Continuous flowing pre-treatment system with steam recovery

• US 8,017,820 B2
• Filed: 09/30/2005
• Issued: 09/13/2011
• Est. Priority Date: 09/30/2004
• Status: Expired due to Fees

• Current Assignee: Iogen Energy Corporation (Iogen Corporation)
• Original Assignee: Iogen Energy Corporation (Iogen Corporation)
• Inventors: Rea, David, Foody, Brian, Anand, Vijay
• Primary Examiner(s): Bhat; Nina
• Application Number:
  US10/592,906
• Publication Number:
  US 20080064906A1
• Time in Patent Office: 2,174 Days
• Field of Search: 585/240, 585/242, 127/1, 127/2, 127/9, 162/17, 162/22, 162/243, 162/173
• US Class Current: 585/242
• CPC Class Codes: C12P 19/02 Monosaccharides 2-ketogulonic acid C12P7/60
• CPC Class Codes: C12P 19/14 produced by the action of a carbohydrase (EC 3.2.x), e.g. by alpha-amylase , e.g. by cellulase, hemicellulase
• CPC Class Codes: C12P 2201/00 Pretreatment of cellulosic or lignocellulosic material for subsequent enzymatic treatment or hydrolysis
• CPC Class Codes: C12P 7/10 substrate containing cellulosic material
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

The present invention is directed to a continuous process for pretreating a lignocellulosic feedstock. A feedstock slurry is provided, which has a solids concentration of 10% to 33% by weight. The feedstock slurry is pumped through a heating train of at least two stages, each stage including a pump to increase stage pressure and a direct steam injection to heat the feedstock slurry. Acid is also added to the feedstock slurry prior to the heating train, during a heating stage, or after leaving the heating train; the acid is added at a concentration of 0% to 12% weight of acid on weight of initial feedstock. A heated, acidified feedstock slurry is thus produced. The heated, acidified feedstock slurry is flowed through a pre-treatment reactor at a temperature of 160° C. to 280° C. for a time sufficient to increase efficiency of conversion of cellulose in the feedstock to glucose using cellulase enzymes. After the slurry exits the pre-treatment reactor, it is cooled using two, or more than two flashing stages at successively lower pressures, without intermittent increases in pressure. The steam energy, at or near its flash temperature, from two or more than two of the flashing stages is used to heat the feedstock slurry in the heating train.

Claims

1. A continuous process for pre-treating a lignocellulosic feedstock, comprising:

(a) providing a pumpable feedstock slurry having a solids concentration of 8% to 30% by weight;

(b) pumping the feedstock slurry through a heating train of two, or more than two heating stages, each heating stage including a pump to increase heating stage pressure and a direct steam injection to heat the feedstock slurry;

(c) adding acid to the feedstock slurry prior to the heating train, during a heating stage, or after leaving the heating train, the acid added at a concentration of 0.2% to 12% weight of acid on weight of initial feedstock, to produce a heated, acidified feedstock slurry;

(d) flowing the heated, acidified feedstock slurry through a pre-treatment reactor at a temperature of 160°

C. to 280°

C. for a time sufficient to increase efficiency of conversion of cellulose in the feedstock to glucose using cellulase enzymes;

(e) cooling the slurry after the slurry exits the pre-treatment reactor, using two, or more than two flashing stages at successively lower pressures, without increasing the steam pressure after flashing; and

(f) using at least a portion of the steam energy from two or more than two of the flashing stages to heat the feedstock slurry in the heating train, wherein flash steam from at least one of the flashing stages, from which at least a portion of the flash steam is used in the heating train, has a pressure that is 20% to 99.5% of the inlet slurry pressure to such flashing stage.

2. The process of claim 1, wherein, in the step of providing (step a), the feedstock is selected from the group consisting of agricultural waste, grass, forestry biomass, sugar processing residues and combinations thereof.

3. The process of claim 2, wherein the agricultural waste is selected from the group consisting of corn stover, soybean stover, corn cobs, rice straw, rice hulls, corn fiber, wheat straw, barley straw, canola straw, oat straw, oat hulls and combinations thereof.

4. The process of claim 2, wherein the grass is selected from the group consisting of switch grass, miscanthus, cord grass, rye grass, reed canary grass and combinations thereof.

5. The process of claim 2, wherein the forestry biomass is selected from the group consisting of recycled wood pulp fiber, softwood, hardwood, sawdust and combinations thereof.

6. The process of claim 2, wherein the sugar processing residue is bagasse, beet pulp or combinations thereof.

7. The process of claim 1, wherein, in the step of providing (step a), the feedstock is slurried in an aqueous solution.

8. The process of claim 7, wherein, in the step of pumping (step b), the heating train comprises 2 to 8 heating stages.

9. The process of claim 8, wherein the step of cooling (step e) comprises 2 to 8 flashing stages.

10. The process of claim 9, wherein the slurry is subsequently cooled to about 30°

C. to about 100°

C. after the final flashing stage.

11. The process of claim 1, wherein, in the step of adding (step c), the acid is selected from the group consisting of sulfuric acid, sulfurous acid, and sulfur dioxide.

12. The process of claim 1, wherein, in the step of adding (step c), the acid is added to the feedstock slurry prior to the heating train.

13. The process of claim 1, wherein, in the step of adding (step c), the acid is added to the feedstock slurry after the heating train.

14. The process of claim 1, wherein, in the step of adding (step c), the acid is added to the feedstock slurry in a heating stage.

15. The process of claim 1, wherein, after the step of adding (step c) and before the step of pumping (step d), the feedstock slurry is reacted at a temperature of less than about 170°

C. in the presence of about 0.5% to about 3% weight of acid on weight of initial feedstock to hydrolyze the hemicellulose.

16. The process of claim 1, wherein, after the step of cooling (step e), the slurry is submitted to enzymatic hydrolysis by cellulase enzymes.

17. The process of claim 1, wherein, in the step of pumping (step b), live steam is added to one or more than one heating stage to heat the feedstock slurry.

18. The process of claim 1, wherein, in the step of using steam energy (step f), flash steam, or a portion thereof, from at least one of the two or more flashing stages is used to heat a stream of water, steam, or a combination thereof, and wherein at least a portion of the heated stream is sent to the heating train to heat the feedstock slurry.