Optical analysis system and methods for operating multivariate optical elements in a normal incidence orientation

• US 8,049,881 B2
• Filed: 11/27/2006
• Issued: 11/01/2011
• Est. Priority Date: 11/28/2005
• Status: Active Grant

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Blackburn, John C., Priore, Ryan J., Freese, Robert P., Myrick, Michael L.
• Primary Examiner(s): Chowdhury; Tarifur
• Assistant Examiner(s): Lapage; Michael P
• Application Number:
  US12/094,469
• Publication Number:
  US 20090073433A1
• Time in Patent Office: 1,800 Days
• Field of Search: 356/451, 356/454, 356300-307, 356317-318, 356/39, 356416-420, 250/226
• US Class Current: 356/303
• CPC Class Codes: A61K 8/046 Aerosols; Foams
• CPC Class Codes: A61K 8/25 Silicon; Compounds thereof
• CPC Class Codes: A61K 8/26 Aluminium; Compounds thereof
• CPC Class Codes: A61K 8/44 Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
• CPC Class Codes: A61Q 11/00 Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
• CPC Class Codes: G01J 3/02 Details
• CPC Class Codes: G01J 3/0205 Optical elements not provided otherwise, e.g. optical manifolds, diffusers, windows
• CPC Class Codes: G01J 3/021 using plane or convex mirrors, parallel phase plates, or particular reflectors
• CPC Class Codes: G01J 3/0232 using shutters
• CPC Class Codes: G01J 3/0291 Housings; Spectrometer accessories; Spatial arrangement of elements, e.g. folded path arrangements
• CPC Class Codes: G01J 3/08 Beam switching arrangements
• CPC Class Codes: G01J 3/28 Investigating the spectrum using colour filters G01J3/51
• CPC Class Codes: G01N 21/274 Calibration, base line adjustment, drift correction
• CPC Class Codes: G01N 21/31 Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry G01N21/72 takes precedence

Abstract

A method of arranging and utilizing a multivariate optical computing and analysis system includes transmitting light from a light source; reflecting the light from the sample; directing a portion of the light reflected from the sample with a beamsplitter; and arranging an optical filter mechanism in a normal incidence orientation to receive the light reflected from the sample, the optical filter mechanism configured to filter and measure data carried by the light reflected from the sample.

Claims

1. A method of arranging and utilizing a multivariate optical computing and analysis system, the method comprising:

transmitting a first light from a light source;

filtering the first light for a spectral range of interest of a sample;

directing the first light in a direction of the sample;

directing a calibration light from a portion of the first light to a first detector and a second detector without interacting with the sample;

directing a second light generated by a reflection of the first light from the sample through the cavity;

directing a portion of the second light to the first detector and the second detector with a beamsplitter;

arranging an optical mechanism in a normal incidence orientation to receive the portion of the second light and the calibration light in the first detector, the optical

mechanism being configured to optically derive data carried by the portion of the second light and the calibration light into at least one orthogonal component; and

measuring a property of the orthogonal component with the first detector and measuring a portion of the second light and a portion of the calibration light with the second detector to assess the data.

2. The method as in claim 1, wherein the optical mechanism includes a multivariate optical element.

3. The method as in claim 1, wherein the beamsplitter is a neutral beamsplitter.

4. The method as in claim 1, further comprising adjusting a beamsplit fraction so that the first detector and the second detector have similar signal levels.

5. The method as in claim 1, further comprising monitoring only the portion of the second light transmitted through the optical mechanism.

6. The method as in claim 1, further comprising supplementing the portion of the second light transmitted through the optical mechanism with a measurement proportional to a total intensity of light in the system.

7. The method as in claim 1, further comprising reducing angular sensitivity by disposing the optical mechanism in the normal incidence orientation.

8. The method as in claim 1, further comprising directing an additional portion of the second light to a neutral detector for the additional portion of the second light with the property of the orthogonal component.

9. The method as in claim 8, further comprising obtaining comparable signals on the detectors.

10. The method as in claim 1, further comprising modulating the first light to a desired frequency.

11. A method of arranging and utilizing a multivariate optical computing and analysis system, the method comprising:

transmitting a first light from a light source;

directing a calibration light from a portion of the first light to a first detector and a second detector without interacting with the sample;

generating a second light by reflecting the first light from the sample;

directing a portion of the second light to the first detector and the second detector with a beamsplitter; and

arranging an optical mechanism in a normal incidence orientation to receive the portion of the second light and the calibration light in the first detector, the optical mechanism being configured to optically derive data carried by the portion of the second light and the calibration light.

12. The method as in claim 11, wherein the optical mechanism includes a multivariate optical element.

13. The method as in claim 11, wherein the beamsplitter is a neutral beamsplitter.

14. The method as in claim 11, wherein the optical mechanism optically filters the data into at least one orthogonal component.

15. The method as in claim 11, further comprising measuring a property of the orthogonal component with a detector in communication with the optical mechanism to assess the data.

16. The method as in claim 11, further comprising filtering the first light for a spectral range of interest of a sample.

17. The method as in claim 16, wherein the first light is filtered using a spectral element.

18. The method as in claim 11, further comprising modulating the first light to a desired frequency.

19. A multivariate optical computing and analysis system, comprising:

a light source being configured to radiate a first light along a first ray path;

a chopper wheel configured to direct a calibration light from a portion of the first light to a first detector and a second detector without interacting with the sample;

a cavity being configured to direct the first light in a direction of a sample and being configured to direct a second light generated by a reflection of the first light from the sample;

a beamsplitter being configured to direct a portion of the second light to the first detector and the second detector;

an optical mechanism disposed in a normal incidence orientation proximate the beamsplitter, the optical mechanism being configured to optically derive data carried by portion of the second light into at least one orthogonal component; and

a detector being configured to receive the portion of the second light transmitted through the optical mechanism to measure a property of the orthogonal component.

20. The system as in claim 19, wherein the optical mechanism includes a multivariate optical element.

21. The system as in claim 19, wherein the beamsplitter is a neutral beamsplitter.

22. The system as in claim 19, further comprising an additional detector being configured to receive another portion of the second light for comparison of the property of the orthogonal component.

23. The system as in claim 19, further wherein the chopper wheel is configured to modulate the first light to a desired frequency.