Process for the regeneration of an ion exchange resin using sulfurous acid

• US 8,063,112 B2
• Filed: 12/08/2008
• Issued: 11/22/2011
• Est. Priority Date: 12/08/2008
• Status: Active Grant

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Cansolv Technologies Inc. (Shell Plc)
• Inventors: Campbell, Matthew, Sarlis, John, Godhwani, Vijay Bhambhani, Infantino, Melina
• Primary Examiner(s): Choi, Ling
• Assistant Examiner(s): WANG, CHUN CHENG
• Application Number:
  US12/329,938
• Publication Number:
  US 20100144908A1
• Time in Patent Office: 1,079 Days
• Field of Search: 521/26, 29/26
• US Class Current: 521/26
• CPC Class Codes: B01D 2252/2041 Diamines
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1481 Removing sulfur dioxide or sulfur trioxide
• CPC Class Codes: B01J 49/53 for cationic exchangers
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A diamine absorbent that contains heat stable salts is regenerated using an ion exchange process wherein the cation exchange resin is regenerated using sulfurous acid reflux.

Claims

1. A process for the regeneration of an acidic cation exchange resin used to treat an acid gas absorbent stream comprising at least one alkali metal salt, the process comprising:

(a) obtaining the acid gas absorbent stream from an acid gas recovery unit;

(b) contacting the acid gas absorbent stream with an acidic cation exchange resin and generating a cation reduced acid gas absorbent stream; and

,

(c) regenerating the acidic cation exchange resin using a sulfurous acid reflux obtained from the acid gas recovery unit and producing a spent regeneration stream

wherein step (c) comprises a single chemical treatment step.

2. The process according to claim 1, wherein the sulfurous acid reflux is obtained from a steam stripping unit of the acid gas recovery unit.

3. The process according to claim 1, wherein a feed gas to the acid gas recovery unit includes SO2 and the sulfurous acid is generated from the SO2 captured by an acid gas absorbent stream from the feed gas in the acid gas recovery unit.

4. The process according to claim 1, wherein the sulfurous acid reflux has a concentration of sulfurous acid of from about 1 to about 5 wt %.

5. The process according to claim 1, wherein the alkali metal salt is an alkali metal salt of at least one strong acid.

6. The process according to claim 5, wherein the strong acid comprises at least one of sulfuric acid, nitric acid or hydrochloric acid.

7. The process according to claim 1, wherein the alkali metal comprises sodium or potassium.

8. The process according to claim 1, wherein the acidic cation exchange resin is a strong acid resin.

9. The process according to claim 1, further recycling the cation reduced acid gas absorbent stream to the acid gas recovery unit.

10. The process according to claim 1, wherein the acid gas recovery unit includes an absorption unit including an absorber and an absorbent regeneration unit that includes a steam stripping column and the process further comprises obtaining the acid gas absorbent stream from downstream of the steam stripping column and upstream of the absorber.

11. The process according to claim 1, wherein the spent regeneration stream comprises a first portion and a second portion and the process further comprises recycling only the first portion of the spent regeneration stream to the acid gas recovery unit for use as part of an acid gas absorption solution.

14. The process according to claim 1, further comprising rinsing the acidic cation exchange resin with water and generating an absorbent rich rinse stream prior to contacting the acidic cation exchange resin with the acid gas absorbent stream.

15. The process according to claim 14, wherein the absorbent rich rinse stream is recycled back to the acid gas recovery unit for use as part of an acid gas absorption stream.

17. The process according to claim 1, further comprising utilizing the acidic cation exchange resin to treat an additional amount of the acid gas absorbent stream as the next process step subsequent to step (c) of claim 1.

20. The process according to claim 1, further comprising contacting the acid gas absorbent stream with a basic anion exchange resin in the hydroxide form and generating an anion lean acid gas absorbent stream and using at least a portion of the anion lean acid gas absorbent stream in step (b) of claim 1.

12. A process for the regeneration of an acidic cation exchange resin used to treat an acid gas absorbent stream comprising at least one alkali metal salt, the process comprising:

(a) obtaining the acid gas absorbent stream from an acid gas recovery unit;

(b) contacting the acid gas absorbent stream with an acidic cation exchange resin and generating a cation reduced acid gas absorbent stream; and

,

(c) regenerating the acidic cation exchange resin using a sulfurous acid reflux obtained from the acid gas recovery unit and producing a spent regeneration stream

wherein the spent regeneration stream comprises a first portion and a second portion and the process further comprises recycling only the first portion of the spent regeneration stream to the acid gas recovery unit for use as part of an acid gas absorption solution and wherein the acid gas absorbent stream comprises a diamine absorbent and the first portion of the spent regeneration stream has a diamine concentration of about 1000 ppm to about 30000 ppm.

13. A process for the regeneration of an acidic cation exchange resin used to treat an acid gas absorbent stream comprising at least one alkali metal salt, the process comprising:

(a) obtaining the acid gas absorbent stream from an acid gas recovery unit;

(b) contacting the acid gas absorbent stream with an acidic cation exchange resin and generating a cation reduced acid gas absorbent stream; and

,

(c) regenerating the acidic cation exchange resin using a sulfurous acid reflux obtained from the acid gas recovery unit and producing a spent regeneration stream

wherein the spent regeneration stream comprises a first portion and a second portion and the process further comprises recycling only the first portion of the spent regeneration stream to the acid gas recovery unit for use as part of an acid gas absorption solution and wherein the second portion of the spent regeneration stream comprises alkali metal salts having a concentration of about 250 ppm to about 7000 ppm and the second portion is directed to waste treatment.

16. A process for the regeneration of an acidic cation exchange resin used to treat an acid gas absorbent stream comprising at least one alkali metal salt, the process comprising:

(a) obtaining the acid gas absorbent stream from an acid gas recovery unit;

(b) contacting the acid gas absorbent stream with an acidic cation exchange resin and generating a cation reduced acid gas absorbent stream; and

,

(c) regenerating the acidic cation exchange resin using a sulfurous acid reflux obtained from the acid gas recovery unit and producing a spent regeneration stream wherein a sufficient amount of sulfurous acid reflux is utilized to regenerate the acidic cation exchange resin that the acidic cation exchange resin is ready for use to treat an additional amount of the acid gas absorbent stream in the absence of a final water rinse.

18. A process for the regeneration of an acidic cation exchange resin used to treat an acid gas absorbent stream comprising at least one alkali metal salt, the process comprising:

(a) obtaining the acid gas absorbent stream from an acid gas recovery unit;

(b) contacting the acid gas absorbent stream with an acidic cation exchange resin and generating a cation reduced acid gas absorbent stream; and

,

(c) regenerating the acidic cation exchange resin using a sulfurous acid reflux obtained from the acid gas recovery unit and producing a spent regeneration stream wherein the acid gas absorbent stream comprises a diamine absorbent having a concentration of heat stable salts that is less than 1 equivalent/mole of diamine.

19. The process according to claim 18, wherein the concentration is less than about 0.7 equivalent/mole of diamine.

21. A process for the regeneration of an acidic cation exchange resin used to treat an acid gas absorbent stream comprising at least one alkali metal salt, the process comprising:

(a) obtaining the acid gas absorbent stream from an acid gas recovery unit;

(b) contacting the acid gas absorbent stream with an acidic cation exchange resin and generating a cation reduced acid gas absorbent stream;

(c) regenerating the acidic cation exchange resin using a sulfurous acid reflux obtained from the acid gas recovery unit and producing a spent regeneration stream; and

,

(d) contacting the acid gas absorbent stream with a basic anion exchange resin in the hydroxide form and generating an anion lean acid gas absorbent stream and using at least a portion of the anion lean acid gas absorbent stream in step (b) wherein the portion of the anion lean acid gas absorbent stream used in step (b) has a concentration of heat stable salts that is less than 1 equivalent/mole of diamine.