Polymer nanofiber-based electronic nose

• US 8,052,932 B2
• Filed: 12/22/2006
• Issued: 11/08/2011
• Est. Priority Date: 12/22/2006
• Status: Active Grant

• Current Assignee: Research Triangle Institute
• Original Assignee: Research Triangle Institute
• Inventors: Ensor, David S., Han, Li, Andrady, Anthony L.
• Primary Examiner(s): Caldarola; Glenn
• Assistant Examiner(s): Boyer; Randy
• Application Number:
  US11/615,285
• Publication Number:
  US 20080150556A1
• Time in Patent Office: 1,782 Days
• Field of Search: 422/50, 422/68.1, 422/82.01, 422/82.02, 422/83, 422/88, 422/90, 977/700, 977/742, 977/744, 977/748, 977/762, 977/902, 977/932, 977/953, 977/957, 324/693
• US Class Current: 422/90
• CPC Class Codes: B82Y 15/00 Nanotechnology for interacting, sensing or actuating, e.g. quantum dots as markers in protein assays or molecular motors
• CPC Class Codes: G01N 27/127 comprising nanoparticles
• CPC Class Codes: Y10S 977/957 Of chemical property or presence

Abstract

A chemical sensor and a system and method for sensing a chemical species. The chemical sensor includes a plurality of nanofibers whose electrical impedance varies upon exposure to the chemical species, a substrate supporting and electrically isolating the fibers, and a set of electrodes connected to the plurality of fibers at spatially separated points to permit the electrical impedance of the plurality of fibers to be measured. The system includes the chemical sensor, an impedance measuring device coupled to the electrodes and configured to determine an electrical impedance of the plurality of fibers, and an analyzer configured to identify the chemical species based on a change in the electrical impedance. The method measures at least one change in an electrical impedance between spatially separated electrodes connected to a plurality of fibers upon exposure of the fibers to the chemical species, and identifies the chemical species based on the measured change in the electrical impedance.

Claims

1. A chemical sensor comprising:

a plurality of fibers whose electrical impedance varies upon exposure to a chemical species;

a substrate supporting and electrically isolating the fibers; and

a set of electrodes disposed on the plurality of fibers at spatially separated points to permit the electrical impedance of the plurality of fibers to be measured.

2. The sensor of claim 1, wherein the fibers comprise nanofibers whose average fiber diameter is less than 500 nm.

3. The sensor of claim 1, wherein the fibers comprise nanofibers whose average fiber diameter is less than 100 nm.

4. The sensor of claim 1, wherein the fibers have an electrical impedance which changes due to at least one of an increase in volumetric size of the fibers by sorption of the chemical species or a change in electrical conduction by a chemical reaction or sorption of the chemical species with a material of the fiber.

5. The sensor of claim 1, wherein the fibers comprise conductive fibers.

6. The sensor of claim 5, wherein:

the conductive fibers comprise a non-conducting medium and a conducting additive dispersed in the non-conducting medium, and the conducting additive has a concentration which permits electrical conduction by percolation of charge carriers through the conductive fibers.

7. The sensor of claim 6, wherein the conducting medium comprises a percentage of the conductive fibers ranging from 2% to 10%.

8. The sensor of claim 6, wherein the conducting medium comprises carbon tubes.

9. The sensor of claim 8, wherein the carbon tubes are disposed in a body of the fibers at a concentration that is within 10% of a conduction percolation threshold.

10. The sensor of claim 6, wherein the non-conducting medium comprises an organic polymer.

11. The sensor of claim 1, wherein the fibers comprises conductive particles included in the fibers to increase a fiber conductivity.

12. The sensor of claim 11, wherein the conductive particles include at least one of carbon black, carbon nanotubes, fullerenes and conducting metals, including at least one of Ag, Au, Cu, and Al.

13. The sensor of claim 1, wherein the plurality of fibers comprises aligned fibers.

14. The sensor of claim 1, further comprising:

plural sets of the electrodes to which respective groups of the fibers are connected at spatially separated points.

15. The sensor of claim 1, further comprising:

a preconcentrator disposed in relation to the plurality of fibers to enhance sorption of the chemical species.

16. The sensor of claim 15, wherein the preconcentrator comprises a silicone layer.

41. The sensor of claim 16, wherein the silicone layer comprises a silicone elastomer or PDMS film.)

42. The sensor of claim 1, wherein the fibers comprise a polymer blended fiber spun from a common solvent.

43. The sensor of claim 1, wherein the fibers comprise conductive fibers.

44. The sensor of claim 1, wherein the fibers are composed of at least one polymer that is conductive and at least one polymer that is nonconductive.

45. The sensor of claim 1, wherein:

the electrical impedance varies upon exposure to an organic species in response to concentrations of the organic species in the parts per million range or greater; and

the substrate comprises a gas or liquid permeable substrate supporting and electrically isolating the fibers

a plurality of fibers whose electrical impedance varies upon exposure to a chemical species;

a substrate supporting and electrically isolating the fibers; and

a set of electrodes disposed on the plurality of fibers at spatially separated points to permit the electrical impedance of the plurality of fibers to be measured.

46. The sensor of claim 45, wherein the chemical sensor functions as a residual lifetime indicator for a filter.

47. The sensor of claim 45,

wherein

the fibers comprise a non-conducting medium and an elongated conducting additive dispersed in the non-conducting medium comprising a 1-30 weight percentage.

48. The sensor of claim 47, wherein the elongated conducting additive comprises carbon nanotubes.

50. The sensor of claim 1, wherein the electrodes are printed on the plurality of fibers.

17. A system for sensing a chemical species, comprising:

a chemical sensor including,

a plurality of fibers having a electrical impedance which varies upon exposure to the chemical species,

a substrate supporting and electrically isolating the fibers, and

a set of electrodes disposed on the plurality of fibers at spatially separated points on the fibers;

an impedance measuring device coupled to the electrodes and configured to determine an electrical impedance of the plurality of fibers, and

an analyzer configured to identify the chemical species based on a change in the electrical impedance.

18. The system of claim 17, wherein the fibers comprise nanofibers having an average fiber diameter less than 500 nm.

19. The system of claim 17, wherein the fibers comprise nanofibers having an average fiber diameter less than 100 nm.

20. The system of claim 17, wherein the fibers have an electrical impedance which changes due to at least one of an increase in volumetric size of the fibers by sorption of the chemical species, a change in electrical conduction by a chemical reaction of the chemical species with a material of the fiber or surface adsorption of a volatile solvent on a surface of the fiber.

21. The system of claim 17, wherein the fibers comprise conductive fibers.

22. The system of claim 21, wherein:

the conductive elements comprise a conducting additive dispersed in the non-conducting medium, and

the conducting additive has a density which permits electrical conduction by percolation of charge carriers through regions of the conducting medium in the conductive fibers.

23. The system of claim 22, wherein the conducting medium comprises a percentage of the conductive fibers ranging from 2% to 10%.

24. The system of claim 22, wherein the conducting medium comprises carbon nanotubes.

25. The system of claim 24, wherein the carbon nanotubes are disposed in a body of the fibers at a concentration that is within 10% of a conduction percolation threshold.

26. The system of claim 22, wherein the fibers comprises conductive particles included in the fibers to increase a fiber conductivity.)

27. The system of claim 26, wherein the conductive particles include at least one of carbon black, carbon nanotubes, fullerenes and conducting metals, including at least one of Ag, Au, Cu, and Al.

28. The system of claim 22, wherein the non-conducting medium comprises an organic polymer.

29. The system of claim 17, wherein the plurality of fibers comprises aligned fibers.

30. The system of claim 17, further comprising:

plural sets of electrodes connected to plural respective groups of the fibers at spatially separated points.

31. The system of claim 17, further comprising a plurality of the chemical sensors forming a sensor network.

51. The system of claim 17, wherein the electrodes are printed on the plurality of fibers.

32. A method for sensing a chemical species, comprising:

providing a chemical sensor disposed on a gas or liquid permeable substrate;

exposing the chemical sensor disposed on the gas or liquid permeable substrate to the chemical species in a gaseous or liquid environment;

measuring at least one change in an electrical impedance between spatially separated electrodes disposed on a plurality of fibers of the chemical sensor upon exposure of the fibers to the chemical species; and

identifying the chemical species based on the measured change in the electrical impedance of the plurality of fibers.

33. The method of claim 32, wherein measuring comprises:

measuring the change in electrical impedance of a plurality of nanofibers having an average fiber diameter less than 500 nm.

34. The method of claim 32, wherein measuring comprises:

measuring the change in electrical impedance of a plurality of nanofibers having an average fiber diameter less than 100 nm.

35. The method of claim 32, wherein measuring comprises:

measuring the change in electrical impedance of a plurality of conductive fibers.

36. The method of claim 32, wherein measuring comprises:

measuring the change in electrical impedance of a plurality of fiber having a non-conducting medium and a conducting medium dispersed in the non-conducting medium,

wherein the conducting medium has a density which permits electrical conduction by percolation of charge carriers through regions of the conducting medium in the conductive fibers.

37. The method of claim 32, wherein identifying the chemical species comprises:

comparing the measured change in electrical impedance to a library of changes for known concentrations of predetermined chemical species.

38. The method of claim 32, wherein identifying the chemical species comprises:

comparing measured changes in electrical impedance for respective groups of fibers to a library of changes for known concentrations of plural predetermined chemical species.

39. The method of claim 32, wherein measuring comprises measuring changes due to at least one of an increase in volumetric size of the fibers by sorption of the chemical species or a change in electrical conduction by a chemical reaction of the chemical species with a material of the fiber.

40. The method of claim 32, wherein the liquid environment is aqueous.

49. A system for sensing a chemical species,

a chemical sensor including,

a plurality of fibers having an electrical impedance which varies upon exposure to a chemical species,

a substrate supporting and electrically isolating the fibers,

a set of electrodes connected to the plurality of fibers at spatially separated points to permit the electrical impedance of the plurality of fibers to be measured, and

said fibers having an electrical impedance which changes due to a change in electrical conduction by a chemical reaction of the chemical species with a material of the fiber;

and

a source of the chemical species which chemically reacts with the material of the fiber to chemically alter the bonds of the material of the fiber after exposure to the chemical species.

52. A chemical sensor comprising:

a plurality of fibers whose electrical impedance varies upon exposure to a chemical species;

a flexible, gas or liquid permeable substrate supporting and electrically isolating the fibers; and

a set of electrodes in electrical contact with the plurality of fibers at spatially separated points to permit the electrical impedance of the plurality of fibers to be measured,

wherein the electrodes are disposed on the plurality of fibers.

53. The sensor of claim 52, wherein

the fibers comprise a non-conducting medium and an elongated conducting additive dispersed in the non-conducting medium, and

the elongated conducting additive has a density which permits electrical conduction by percolation of charge carriers through the conductive fibers.

54. The sensor of claim 53, wherein the elongated conducting additive comprises carbon nanotubes.

55. The sensor of claim 52, wherein chemical species chemically react with the material of the fiber to chemically alter the bonds of the material of the fiber after exposure to the chemical species.

56. The sensor of claim 52, wherein the electrodes are printed on the plurality of fibers.

57. The sensor of claim 52, wherein the electrodes are disposed on the substrate.