Processing of titanium-aluminum-vanadium alloys and products made thereby

• US 8,048,240 B2
• Filed: 05/07/2007
• Issued: 11/01/2011
• Est. Priority Date: 05/09/2003
• Status: Active Grant

• Current Assignee: ATI Properties LLC (CNH Industrial N.V.)
• Original Assignee: ATI Properties Incorporated (Allegheny Technologies Incorporated)
• Inventors: Hickman, Randall W., Hebda, John J., Graham, Ronald A.
• Primary Examiner(s): King; Roy
• Assistant Examiner(s): ZHENG, LOIS L
• Application Number:
  US11/745,189
• Publication Number:
  US 20110232349A1
• Time in Patent Office: 1,639 Days
• Field of Search: 148/421, 148668-670, 420417-418, 420/420
• US Class Current: 148/670
• CPC Class Codes: B21B 1/26 by hot-rolling , e.g. Steckel hot mill
• CPC Class Codes: C22C 14/00 Alloys based on titanium
• CPC Class Codes: C22F 1/183 of titanium or alloys based thereon

Abstract

A method of forming an article from an α−β titanium including, in weight percentages, from about 2.9 to about 5.0 aluminum, from about 2.0 to about 3.0 vanadium, from about 0.4 to about 2.0 iron, from about 0.2 to about 0.3 oxygen, from about 0.005 to about 0.3 carbon, from about 0.001 to about 0.02 nitrogen, and less than about 0.5 of other elements. The method comprises cold working the α−β titanium alloy.

Claims

1. A method of forming an article from an α

−

β

titanium alloy consisting of, in weight percentages, from 2.9 to 5.0 aluminum, from 2.0 to 3.0 vanadium, from 0.4 to 2.0 iron, from 0.2 to 0.3 oxygen, from 0.005 to 0.3 carbon, from 0.001 to 0.02 nitrogen, from 0 to 0.1 chromium, from 0 to 0.1 nickel, incidental impurities, and titanium, the method consisting of;

α

−

β

working the α

−

β

titanium alloy at a temperature greater than 1600°

F. to provide the α

−

β

titanium alloy with a microstructure conducive to subsequent cold deformation; and

cold working the α

−

β

titanium alloy at a temperature in the range of ambient temperature to less than 1250°

F.;

wherein the article has tensile strength of at least 120 ksi and ultimate tensile strength of at least 130 ksi.

2. The method of claim 1, wherein cold working the α

−

β

titanium alloy is conducted at a temperature in the range of ambient temperature up to 1000°

F.

3. The method of claim 1, wherein cold working the α

−

β

titanium alloy comprises working the α

−

β

titanium alloy at less than 1250°

F. by at least one technique selected from the group consisting of rolling, forging, extruding, pilgering, rocking, drawing, flow-turning, liquid compressive forming, gas compressive forming, hydro-forming, bulge forming, roll forming, stamping, fine-blanking, die pressing, deep drawing, coining, spinning, swaging, impact extruding, explosive forming, rubber forming, back extrusion, piercing, stretch forming, press bending, electromagnetic forming, and cold heading.

4. The method of claim 1, wherein the article is selected from the group consisting of a coil, a sheet, a strip, a foil, a plate, a bar, a rod, a wire, a tubular hollow, a pipe, a tube, a cloth, a mesh, a structural member, a cone, a cylinder, a duct, a nozzle, a honeycomb structure, a fastener, a rivet and a washer.

5. The method of claim 1, where the α

−

β

titanium alloy has lower flow stress than Ti-6Al-4V alloy.

6. The method of claim 1, wherein cold working the α

−

β

titanium alloy comprises cold rolling the α

−

β

titanium alloy, and wherein the article is a generally flat-rolled article selected from the group consisting of a sheet, a strip, a foil and a plate.

7. The method of claim 6, wherein cold working the α

−

β

titanium alloy comprises reducing a thickness of the α

−

β

titanium alloy by at least two cold rolling steps, and wherein the method further comprises;

annealing the α

−

β

titanium alloy intermediate successive cold rolling steps, wherein annealing the α

−

β

titanium alloy reduces stresses within the α

−

β

titanium alloy.

8. The method of claim 7, wherein at least one anneal intermediate successive cold rolling steps is conducted on a continuous anneal furnace line.

9. The method of claim 7, wherein in at least one of the cold rolling steps, a thickness of the α

−

β

titanium alloy is reduced by 30% to 60%.

10. The method of claim 1, wherein cold working the α

−

β

titanium alloy comprises rolling the α

−

β

titanium alloy, and wherein the article is selected from the group consisting of a bar, a rod, and a wire.

11. The method of claim 1, wherein cold working the α

−

β

titanium alloy comprises at least one of pilgering and rocking the α

−

β

titanium alloy, and wherein the article is one of a tube and a pipe.

12. The method of claim 1, wherein cold working the α

−

β

titanium alloy comprises drawing the α

−

β

titanium alloy, and wherein the article is selected from the group consisting of a rod, a wire, a bar and a tubular hollow.

13. The method of claim 1, wherein cold working the α

−

β

titanium alloy comprises at least one of flow-turning, shear spinning and spinning the α

−

β

titanium alloy, and wherein the article has axial symmetry.

14. The method of claim 1, wherein the article has a thickness up to 4 inches, and wherein room temperature properties of the article include elongation of at least 10%.

15. The method of claim 14, wherein the article has elongation of at least 12%.

16. The method of claim 1, wherein yield strength, ultimate tensile strength and elongation properties of the article are each at least as great as for Ti-6Al-4V.

17. The method of claim 1, wherein the article can be bent around a radius of 4 times its thickness without failure of the article.

18. The method of claim 1, wherein the α

−

β

titanium alloy has a nominal composition of titanium, 4 weight percent aluminum, 2.5 weight percent vanadium, 1.5 weight percent iron, and 0.25 weight percent oxygen.

19. A method of forming an article from an α

−

β

titanium alloy consisting of, in weight percentages, from about 2.9 to about 5.0 aluminum, from about 2.0 to about 3.0 vanadium, from about 0.4 to about 2.0 iron, from about 0.2 to about 0.3 oxygen, from about 0.005 to about 0.3 carbon, from about 0.001 to about 0.02 nitrogen, from 0 to 0.1 chromium, from 0 to 0.1 nickel, incidental impurities, and titanium, the method consisting of;

α

−

β

working the α

−

β

titanium alloy at a temperature greater than 1600°

F. to provide the α

−

β

titanium alloy with a microstructure conducive to subsequent cold deformation;

reducing a thickness of the α

−

β

titanium alloy at a temperature in the range of ambient temperature to less than 1250°

F. by a process comprising at least two cold rolling steps, wherein in at least one cold rolling step a thickness of the α

−

β

titanium alloy is reduced by 30% to 60%; and

annealing the α

−

β

titanium alloy intermediate successive cold rolling steps and thereby reducing stresses within the α

−

β

titanium alloy;

wherein the article has tensile strength of at least 120 ksi and ultimate tensile strength of at least 130 ksi.

20. The method of claim 19, wherein the article is selected from the group consisting of a sheet, a strip, a foil and a plate.

21. The method of claim 19, wherein at least one anneal intermediate successive cold rolling step is conducted on a continuous anneal furnace line.

22. The method of claim 19, wherein the α

−

β

titanium alloy has a nominal composition of titanium, 4 weight percent aluminum, 2.5 weight percent vanadium, 1.5 weight percent iron, and 0.25 weight percent oxygen.

23. A method of making an armor plate from an α

−

β

titanium alloy consisting of, in weight percentages, from 2.9 to 5.0 aluminum, from 2.0 to 3.0 vanadium, from 0.4 to 2.0 iron, from 0.2 to 0.3 oxygen, from 0.005 to 0.3 carbon, from 0.001 to 0.02 nitrogen, from 0 to 0.1 chromium, from 0 to 0.1 nickel, incidental impurities, and titanium, the method consisting of;

α

−

β

working the α

−

β

titanium alloy at a temperature greater than 1600°

F. to provide the α

−

β

titanium alloy with a microstructure conducive to subsequent cold deformation; and

rolling the α

−

β

titanium alloy at a temperature no greater than 400°

F. below the T_β

of the alloy;

wherein the armor plate has tensile strength of at least 120 ksi and ultimate tensile strength of at least 130 ksi.

24. The method of claim 23, wherein rolling the α

−

β

titanium alloy comprises rolling the alloy at a temperature that is in the range of 400°

F. to 700°

F. below the T_β

of the alloy.

25. The method of claim 23, wherein the α

−

β

titanium alloy has a nominal composition of titanium, 4 weight percent aluminum, 2.5 weight percent vanadium, 1.5 weight percent iron, and 0.25 weight percent oxygen.