Proton exchange membrane fuel cell stack and fuel cell stack module

• US 8,026,020 B2
• Filed: 05/08/2007
• Issued: 09/27/2011
• Est. Priority Date: 05/08/2007
• Status: Active Grant

• Current Assignee: Emergent Power Inc. (Plug Power Inc.)
• Original Assignee: Relion Incorporated (Plug Power Inc.)
• Inventors: Ryan, Eric J., Yemul, Dinesh S., Wright, Matthew M., Fisher, John M., Lott, David R., Spink, Scott A.
• Primary Examiner(s): Michener; Jennifer
• Assistant Examiner(s): WILLS, MONIQUE M
• Application Number:
  US11/800,994
• Publication Number:
  US 20080280178A1
• Time in Patent Office: 1,603 Days
• Field of Search: 429/514, 429/400, 429/408, 429/428, 429/434, 429/437, 429/438, 429/439, 429/440, 429/442, 429/443, 429/452
• US Class Current: 429/514
• CPC Class Codes: H01M 8/0236 Glass; Ceramics; Cermets
• CPC Class Codes: H01M 8/0245 in the form of layered or coated products
• CPC Class Codes: H01M 8/0267 having heating or cooling means, e.g. heaters or coolant flow channels
• CPC Class Codes: H01M 8/0273 with sealing or supporting means in the form of a frame
• CPC Class Codes: H01M 8/0297 Arrangements for joining electrodes, reservoir layers, heat exchange units or bipolar separators to each other H01M8/0271 takes precedence
• CPC Class Codes: H01M 8/04014 Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
• CPC Class Codes: H01M 8/04067 Heat exchange or temperature measuring elements, thermal insulation, e.g. heat pipes, heat pumps, fins
• CPC Class Codes: H01M 8/04089 of gaseous reactants
• CPC Class Codes: H01M 8/241 with solid or matrix-supported electrolytes
• CPC Class Codes: H01M 8/242 comprising framed electrodes or intermediary frame-like gaskets H01M8/2425, H01M8/244 take precedence
• CPC Class Codes: H01M 8/248 Means for compression of the fuel cell stacks
• CPC Class Codes: H01M 8/2483 characterised by internal manifolds
• CPC Class Codes: H01M 8/2484 characterised by external manifolds
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A proton exchange membrane fuel cell stack and novel proton exchange membrane fuel cell module are disclosed and wherein the proton exchange membrane fuel cell stack includes a plurality of repeating, serially electrically coupled fuel cell stack modules, and which are sealably mounted together by a compressive force of less than about 60 pounds per square inch.

Claims

1. A proton exchange membrane fuel cell stack, comprising:

a plurality of repeating, serially electrically coupled fuel cell stack modules, wherein the respective fuel cell stack modules include an electrically conductive heat sink having a low thermal conductive mass, and wherein the thermal conductive mass of individual heat sinks of individual fuel cell stack modules provide a substantially different degree of cooling for each of the respective fuel cell stack modules within the fuel cell stack, so that a resulting operating temperature of any one of the plurality of fuel cell stack modules differs from an operating temperature of any other of the plurality of fuel cell stack modules by less than about ten percent.

2. A proton exchange membrane fuel cell stack as claimed in claim 1, and further comprising:

a first and second endplate which are disposed in predetermined spaced relation, one relative to the other, and wherein the plurality of fuel cell stack modules are disposed between the respective first and second endplates, and wherein the first and second endplates are coupled together, and in combination, exert a compressive force of less than about 60 pounds per square inch to each of the respective fuel cell stack modules.

3. A proton exchange membrane fuel cell stack as claimed in claim 2, and further comprising:

a coupler having opposite ends which individually cooperate with and connect the respective first and second endplates together, and which passes through each of the respective fuel cell stack modules.

4. A proton exchange membrane fuel cell stack as claimed in claim 2, and further comprising:

a coupler having opposite ends which individually cooperate with and connect the respective first and second endplates together, and which does not pass through the respective fuel cell stack modules.

5. A proton exchange membrane fuel cell stack as claimed in claim 1, and wherein the respective fuel cell stack modules are individually fastened together so as to produce a compressive force of less than about 60 pounds per square inch that sealably mounts the plurality of fuel cell stack modules together.

6. A proton exchange membrane fuel cell stack as claimed in claim 1, and further comprising:

a fastener borne by each of the respective fuel cell stack modules and which engages an adjacent, juxtaposed, fuel cell stack module, and which creates a compressive force of less than about 60 pounds per square inch.

7. A proton exchange membrane fuel cell stack as claimed in claim 1, and wherein the respective fuel cell stack modules further comprise:

a frame having opposite first and second sides, and an inside and an outside peripheral edge, and wherein the inside peripheral edge defines an internal cavity, and wherein the respective frames are substantially self-aligning, and wherein the respective frames each define an air passageway which extends between the inside and outside peripheral edges and which communicates with the internal cavity thereof.

8. A proton exchange membrane fuel cell stack as claimed in claim 7, and wherein a mounting flange is made integral with the inside peripheral edge of the frame and which extends into the internal cavity of the frame, and wherein the frame further defines a fuel gas passageway, and an exhaust gas passageway, which are each coupled in fluid flowing relation relative to the cavity, and wherein the fuel gas and exhaust gas passageways of the respective fuel cell stack modules are coupled in fluid flowing relation, one relative to the others.

9. A proton exchange membrane fuel cell stack as claimed in claim 8, and wherein the respective fuel gas passageways are coupled in fluid flowing relation relative to a plurality of fuel gas channels which are defined, at least in part, by the first side of the frame, and wherein the fuel gas channels are coupled in fluid flowing relation to the internal cavity of the frame.

10. A proton exchange membrane fuel cell stack as claimed in claim 9, and wherein the respective fuel cell stack modules further comprise:

a first gas diffusion layer positioned within the cavity of the frame;

a proton exchange membrane received within the cavity, and disposed in resting, sealing relation relative to the mounting flange, and wherein the proton exchange membrane has an anode side which is juxtaposed relative to the first gas diffusion layer, and an opposite cathode side;

a second gas diffusion layer which is positioned within the cavity of the frame and which is juxtaposed relative to the cathode side of the proton exchange membrane; and

the electrically conductive heat sink is received within the cavity of the frame, and juxtaposed relative to the second gas diffusion layer, and wherein the heat sink is oriented in fluid flowing relation relative to the air passageway which is defined by the frame.

11. A proton exchange membrane fuel cell stack as claimed in claim 1, and wherein the heat sink is a corrugated metal.

12. A proton exchange membrane fuel cell stack as claimed in claim 1, and wherein the heat sink is a reticulated metal foam.

13. A proton exchange membrane fuel cell stack as claimed in claim 1, and wherein the heat sink comprises an extruded aluminum plate defining a plurality of passageways.

14. A proton exchange membrane fuel cell stack as claimed in claim 1, and wherein the heat sink comprises a stamped, resilient, reticulated metal.

15. A proton exchange membrane fuel cell stack as claimed in claim 10, and wherein the heat sink is fabricated from an electrically conductive substrate which defines a plurality of passageways which are oriented in fluid flowing relation relative to the air passageway which is defined by the frame.

16. A proton exchange membrane fuel cell stack as claimed in claim 1, and wherein the thermal conductive mass of the individual heat sinks of each of the fuel cell modules is variable.

17. A proton exchange membrane fuel cell stack as claimed in claim 1, and wherein the heat sink of at least one of the fuel cell stack modules defines a plurality of passageways which provide a first and second cooling air velocity relative to the passageways, and wherein the first and second cooling air velocities each provide substantially different degrees of cooling relative to the heat sink.

18. A proton exchange membrane fuel cell stack as claimed in claim 7, and wherein the air passageway as defined by the frame has a cross sectional area, and wherein the cross sectional area of the air passageways of the respective frames are variable.

19. A proton exchange membrane fuel cell stack as claimed in claim 10, and wherein the respective fuel cell stack modules further comprise:

a current collecting separator plate mounted on the first side of the frame and which is positioned, at least in part, in ohmic electrical contact with the first gas diffusion layer, and wherein the electrically conductive heat sink is placed in ohmic electrical contact with the current collecting separator plate of an adjacent fuel cell stack module.

20. A proton exchange membrane fuel cell stack as claimed in claim 19, and wherein the current collecting separator plate is a non-porous, substantially smooth metal plate, which is sealably affixed to the first side of the frame, and which is further disposed in covering relation relative to the plurality of fuel gas channels defined by the first side of the frame.

21. A proton exchange membrane fuel cell stack as claimed in claim 19, and wherein the current collecting separator plate matingly cooperates with, and is self-aligning relative to the frame.

22. A proton exchange membrane fuel cell stack as claimed in claim 19, and wherein the anode side of the proton exchange membrane has an active area surface, and wherein the active area surface of the anode side of the proton exchange membrane, or a region of the current collecting separator plate which is in at least partial covering relation relative to the active area surface of the anode side, is substantially devoid of predetermined passageways for accommodating the flow of a reactant gas.