Methods and devices for reducing hazardous air pollutants

• US 7,993,616 B2
• Filed: 09/18/2008
• Issued: 08/09/2011
• Est. Priority Date: 09/19/2007
• Status: Active Grant

• Current Assignee: C-Quest Technology LLC
• Original Assignee: C-Quest Technologies LLC
• Inventors: Comrie, Douglas C.
• Primary Examiner(s): Lorengo; Jerry
• Assistant Examiner(s): Wood; Jared
• Application Number:
  US12/233,144
• Publication Number:
  US 20090081093A1
• Time in Patent Office: 1,055 Days
• Field of Search: 951/29, 951/37, 423/244.01, 423/244.07, 423/242.1
• US Class Current: 423/220
• CPC Class Codes: B01D 2251/404 of calcium
• CPC Class Codes: B01D 2253/106 Silica or silicates
• CPC Class Codes: B01D 2257/2045 Hydrochloric acid
• CPC Class Codes: B01D 2257/2064 Chlorine
• CPC Class Codes: B01D 2257/2066 Fluorine
• CPC Class Codes: B01D 2257/302 Sulfur oxides
• CPC Class Codes: B01D 2257/404 Nitrogen oxides other than dinitrogen oxide
• CPC Class Codes: B01D 2257/502 Carbon monoxide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2257/602 Mercury or mercury compounds
• CPC Class Codes: B01D 2257/708 Volatile organic compounds V.O.C.'s
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01D 53/508 by treating the gases with solids
• CPC Class Codes: B01D 53/565 by treating the gases with solids
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02E 20/32 Direct CO2 mitigation

Abstract

The disclosure provides methods and systems for sequestering and/or reducing sulfur oxides, nitrogen oxides and/or carbon dioxide present in industrial effluent fluid streams. A solid particulate material comprising a slag component, a binder component (distinct from the slag component), and optionally water is formed and then contacted with the effluent fluid stream to reduce at least one of the sulfur oxides, nitrogen oxides, and/or carbon dioxide. The contacting of the effluent stream may occur in a packed bed reactor with the solid dry particulate material. Methods of reducing pollutants from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided.

Claims

1. A method of reducing pollution generated by a combustion source, the method comprising:

contacting a fluid stream comprising sulfur oxides and carbon dioxide exiting the combustion source with a substantially dry solid material formed by admixing a slag component having one or more reactive silicate compounds with a binder component, wherein the slag comprises silicon dioxide at greater than or equal to about 25% by weight, and prior to the contacting the fluid stream has a temperature of less than about 600°

F. (about 316°

C.), and wherein the sulfur oxides present in the fluid stream are removed after the contacting to a removal efficiency of greater than or equal to about 70% in comparison to the initial amount of sulfur oxides present in the fluid stream prior to the contacting and the carbon dioxide present in the fluid stream is removed after the contacting to a removal efficiency of greater than or equal to about 20% in comparison to the initial amount of carbon dioxide present in the fluid stream prior to the contacting.

2. The method according to claim 1, further comprising monitoring the amount of at least one of sulfur oxides and carbon dioxide present in the fluid stream after the contacting.

3. The method according to claim 2, further comprising comparing the amount of at least one of the carbon dioxide or sulfur oxides present in the fluid stream after the contacting to a predetermined set point amount for at least one of carbon dioxide or sulfur oxides, wherein when the amount of monitored carbon dioxide or sulfur oxides after the contacting exceeds the predetermined set point, replacing the solid material with new solid material.

4. The method according to claim 1, wherein the binder component comprises one or more materials selected from the group consisting of:

Portland cement, cement clinker, molasses, guar gum, and starch and the slag component comprises one or more materials selected from the group consisting of;

carbon slag, air cooled blast furnace slag, granulated blast furnace slag, ground granulated blast furnace slag, expanded and/or pelletized blast furnace slag, basic oxygen furnace steel slag, open hearth furnace steel slag, and electric arc furnace steel slag.

5. The method according to claim 1, wherein the solid material further comprises a third component comprising a source of calcium oxide and a source of alkali metal ions comprising free lime (free CaO) at greater than or equal to about 3% by weight and Na₂O, K₂O, or combinations thereof at greater than or equal to 1% by weight.

6. The method according to claim 1, wherein the solid material comprises a plurality of particles having an average particle size diameter of about 0.25 mm to about 12 mm.

7. The method according to claim 6, wherein the contacting occurs in a packed bed reactor containing the solid material, wherein the reactor has a differential pressure measured from an inlet of the packed bed reactor to an outlet of the packed bed reactor of less than or equal to about 250 Pa.

8. The method according to claim 1, further comprising recycling the fluid stream for additional contacting after the initial contacting to provide additional removal of the sulfur oxides and carbon dioxide.

9. The method according to claim 1, wherein a ratio of the slag component to the binder component in the solid material is about 6:

1 to about 99;

1 on a dry basis.

10. The method according to claim 1, wherein the admixing further comprises admixing water with the slag component and the binder component.

11. The method according to claim 1, wherein the contacting further reduces an amount of at least one additional pollutant selected from the group consisting of:

carbon monoxide, nitrogen oxides, chlorofluorocarbons, hydrochloric acid, particulate matter, volatile organic compounds, aerosol compounds, mercury, lead, ammonia, and ozone.

12. The method according to claim 1, wherein the temperature is greater than or equal to about 275°

F. (about 135°

C.) and less than or equal to about 450°

F. (about 232°

C.) and the removal efficiency of sulfur oxides after the contacting is greater than or equal to about 80% and the removal efficiency of carbon dioxide after the contacting is greater than or equal to about 30%.

13. The method according to claim 1, wherein the substantially dry solid material has a water content of less than about 3% by weight.

14. A method of reducing pollution generated by a combustion source, the method comprising:

introducing an effluent fluid stream generated in the combustion source to a packed bed reactor, the effluent stream having a temperature of less than about 600°

F. (about 316°

C.), the effluent fluid stream comprising carbon dioxide and sulfur oxides, the reactor having at least one chamber comprising a plurality of substantially dry solid particles having an average particle diameter size of about 0.25 mm to about 12 mm that are formed by admixing a slag component having one or more reactive silicate compounds with a binder component, wherein the slag component comprises silicon dioxide at greater than or equal to about 25% by weight;

contacting the effluent stream with the solid particles in the reactor; and

monitoring the level of at least one of the carbon dioxide or sulfur oxides pollutants present in the effluent stream exiting the reactor, wherein the respective levels of carbon dioxide and sulfur oxides in the stream exiting the reactor are respectively at least 20% less than the level of carbon dioxide and sulfur oxides initially in the effluent stream entering the reactor.

15. The method of claim 14, wherein the plurality of solid particles is contained in a replaceable cartridge disposed in the chamber.

16. The method of claim 14, wherein the temperature is greater than or equal to about 275°

F. (about 135°

C.) and less than or equal to about 450°

F. (about 232°

C.).

17. The method according to claim 14, wherein the binder component comprises:

Portland cement, cement clinker, molasses, guar gum, and/or starch and the slag component comprises carbon slag, blast furnace slag, and/or steel slag.

18. The method according to claim 14, wherein the effluent stream comprises sulfur oxides, nitrogen oxides, and carbon dioxide and the level of sulfur oxides in the stream exiting the reactor is 70% less than the level of sulfur oxides initially in the effluent stream entering the reactor;

the level of carbon dioxide in the stream exiting the reactor is 30% less than the level of carbon dioxide initially in the effluent stream entering the reactor, and the level of nitrogen oxides in the stream exiting the reactor is 20% less than the level of nitrogen oxides initially in the effluent stream entering the reactor.

19. The method according to claim 14, further comprising recycling the effluent stream to the packed bed reactor after the exiting to remove an additional amount of the at least one air pollutant.

20. The method according to claim 14, wherein the substantially dry solid particles have a water content of less than about 3% by weight.

21. A method of reducing pollution generated by a combustion source, the method comprising:

contacting a fluid stream comprising sulfur oxides and carbon dioxide exiting the combustion source with a substantially dry solid material formed by admixing a slag component having one or more reactive silicate compounds, where the slag component comprises silicon dioxide at greater than or equal to about 25% by weight, a binder component, and a third component comprising a source of calcium oxide and a source of alkali metal ions, wherein the binder component is distinct from the third component and the slag is present at greater than or equal to about 40% to less than or equal to about 70% by weight of the solid material, the binder component is present at greater than or equal to about 1% to less than or equal to about 15% by weight of the solid material, the third component is present at greater than or equal to about 15% to less than or equal to about 57% by weight of the solid material, and wherein prior to the contacting the fluid stream has a temperature of less than about 600°

F. (about 316°

C.), wherein the sulfur oxides present in the fluid stream are removed after the contacting to a removal efficiency of greater than or equal to about 70% and the carbon dioxide present in the fluid stream is removed after the contacting to a removal efficiency of greater than or equal to about 20% in comparison to the initial amount of sulfur oxides and carbon dioxide respectively present in the fluid stream prior to the contacting.

22. The method according to claim 21, wherein the binder component comprises one or more materials selected from the group consisting of:

Portland cement, cement clinker, molasses, guar gum, starch, and combinations thereof;

the slag component comprises one or more materials selected from the group consisting of;

carbon slag, air cooled blast furnace slag, granulated blast furnace slag, ground granulated blast furnace slag, expanded and/or pelletized blast furnace slag, basic oxygen furnace steel slag, open hearth furnace steel slag, electric arc furnace steel slag, and combinations thereof; and

the third component comprises a material selected from the group consisting of;

cement kiln dust, lime kiln dust, sugar beet lime, clinker dust, slaked lime, quick lime, and combinations thereof, wherein the binder component is substantially dry having a water content of less than 3% by weight.

23. A method of reducing pollution generated by a combustion source, the method comprising:

contacting a fluid stream comprising sulfur oxides and carbon dioxide exiting the combustion source with a substantially dry solid material formed by admixing i) a slag component having one or more reactive silicate compounds, where the slag component comprises silicon dioxide at greater than or equal to about 25% by weight, ii) a binder component, and iii) a third component distinct from said binder component that comprises a source of calcium oxide and a source of alkali metal ions comprising free lime (free CaO) at greater than or equal to about 3% by weight and Na₂O, K₂O, or combinations thereof at greater than or equal to 1% by weight of the third component, wherein a ratio of the slag component to the third component ranges from about 99;

1 to about 1;

99, wherein prior to the contacting the fluid stream has a temperature of less than about 600°

F. (about 316°

C.), wherein the sulfur oxides present in the fluid stream are removed after the contacting to a removal efficiency of greater than or equal to about 70% and the carbon dioxide present in the fluid stream is removed after the contacting to a removal efficiency of greater than or equal to about 20% in comparison to the initial amount of sulfur oxides and carbon dioxide respectively present in the fluid stream prior to the contacting.

24. The method according to claim 23, wherein the binder component comprises one or more materials selected from the group consisting of:

Portland cement, cement clinker, molasses, guar gum, starch, and combinations thereof;

the slag component comprises one or more materials selected from the group consisting of;

carbon slag, air cooled blast furnace slag, granulated blast furnace slag, ground granulated blast furnace slag, expanded and/or pelletized blast furnace slag, basic oxygen furnace steel slag, open hearth furnace steel slag, electric arc furnace steel slag, and combinations thereof; and

the third component comprises a material selected from the group consisting of;

cement kiln dust, lime kiln dust, sugar beet lime, clinker dust, slaked lime, quick lime, and combinations thereof and wherein the solid material has a water content of less than 3% by weight.