Apparatus for solid-oxide fuel cell shutdown having a timing circuit and a reservoir

• US 8,053,128 B2
• Filed: 04/10/2008
• Issued: 11/08/2011
• Est. Priority Date: 04/10/2008
• Status: Active Grant

• Current Assignee: Aptiv Technologies AG (Aptiv PLC)
• Original Assignee: Delphi Technologies, Inc. (Aptiv PLC)
• Inventors: Kelly, Sean M., Mergler, Christopher M.
• Primary Examiner(s): Prasad; Chandrika
• Application Number:
  US12/082,334
• Publication Number:
  US 20090258267A1
• Time in Patent Office: 1,307 Days
• Field of Search: 429/442, 429/495, 429/428, 429/488, 429/508, 429/513
• US Class Current: 429/442
• CPC Class Codes: H01M 2008/1293 Fuel cells with solid oxide electrolytes
• CPC Class Codes: H01M 2250/20 Fuel cells in motive systems, e.g. vehicle, ship, plane
• CPC Class Codes: H01M 8/04007 related to heat exchange
• CPC Class Codes: H01M 8/04228 during shut-down
• CPC Class Codes: H01M 8/04231 Purging of the reactants
• CPC Class Codes: H01M 8/04303 applied during shut-down
• CPC Class Codes: H01M 8/04365 of other components of a fuel cell or fuel cell stacks
• CPC Class Codes: H01M 8/04753 of fuel cell reactants
• CPC Class Codes: H01M 8/04955 Shut-off or shut-down of fuel cells
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02T 90/40 Application of hydrogen technology to transportation, e.g. using fuel cells

Abstract

An emergency shutdown apparatus for a solid-oxide fuel cell system, including a fuel cell stack, comprises a reservoir containing a reducing fluid, a valve enabling or preventing flow of the reducing fluid from the reservoir to the fuel cell stack, a timing circuit operating and controlling the valve, and a battery powering the timing circuit. The apparatus for an emergency system shutdown is able to operate independently of the main power plant and does not require any active control from the solid-oxide fuel cell system. The disclosed apparatus is entirely a stand-alone component that may be added to any conventional solid-oxide fuel cell system. The apparatus in accordance with the invention can be recharged, allowing the same hardware to be used over and over, however, a disposable unit could be used if found to be desirable.

Claims

1. An emergency shutdown apparatus for a solid-oxide fuel cell system including a fuel cell stack, the apparatus comprising:

a reservoir containing a reducing fluid;

a valve enabling or preventing flow of said reducing fluid from said reservoir to said fuel cell stack;

a timing circuit operating and controlling said valve; and

a power source powering said timing circuit.

2. The apparatus of claim 1, wherein the power source is a battery.

3. The apparatus of claim 1, wherein the power source is a rechargeable battery.

4. The apparatus of claim 1, further including a relay positioned between said power source and said timing circuit, wherein said relay enables activation of said timing circuit.

5. The apparatus of claim 4, wherein said relay is a normally closed relay, wherein said relay is opened by a signal from said fuel cell system, and wherein said relay closes when said signal is lost.

6. The apparatus of claim 1, further including a temperature sensor that detects a temperature of said fuel cell stack, wherein said temperature sensor disables operation of said timing circuit when said temperature of said fuel cell stack reaches a prescribed set point.

7. The apparatus of claim 6, wherein said prescribed set point is a temperature below an oxidation temperature of said fuel cell stack.

8. The apparatus of claim 1, further including a second relay activated by a temperature sensor at a calibrated threshold, wherein said second relay disables operation of said timing circuit.

9. The apparatus of claim 1, wherein said flow of said reducing fluid is intermittent.

10. The apparatus of claim 1, wherein said timing circuit pulses said valve, and wherein said timing circuit opens said valve for a first prescribed period of time and closes said valve for a second prescribed period of time in an alternating fashion.

11. The apparatus of claim 1, wherein said timing circuit pulses said valve at a fixed rate.

12. The apparatus of claim 1, wherein said valve is a solenoid actuated valve, and wherein said solenoid is activated by a voltage provided by said timing circuit.

13. A solid-oxide fuel cell power plant, comprising:

a solid-oxide fuel cell system including at least one solid-oxide fuel cell stack having a plurality of anodes; and

an emergency shutdown apparatus providing a flow of a reducing fluid to said anodes when activated;

wherein said emergency shutdown apparatus is activated concurrently with an emergency shutdown of said fuel cell system.

14. The solid-oxide fuel cell power plant of claim 13, wherein said flow of reducing fluid is intermittent.

15. The solid-oxide fuel cell power plant of claim 13, wherein said emergency shutdown apparatus includes a timing circuit that is powered by a battery, wherein said timing circuit pulses a valve, and wherein said valve enables and prevents said flow of said reducing fluid for prescribed periods of time in an alternating fashion.

16. The solid-oxide fuel cell power plant of claim 13, wherein said reducing fluid is stored in a reservoir, wherein said reservoir is refillable.

17. The solid-oxide fuel cell power plant of claim 13, wherein said reducing fluid is stored in a reservoir, wherein said reservoir is exchangeable.

18. The solid-oxide fuel cell power plant of claim 13, wherein said reducing fluid is a reducing gas mixture.

19. The solid-oxide fuel cell power plant of claim 13, wherein said reducing fluid is reformate produced during normal operation of said solid-oxide fuel cell system, and wherein said reformate is pumped by said solid-oxide fuel cell system into a reservoir of said emergency shutdown apparatus to fill and refill said reservoir.

20. The solid-oxide fuel cell power plant of claim 13, wherein a relay positioned between a battery and a timing circuit activates said emergency shutdown apparatus, wherein said relay closes when a signal from said solid-oxide fuel cell system is lost upon emergency shutdown.

21. The solid-oxide fuel cell power plant of claim 13, wherein a temperature sensor that detects the temperature of said solid-oxide fuel cell stack deactivates said emergency shutdown apparatus when a calibrated threshold is reached.

22. The solid-oxide fuel cell power plant of claim 13, wherein a state of a reservoir containing said reducing fluid is sensed, and wherein timing of said flow of said reducing fluid is adjusted accordingly.

23. A method for preventing oxidation of anodes contained in a fuel cell stack during an emergency shutdown of a solid-oxide fuel cell system, comprising the steps of:

activating a timing circuit that controls a valve concurrently to said emergency shutdown; and

pulsing said valve with said timing circuit to enable and disable flow of a reducing fluid from a reservoir to said anodes for prescribed periods of time in an alternating fashion.

24. The method of claim 23, further comprising the steps of:

providing a signal from said fuel cell system to open a normally closed relay during normal operation of said fuel cell system at elevated temperatures;

closing said relay when said signal is lost upon an emergency shutdown of said fuel cell system; and

powering said timing circuit with a battery.

25. The method of claim 23, further comprising the steps of:

using reformate produced during normal operation of said fuel cell system as said reducing fluid; and

filling and refilling said reservoir with said reformate during normal operation of said fuel cell system.

26. The method of claim 23, further comprising the steps of:

sensing a state of said reservoir; and

adjusting timing of said valve accordingly.