
• CPC Class Codes: C02F 2201/4613 Inversing polarity
• CPC Class Codes: C02F 2201/46135 Voltage
• CPC Class Codes: C02F 2201/46185 Recycling the cathodic or anodic feed
• CPC Class Codes: C02F 2209/06 pH
• CPC Class Codes: C02F 2301/046 Recirculation with an external loop
• CPC Class Codes: C25B 1/00 Electrolytic production of inorganic compounds or non-metals
• CPC Class Codes: C25B 1/02 Hydrogen or oxygen
• CPC Class Codes: C25B 1/04 by electrolysis of water
• CPC Class Codes: C25B 1/14 Alkali metal compounds
• CPC Class Codes: C25B 1/16 Hydroxides by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34
• CPC Class Codes: C25B 1/26 Chlorine; Compounds thereof by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

A low-voltage, low-energy electrochemical system and method of removing protons and/or producing a base solution using a gas diffusion anode and a cathode electrolyte comprising dissolved carbon dioxide, while applying 2V or less across the anode and cathode.

Claims

1. An electrochemical system comprising:

a gas diffusion anode contacting an anode electrolyte wherein the anode is configured to produce protons from hydrogen gas;

a cathode contacting a cathode electrolyte comprising dissolved carbon dioxide and gaseous carbon dioxide, wherein the carbon dioxide is obtained from sources comprising combustion gas of fossil fuelled electrical power generating plant, cement plant, ore processing plant, or combination thereof; and

a gas delivery system configured to deliver hydrogen gas produced at the cathode to the anode;

wherein the system is configured to not produce a gas at the anode and wherein the system is configured to produce an acid in the anode electrolyte on application of a voltage across the anode and cathode.

2. The system of claim 1, wherein the cathode is configured to produce hydroxide ions.

3. The system of claim 1, wherein the voltage is less than 2V.

4. The system of claim 1, wherein the system is configured to produce sodium hydroxide and/or sodium bicarbonate and/or sodium carbonate in the cathode electrolyte.

5. The system of claim 1, further comprising a partition that partitions the cathode electrolyte into a first cathode electrolyte portion and a second cathode electrolyte portion, wherein the second cathode electrolyte portion contacts the cathode and comprises dissolved carbon dioxide.

6. The system of claim 5, wherein the first cathode electrolyte portion comprises dissolved carbon dioxide and gaseous carbon dioxide.

7. The system of claim 6, wherein the partition is positioned to isolate gaseous carbon dioxide gas in the first cathode electrolyte portion from cathode electrolyte in the second cathode electrolyte portion.

8. The system of claim 7, comprising sodium hydroxide and/or sodium carbonate and/or sodium bicarbonate in the cathode electrolyte.

9. The system of claim 1, further comprising a carbon dioxide gas/liquid contactor configured to dissolve carbon dioxide in the cathode electrolyte.

10. The system of claim 9, further comprising a system configured to produce carbonates and/or bicarbonates and/or hydroxides by contacting the cathode electrolyte comprising carbon dioxide with divalent cations.

11. The system of claim 1, further comprising a carbon dioxide sequestration system operatively connected to receive the cathode electrolyte and mix the cathode electrolyte with divalent cations to precipitate a hydroxide, carbonate and/or bicarbonate.

12. The system of claim 11, wherein the precipitate comprises calcium hydroxide, magnesium hydroxide, calcium carbonate, magnesium carbonate, calcium bicarbonate, and/or magnesium bicarbonate.

13. The system of claim 1, further comprising a mineral dissolution system operatively connected to the anode electrolyte wherein the mineral dissolution system comprises means for dissolving a mineral with the acid in the anode electrolyte.

14. The system of claim 1, further comprising a desalination system operatively connected to the electrochemical system and configured to produce desalinated water from the anode electrolyte and/or cathode electrolyte.

15. An electrochemical method comprising:

contacting an anode electrolyte with a gas diffusion anode;

contacting a cathode electrolyte with a cathode, wherein the cathode electrolyte comprises dissolved carbon dioxide and gaseous carbon dioxide;

dissolving the gaseous carbon dioxide into the cathode electrolyte wherein the carbon dioxide is obtained from sources comprising combustion gas of fossil fuelled electrical power generating plant, cement plant, ore processing plant, or combination thereof;

separating the anode electrolye from the cathode electrolyte using an ion exchange membrane;

applying a voltage across the gas diffusion anode and the cathode;

producing hydrogen gas at the cathode and directing the hydrogen gas to the gas diffusion anode;

oxidizing the hydrogen gas to protons at the anode without producing a gas at the anode; and

producing an acid in the anode electrolyte.

16. The method of claim 15, wherein the voltage is less than 2V.

17. The method of claim 15, further comprising producing hydroxide ions and/or carbonate ions and/or bicarbonate ions in the cathode electrolyte.

18. The method of claim 15, further comprising partitioning the cathode electrolyte into a first cathode electrolyte portion and a second cathode electrolyte portion, wherein the second cathode electrolyte portion contacts the cathode and comprises dissolved carbon dioxide and is devoid of gaseous carbon dioxide, and wherein the first cathode electrolyte portion comprises gaseous carbon dioxide.

19. The method of claim 18, wherein the partition is positioned to isolate the gaseous carbon dioxide in the first cathode electrolyte portion from the cathode electrolyte in the second cathode electrolyte portion such that the first cathode electrolyte portion contacts the gaseous carbon dioxide and the second cathode electrolyte portion is devoid of the gaseous carbon dioxide.

20. The method of claim 15, comprising

dissolving the gaseous carbon dioxide into the cathode electrolyte through a gas/liquid contactor;

contacting the cathode electrolyte with a divalent cation solution comprising calcium and/or magnesium ions; and

precipitating calcium and/or magnesium carbonate and/or bicarbonate from the cathode electrolyte.

21. The method of claim 15, further comprising connecting the anode electrolyte to a mineral dissolution system and dissolving the mineral with acid to produce a divalent cation solution.