Glass package that is hermetically sealed with a frit and method of fabrication
First Claim
1. A frit comprising a non-lead based glass doped with at least one transition metal, and a coefficient of thermal expansion (CTE) lowering filler.
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Abstract
A hermetically sealed glass package and method for manufacturing the hermetically sealed glass package are described herein using an OLED display as an example. Basically, the hermetically sealed OLED display is manufactured by providing a first substrate plate and a second substrate plate and depositing a frit onto the second substrate plate. OLEDs are deposited on the first substrate plate. An irradiation source (e.g., laser, infrared light) is then used to heat the frit which melts and forms a hermetic seal that connects the first substrate plate to the second substrate plate and also protects the OLEDs. The frit is glass that was doped with at least one transition metal and possibly a CTE lowering filler such that when the irradiation source heats the frit, it softens and forms a bond. This enables the frit to melt and form the hermetic seal while avoiding thermal damage to the OLEDs.
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Citations
41 Claims
- 1. A frit comprising a non-lead based glass doped with at least one transition metal, and a coefficient of thermal expansion (CTE) lowering filler.
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16. A frit comprising a coefficient of thermal expansion (CTE) lowering filler and a glass comprising:
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K2O (0-10 mole %) Fe2O3 (0-20 mole %) Sb2O3 (0-40 mole %) P2O5 (20-40 mole %) V2O5 (30-60 mole %) TiO2 (0-20 mole %) Al2O3 (0-5 mole %) B2O3 (0-5 mole %) WO3 (0-5 mole %) Bi2O3 (0-5 mole %). - View Dependent Claims (17, 18, 19, 20, 21, 22, 29)
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23. A frit comprising a coefficient of thermal expansion (CTE) lowering filler and a glass comprising:
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K2O (0-10 mole %) Fe2O3 (0-20 mole %) Sb2O3 (0-20 mole %) ZnO (0-20 mole %) P2O5 (20-40 mole %) V2O5 (30-60 mole %) TiO2 (0-20 mole %) Al2O3 (0-5 mole %) B2O3 (0-5 mole %) WO3 (0-5 mole %) Bi2O3 (0-5 mole %). - View Dependent Claims (24, 25, 26, 27, 28)
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30. A frit comprising a coefficient of thermal expansion (CTE) lowering filler and a glass consisting essentially of:
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Sb2O3 (7.4 mole %) ZnO (17.6 mole %) P2O5 (16.5 mole %) V2O5 (46.6 mole %) TiO2 (1.0 mole %) Al2O3 (1.0 mole %). - View Dependent Claims (31)
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32. A fit comprising a coefficient of thermal expansion (CTE) lowering filler and a glass comprising at least one transition metal selected from the group of glasses consisting of a titano-vanadium glass, an iron-vanadium glass, a zinc-vanadium glass, a Sn—
- Zn-phosphate glass, a mixed alkali zinc-phosphate glass, a vanadium-phosphate glass, a Pb-borate glass, and a mixed alkali zinc-phosphate glass with vanadium and lead, and wherein the frit has a coefficient of thermal expansion (CTE) less than about 140×
10−
7/°
C. between about room temperature and 250°
C., and a glass transition temperature Tg less than about 350°
C. - View Dependent Claims (33, 34, 35, 36, 37, 38, 39, 40, 41)
- Zn-phosphate glass, a mixed alkali zinc-phosphate glass, a vanadium-phosphate glass, a Pb-borate glass, and a mixed alkali zinc-phosphate glass with vanadium and lead, and wherein the frit has a coefficient of thermal expansion (CTE) less than about 140×
Specification