Fuel cell systems with maintenance hydration by displacement of primary power

• US 8,034,494 B2
• Filed: 06/30/2010
• Issued: 10/11/2011
• Est. Priority Date: 05/30/2007
• Status: Active Grant

• Current Assignee: DCNS SA (Government of France)
• Original Assignee: IdaTech LLC (IdaTech Ltd.)
• Inventors: Snider, Tod L., Kelley, Mason P., LaVen, Arne
• Primary Examiner(s): Kalafut; Stephen J.
• Application Number:
  US12/828,107
• Publication Number:
  US 20100266917A1
• Time in Patent Office: 468 Days
• Field of Search: 429/9, 429/413, 429/428, 429/432, 429/433, 429/450, 307/64
• US Class Current: 429/413
• CPC Class Codes: H01M 16/006 of fuel cells with rechargeable batteries
• CPC Class Codes: H01M 2008/1095 Fuel cells with polymeric electrolytes
• CPC Class Codes: H01M 8/04126 Humidifying
• CPC Class Codes: H01M 8/04223 during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
• CPC Class Codes: H01M 8/04225 during start-up
• CPC Class Codes: H01M 8/04302 applied during start-up
• CPC Class Codes: H01M 8/0432 Temperature; Ambient temperature
• CPC Class Codes: H01M 8/04492 Humidity; Ambient humidity; Water content
• CPC Class Codes: H01M 8/04619 of fuel cell stacks
• CPC Class Codes: H01M 8/0485 of the electrolyte
• CPC Class Codes: H01M 8/04955 Shut-off or shut-down of fuel cells
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 90/40 Fuel cell technologies in production processes

Abstract

Fuel cell systems and methods that perform maintenance hydration by supplying power to satisfy at least part of an applied load from an energy-consuming assembly while a primary power source is in electrical communication with and available to supply power to the energy-consuming assembly to satisfy the portion of the applied load. In some embodiments, the systems or methods may determine a start time, or start condition, for hydration of the fuel cell system. Power may be supplied from the activated fuel cell system at an output voltage that is higher than a voltage at which power from the primary power source is being supplied, such that the applied load is satisfied, at least in part, by power from the fuel cell system instead of from the primary power source. Upon operation for a period sufficient to rehydrate the fuel cell stack, operation of the fuel cell system may be discontinued.

Claims

1. A method of performing maintenance hydration of a fuel cell system serving as an auxiliary power source for an energy-consuming assembly that is disposed in electrical communication with a primary power source, the method comprising:

activating the fuel cell system from an inactive condition by initiating delivery of at least a fuel to a fuel cell stack of the fuel cell system, wherein the activating is performed responsive to a start condition, and further wherein the start condition is selected to avoid a decrease in the efficiency of the fuel cell system due to inactivity of the fuel cell system; and

supplying power from the activated fuel cell system to satisfy at least a portion of an electrical load applied by the energy consuming assembly while the primary power source is available to at least partially supply the portion of the electrical load being satisfied by the fuel cell system, thereby operating the fuel cell system for power generation and associated hydration while the primary power source is available to satisfy at least a portion of the electrical load applied by the energy consuming assembly.

2. The method of claim 1, wherein the start condition is selected to avoid a decrease in the efficiency of the fuel cell system due to a decrease in hydration of the fuel cell stack of the fuel cell system.

3. The method of claim 1, wherein the start condition is based at least in part on the impedance of the energy consuming device.

4. The method of claim 1, wherein the start condition is based at least in part on the impedance of the fuel cell stack.

5. The method of claim 1, wherein the start condition is based at least in part on at least one of an ambient temperature proximate the fuel cell system, a temperature of at least a portion of the fuel cell system, an ambient humidity proximate the fuel cell system, and a length of time since the fuel cell system was last operated.

6. The method of claim 1, wherein the method further includes ceasing the supplying responsive to a stop condition.

7. The method of claim 6, wherein the stop condition includes determining that at least a predetermined amount of hydration has been provided to the fuel cell stack by the supplying power.

8. The method of claim 6, wherein the stop condition is based at least in part on at least one of an ambient temperature proximate the fuel cell system, a temperature of at least a portion of the fuel cell system, an ambient humidity proximate the fuel cell system, and a length of time since the fuel cell system was last operated.

9. The method of claim 6, wherein the stop condition is based at least in part on at least one of a length of the supplying, an amount of water produced during the supplying, and the total amount of electrical current generated during the supplying.

10. The method of claim 1, wherein supplying power includes supplying power at a fuel cell system voltage that is higher than a primary power source voltage at which the primary power source is supplying power to the energy consuming assembly.

11. The method of claim 1, further comprising adjusting the output voltage of the fuel cell system responsive at least in part to a primary power source voltage at which the primary power source is supplying power to the energy consuming assembly.

12. The method of claim 11, wherein the adjusting the output voltage includes increasing the output voltage, if needed, to supply power from the fuel cell system at an output voltage that is higher than the voltage of power from the primary power source.

13. The method of claim 12, wherein increasing the output voltage includes increasing the output voltage incrementally.

14. The method of claim 13, wherein increasing the output voltage includes increasing the output voltage (a) until the fuel cell system is generating power above a threshold level or (b) until the output voltage reaches and/or exceeds a threshold value, whichever comes first, and wherein, if the output voltage reaches and/or exceeds the threshold value first, the steps of activating the fuel cell system and increasing the output voltage are repeated one or more times until the fuel cell system is generating power above the threshold level such that the step of supplying power can be performed.

15. The method of claim 14, wherein, if the output voltage reaches and/or exceeds the threshold value, the steps of activating the fuel cell system and increasing the output voltage are repeated after waiting a predetermined time interval.

16. The method of claim 1, wherein the supplying includes supplying some but not all of the electrical load applied by the energy consuming assembly.

17. The method of claim 1, wherein the supplying includes supplying all of the electrical load applied by the energy consuming assembly.

18. The method of claim 17, wherein a magnitude of the power supplied by the activated fuel cell system is greater than a magnitude of the electrical load applied by the energy consuming assembly.

19. The method of claim 18, wherein a portion of the power supplied by the activated fuel cell system that is greater than the magnitude of the electrical load applied by the energy consuming assembly is utilized to charge an energy storage device.

20. The method of claim 1, wherein the fuel includes hydrogen gas, and the fuel cell stack includes proton exchange membrane fuel cells.

21. The method of claim 1, wherein the primary power source and the fuel cell system are in electrical communication with at least one energy storage device, and wherein the supplying power includes charging the at least one energy storage device.

22. The method of claim 21, wherein the at least one energy storage device includes a plurality of batteries connected in parallel, and wherein the supplying power includes equalizing charge among the plurality of batteries.

23. The method of claim 1, wherein the method further includes delivering a feedstock stream to a hydrogen generation assembly, generating a mixed gas stream within the hydrogen generation assembly, and providing at least a portion of the mixed gas stream to the fuel cell stack as the fuel.

24. The method of claim 23, wherein the method further includes separating the mixed gas stream into a product hydrogen stream and a byproduct stream and providing at least a portion of the product hydrogen stream to the fuel cell stack as the fuel, wherein the product hydrogen stream includes a lower concentration of at least one impurity when compared to the mixed gas stream and the byproduct stream includes a higher concentration of at least one impurity when compared to the mixed gas stream.

25. The method of claim 1, wherein the steps of activating the fuel cell system and supplying power are repeated at regular time intervals.

26. The method of claim 1, further comprising a step of repeating the steps of activating the fuel cell system and supplying power if the supplying power is stopped before the predetermined maintenance hydration treatment has been completed.