Autoclave with underflow dividers

• US 8,061,888 B2
• Filed: 03/14/2007
• Issued: 11/22/2011
• Est. Priority Date: 03/17/2006
• Status: Expired due to Fees

• Current Assignee: Barrick Gold Corporation
• Original Assignee: Barrick Gold Corporation
• Inventors: Ji, Jinxing, King, James A.
• Primary Examiner(s): SOOHOO, TONY GLEN
• Assistant Examiner(s): Janca; Andrew
• Application Number:
  US11/686,165
• Publication Number:
  US 20070217285A1
• Time in Patent Office: 1,714 Days
• Field of Search: 757/11, 757/44, 366/291, 366/155.1, 366/155.2, 423/41, 422/226, 422/228
• US Class Current: 366/155.1
• CPC Class Codes: B01F 27/2322 with parallel axes
• CPC Class Codes: B01F 27/90 with paddles or arms
• CPC Class Codes: B01F 33/81 Combinations of similar mixers, e.g. with rotary stirring devices in two or more receptacles
• CPC Class Codes: B01F 33/813 mixing simultaneously in two or more mixing receptacles
• CPC Class Codes: B01F 35/52 Receptacles with two or more compartments
• CPC Class Codes: B01J 19/006 Baffles
• CPC Class Codes: B01J 2219/00768 vertical
• CPC Class Codes: B01J 2219/182 horizontal
• CPC Class Codes: B01J 3/042 in the form of a tube

Abstract

The present invention is directed to a multi-compartment autoclave using inter-compartment dividers having one or more underflow openings for passing a feed stream between compartments.

Claims

1. A method for processing a feed stream, comprising:

(a) introducing the feed stream into a stirred tank reactor, the feed stream being a slurry of solid metal-containing particles, the stirred tank reactor comprising a plurality of compartments, a plurality of agitators positioned in the plurality of compartments, and a plurality of dividers separating the plurality of compartments, each of the dividers including at least one underflow opening;

(b) introducing a molecular oxygen-containing gas into the stirred tank reactor; and

(c) passing at least most of the feed stream between sets of adjacent compartments through the at least one underflow opening in the respective divider separating the adjacent compartments, wherein a cumulative cross-sectional area of the at least one underflow opening in each of the dividers is different from a cumulative cross-sectional area of the at least one underflow opening in each of the other dividers to maintain a difference in liquid levels between sets of adjacent compartments in the range of from about 5 to about 150 mm.

2. The method of claim 1, wherein each of a number of the dividers are higher than a feed stream level in an adjacent, upstream compartment so that the feed stream does not overflow the corresponding divider, wherein the cumulative cross-sectional area of the at least one underflow opening ranges from about 0.06 m² to about 1.50 m², wherein a flow volume between adjacent compartments ranges from about 200 m³/hour to about 800 m³/hour, and wherein a height-to-diameter ratio of each of the dividers is at least about 0.80.

3. The method of claim 1, wherein, in each of the dividers, the cumulative cross-sectional area of the at least one underflow opening ranges from about 0.06 to about 1.50 m² and wherein a flow volume between adjacent compartments ranges from about 200 to about 800 m³/hour.

4. The method of claim 3, wherein cumulative cross-sectional area of at least one underflow opening in a first divider at an input end of the reactor is less than a cumulative cross-sectional area of the at least one underflow opening in a second divider, the second divider being nearer an output end of the reactor than the first divider.

5. The method of claim 1, wherein, in each of the plurality of dividers, the at least one underflow opening is positioned at or below an uppermost impeller blade of the agitator in an adjacent, upstream compartment and wherein a head drop between adjacent compartments is maintained in a range from about 5 to about 50 mm.

6. The method of claim 1, wherein, in each of the plurality of dividers, the at least one underflow opening is positioned above a bottom of the stirred tank reactor at a height that is no more than about 66% of the liquid level in an adjacent, upstream compartment and wherein, in a selected divider, a ratio of cumulative cross sectional area of the at least one opening to feed stream flowrate through the at least one opening ranges from about 1 to about 7.

7. The method of claim 1, wherein agitators in a plurality of sets of adjacent compartments counter-rotate and wherein a liquid level in a first compartment ranges between about 5 to about 50 mm higher than a liquid level in an adjacent second compartment.

8. The method of claim 7, wherein, in the first compartment, a first agitator rotates clockwise and the at least one underflow opening in a first divider, separating the first compartment from the adjacent second compartment, is positioned to the right of a longitudinal center line of the stirred tank reactor and wherein, in the second compartment, a second agitator rotates counterclockwise and the at least one underflow opening in a second divider separating the second compartment from an adjacent third compartment, is positioned to the left of the longitudinal center line of the stirred tank reactor.

9. The method of claim 1, wherein a final downstream divider in the stirred tank reactor is free of at least one underflow opening and is configured as an overflow divider.

10. The method of claim 1, wherein at least one underflow opening in a first divider separating a first compartment from an adjacent second compartment is positioned to the right of a longitudinal axis and the at least one underflow opening in a second divider separating the second compartment from an adjacent third compartment is positioned to the left of the longitudinal axis of the stirred tank reactor.

11. A method for processing a metal sulfide-containing material, comprising:

(a) introducing into a stirred tank reactor an input slurry comprising a comminuted metal sulfide-containing material, the stirred tank reactor comprising a plurality of compartments for receiving the input slurry, a plurality of agitators positioned in the plurality of compartments for mixing the input slurry, and a plurality of dividers separating the plurality of compartments, each of the dividers including at least one underflow opening for passing the input slurry from compartment to compartment;

(b) introducing a molecular oxygen-containing gas into the stirred tank reactor;

(c) oxidizing the metal sulfide-containing material in the input slurry to provide a product slurry comprising the oxidized metal-containing material, wherein the oxidizing step comprises the substep of passing at least most of the slurried material between sets of adjacent compartments through the at least one underflow opening in the divider separating the adjacent compartments; and

(d) thereafter recovering the metal from the product slurry, wherein;

the plurality of dividers includes first and second dividers;

the plurality of compartments comprises first, second, and third compartments;

the first divider separates the first and second compartments;

the second divider separates the second and third compartments;

the third compartment is nearer an output end of the stirred tank reactor than the first and second compartments;

the second compartment is positioned between the first and third compartments; and

a first cumulative cross-sectional area of the at least one underflow opening in the first divider is less than a second cumulative cross-sectional area of the at least one underflow opening in the second divider, whereby head drops between the first and second compartments and between the second and third compartments are maintained in a range from about 5 to about 50 mm.

12. The method of claim 11, wherein the metal is at least one of a base metal, a platinum group metal, and a precious metal, wherein each of the dividers are higher than a feed stream level in an adjacent, upstream compartment, wherein the cumulative cross-sectional area of the at least one underflow opening ranges from about 0.06 m² to about 1.50 m², wherein a flow volume between adjacent compartments ranges from about 200 m³/hour to about 800 m³/hour, and wherein a height-to-diameter ratio of each of the dividers is at least about 0.80.

13. The method of claim 11, wherein, in each of the dividers, the cumulative cross-sectional area of the at least one underflow opening ranges from about 0.06 to about 1.50 m², wherein a flow volume between adjacent compartments ranges from about 200 to about 800 m³/hour, and wherein, in each of the plurality of dividers, a ratio of the cumulative cross-sectional area of the respective at least one underflow opening in each of the dividers to slurry flowrate through the respective at least one underflow opening ranges from about 1.0 to about 7.0.

14. The method of claim 11, wherein, in each of the plurality of dividers, the at least one underflow opening is positioned above a bottom of the stirred tank reactor at a height that is no more than about 66% of the liquid level in the adjacent, upstream compartment and wherein the cumulative cross-sectional areas between the respective at least one underflow opening in the first and second dividers are within about 25% of one another.

15. The method of claim 11, wherein, in the first compartment, a first agitator rotates clockwise and the at least one underflow opening in the first divider, separating the first compartment from the adjacent second compartment, is positioned to the right of a longitudinal axis of the stirred tank reactor and wherein, in the second compartment, a second agitator rotates counterclockwise and the at least one underflow opening in the second divider, separating the second compartment from the adjacent third compartment, is positioned to the left of the longitudinal axis of the stirred tank reactor.

16. The stirred tank reactor of claim 11, wherein a final downstream divider in the stirred tank reactor is free of at least one underflow opening and is configured as an overflow divider.

17. A method, comprising:

providing an autoclave comprising;

(a) a plurality of compartments comprising adjacent at least first and second compartments;

(b) a plurality of agitators for mixing a feed stream, the agitators being positioned in the plurality of compartments, the feed stream comprising a comminuted metal sulfide-containing material; and

(c) a plurality of dividers separating the plurality of compartments, each of the dividers including at least one underflow opening for passing the feed stream from compartment to compartment;

inputting the feed stream into the first compartment, the feed steam flowing sequentially from compartment to compartment;

introducing a molecular oxygen-containing gas into the autoclave;

oxidizing the metal sulfide-containing material in the feed stream to provide a product slurry comprising the oxidized metal-containing material, wherein the oxidizing step comprises the substep of passing at least most of the feed stream between sets of adjacent compartments through the at least one underflow opening in the divider separating the adjacent compartments; and

thereafter recovering the metal from the product slurry, wherein;

at least about 75% of the feed stream passes between adjacent pairs of the plurality of compartments by passing through the at least one underflow opening in a respective divider separating the adjacent pairs of compartments;

a first divider separates the first and second compartments;

a second divider separates the second compartment and a third compartment;

the third compartment is nearer an output end of the autoclave than the first and second compartments;

the second compartment is positioned between the first and third compartments; and

a first cumulative cross-sectional area of the at least one underflow opening in the first divider is less than a second cumulative cross-sectional area of the at least one underflow opening in the second divider, whereby a first liquid level in the first compartment is higher than a second liquid level in the second compartment and the second liquid level is higher than a third liquid level in the third compartment.

18. The method of claim 17, wherein a final downstream divider in the autoclave is free of at least one underflow opening and is configured as an overflow divider.

19. The method of claim 17, wherein at least one underflow opening in the first divider separating the first compartment from the adjacent second compartment is positioned to the right of a longitudinal axis and the at least one underflow opening in the second divider separating the second compartment from the adjacent third compartment is positioned to the left of the longitudinal axis of the autoclave.

20. The method of claim 17, wherein each of the plurality of the dividers is higher than a feed stream level in a respective adjacent, upstream compartment so that the feed stream does not overflow the corresponding divider and wherein a height-to-diameter ratio of each of the dividers is at least about 0.80.

21. The method of claim 17, wherein, in each of the plurality of dividers, the cumulative cross-sectional area of the at least one underflow opening ranges from about 0.06 m² to about 1.50 m² and wherein a flow volume between adjacent compartments ranges from about 200 m³/hour to about 800 m³/hour.

22. The method of claim 21, wherein the cumulative cross-sectional area of the at least one underflow opening in each of the plurality of dividers is different, with the cumulative cross-sectional area of the at least one underflow opening in the first divider at the input end of the autoclave being less than the cumulative cross-sectional area of the at least one underflow opening in the second divider, the second divider being nearer the output end of the autoclave than the first divider.

23. The method of claim 17, wherein, in each of the plurality of dividers, the at least one underflow opening is positioned at or below an uppermost impeller blade of the agitator in the adjacent, upstream compartment and wherein a head drop between adjacent pairs of compartments is maintained in a range from about 25 to about 100 mm.

24. The method of claim 17, wherein, in each of the plurality of dividers, the at least one underflow opening is positioned above a bottom of the autoclave at a height that is no more than about 33% of the liquid level in the adjacent, upstream compartment and wherein, in a selected divider, a ratio of cumulative cross sectional area of the at least one opening to feed stream flowrate through the at least one opening ranges from about 1 to about 7.

25. The method of claim 17, wherein agitators in a plurality of sets of adjacent compartments counter-rotate and wherein a liquid level in the first compartment ranges between about 5 to about 150 mm higher than a liquid level in the adjacent second compartment.

26. The method of claim 17, wherein, in the first compartment, a first agitator rotates clockwise and the at least one underflow opening in the first divider, separating the first compartment from the adjacent second compartment, is positioned to the right of a longitudinal axis of the autoclave and wherein, in the second compartment, a second agitator rotates counterclockwise and the at least one underflow opening in the second divider, separating the second compartment from the adjacent third compartment, is positioned to the left of the longitudinal axis of the autoclave.