Apparatus and method for removing arsenic and inorganic compositions from water

• US 8,066,940 B2
• Filed: 06/28/2007
• Issued: 11/29/2011
• Est. Priority Date: 06/30/2006
• Status: Expired due to Fees

• Current Assignee: ZUCO Water LLC
• Original Assignee: Zuvo Water LLC
• Inventors: Denkewicz, Raymond P. Jr., Engelhard, Rolf
• Primary Examiner(s): Griffin; Walter
• Assistant Examiner(s): Allen; Cameron J
• Application Number:
  US11/770,504
• Publication Number:
  US 20080302735A1
• Time in Patent Office: 1,615 Days
• Field of Search: 21074801-7481, 210/760, 210/192, 210/758, 210/784.12, 422/22, 422/24, 422/186.3, 422/186
• US Class Current: 422/24
• CPC Class Codes: C02F 1/325 Irradiation devices or lamp constructions
• CPC Class Codes: C02F 1/722 Oxidation by peroxides
• CPC Class Codes: C02F 1/78 with ozone C02F1/4672 takes precedence
• CPC Class Codes: C02F 2101/103 Arsenic compounds
• CPC Class Codes: C02F 2101/20 Heavy metals or heavy metal compounds
• CPC Class Codes: C02F 2201/3221 Lamps suspended above a water surface or pipe

Abstract

Simultaneous application of ozone and ultraviolet light (UV185 and UV254) in water to be purified will create hydroxyl radicals, which combination will cause conversion of AS (III) that may be present to As (V), oxidation of inorganic matter such as manganese, sulfur, phosphorus and organic matter and provide virucidal and germicidal effects to purify the water.

Claims

1. Apparatus for converting As (III) to As (V) in water to be purified, said apparatus comprising in combination:

a) a tank for receiving water to be purified through an inlet conduit and for discharging purified water through an outlet conduit, said tank including a lower water section under pressure and an upper air space under pressure commensurate in pressure with that present in the lower water section;

b) a pump for conveying water from the lower water section into the upper air section;

c) a nozzle for discharging the water from said pump into the upper air section to entrain air in the discharged water;

d) a tube extending from the upper air section into the lower water section for directing the air entrained water from said nozzle into the lower water section and for causing turbulent flow of water in the lower water section;

e) a UV lamp disposed in the upper air section for converting oxygen molecules in the air to ozone molecules for conveyance with the air into entrainment with the water discharged from said nozzle; and

f) said UV lamp irradiating the water to provide a virucidal and germicidal effect on any micro organisms present in the water and for producing hydroxyl radicals in the water upon irradiation of the ozone molecules in the water, which, in combination result in conversion of As (III) that may be present to As (V).

2. The apparatus as set forth in claim 1, including a further inlet conduit for introducing hydrogen peroxide into the water to enhance production of hydroxyl radicals in the presence of UW radiation and ozone.

3. The apparatus as set forth in claim 1 wherein said UV lamp provides radiation of ultraviolet light having a wavelength of about 185 nm and a wavelength of about 254 nm.

4. The apparatus as set forth in claim 1, including a vent extending into the upper air section and having an inlet for evacuating air within the upper air section until the water level in the lower water section rises above said inlet.

5. Apparatus for converting As (III) to As (V) in water to be purified, said apparatus comprising in combination:

a) a tank for receiving water to be purified through an inlet conduit and for discharging purified water through an outlet conduit, said tank including a lower water section under pressure and an upper air space under pressure commensurate in pressure with that present in the lower water section;

b) a pump for conveying water from the lower water section into the upper air section;

c) a nozzle for discharging the water from said pump into the upper air section to entrain air in the discharged water;

d) a tube extending from the upper air section into the lower water section for directing the air entrained water from said nozzle into the lower water section and for causing turbulent flow of water in the lower water section;

e) a UV lamp disposed in the lower water section;

f) said tube extending into the lower water section to a point in proximity with said UV lamp to discharge air entrained water in proximity to said UV lamp;

g) said UV lamp converting oxygen molecules in the air entrained water to ozone molecules; and

h) said UV lamp irradiating the water to provide a virucidal and germicidal effect on any micro organisms present in the water and for producing hydroxyl radicals in the water upon irradiation of the ozone molecules in the water, which, in combination, result in conversion of As (III) that may be present to As (V).

6. The apparatus as set forth in claim 5, including further inlet conduit for introducing hydrogen peroxide into the water to enhance production of hydroxyl radicals in the presence of UV radiation and ozone.

7. The apparatus as set forth in claim 5 wherein said UV lamp provides radiation of ultraviolet light having a wavelength of about 185 nm and a wavelength of about 254 nm.

8. The apparatus as set forth in claim 5 including a shroud for enclosing said UV lamp.

9. Apparatus for converting As (III) to As (V) in water to be purified, said apparatus comprising in combination:

a) a water tank having an inlet for receiving water to be purified and an outlet for discharging purified water;

b) a sleeve of ultraviolet light transmissive matter disposed in said water tank;

c) a first UV lamp disposed within said sleeve for irradiating the water surrounding said sleeve;

d) an annular space disposed between said first UV lamp and said sleeve;

e) a source of oxygen containing gas under pressure for conveying the gas through said annular space;

f) said first UV lamp irradiating the gas flowing through said annular space and converting oxygen molecules into ozone molecules;

g) a chamber having an inlet for receiving ozone enriched gas from said annular passageway and including an outlet for discharging the ozone enriched gas, said chamber having significantly greater cross sectional area than said annular space resulting in a much slower flow rate from said inlet to said outlet relative to the flow rate through said annular sleeve;

h) a second UV lamp disposed in said chamber for converting oxygen molecules into ozone molecules at a rate greater than the rate in said annular space due to the slower flow rate of the gas; and

i) a conduit for conveying the ozone enriched gas into the water flowing into said tank resulting in irradiation of the ozone molecules within said tank by said second UV lamp to produce hydroxyl radicals to convert As (III) that may be present to As (V).

10. The apparatus as set forth in claim 9 wherein said first and second UV lamps are embodied by a single UV lamp that extends from within said sleeve into said chamber.

11. The apparatus as set forth in claim 9, including a venturi for entraining the ozone enriched gas with the water flowing into said tank.

12. The apparatus as set forth in claim 9, including a source of hydrogen peroxide and a conduit for introducing the hydrogen peroxide into the water flowing into said tank.

13. The apparatus as set forth in claim 12 wherein said conduit for introducing hydrogen peroxide is down stream of the point of introduction of the ozone enriched gas into the water.

14. The apparatus as set forth in claim 11, including a source of hydrogen peroxide and a conduit for introducing the hydrogen peroxide into the water flowing into said tank.

15. The apparatus as set forth in claim 14 wherein said conduit for introducing hydrogen peroxide is down stream of said venturi.

16. The apparatus as set forth in claim 9 wherein the gas is air.

17. A method for converting As (III) in water to As (V), said method comprising the steps of:

a) irradiating the water flowing into a tank with UV from a first UV lamp;

b) conveying an oxygen containing gas through an annular space defined by the first UV lamp and a surrounding sleeve to convert oxygen molecules in the gas to ozone molecules;

c) discharging the ozone enriched gas into a chamber;

d) further irradiating the ozone enriched gas in the chamber with a second UV lamp to convert further oxygen molecules to ozone molecules;

e) reducing the flow rate of the ozone enriched gas through the chamber to increase the time of exposure of the ozone enriched gas to irradiation from the second UV lamp;

f) further conveying the ozone enriched gas from the chamber into the water flowing into the tank; and

g) producing hydroxyl radicals in the water within the tank by irradiating the ozone with UV to convert As (III) that may be present to As (V).

18. The method as set forth in claim 17, including entraining the ozone enriched gas with the water flowing into the tank.

19. The method as set forth in claim 18 wherein said step of entraining is carried out by a venturi.

20. The method as set forth in claim 17, including the step of injecting hydrogen peroxide into the water in the tank to enhance production of hydroxyl radicals.

21. The method as set forth in claim 18 wherein said steps of irradiating with the first UV lamp and further irradiating by a second UV lamp are carried out by a common UV lamp extending from within the sleeve into the chamber.

22. Apparatus for oxidizing dissolved minerals, including iron, manganese, phosphorus and sulfur, that may be present in water to be purified, said apparatus comprising in combination:

a) a tank for receiving water to be purified through an inlet conduit and for discharging purified water through an outlet conduit, said tank including a lower water section under pressure and an upper air space under pressure commensurate in pressure with that present in the lower water section;

b) a pump for conveying water from the lower water section into the upper air section;

c) a nozzle for discharging the water from said pump into the upper air section to entrain air in the discharged water;

d) a tube extending from the upper air section into the lower water section for directing the air entrained water from said nozzle into the lower water section and for causing turbulent flow of water in the lower water section;

e) a UV lamp disposed in the upper air section for converting oxygen molecules in the air to ozone molecules for conveyance with the air into entrainment with the water discharged from said nozzle; and

f) said UV lamp irradiating the water to provide a virucidal and germicidal effect on any micro organisms present in the water and for producing hydroxyl radicals in the water upon irradiation of the ozone molecules in the water, which, in combination result in oxidation of at least some of the dissolved minerals that may be present.

23. The apparatus as set forth in claim 22, including a further inlet conduit for introducing hydrogen peroxide into the water to enhance production of hydroxyl radicals in the presence of UV radiation and ozone.

24. The apparatus as set forth in claim 22 wherein said UV lamp provides radiation of ultraviolet light having a wavelength of about 185 nm and a wavelength of about 254 nm.

25. The apparatus as set forth in claim 22, including a vent extending into the upper air section and having an inlet for evacuating air within the upper air section until the water level in the lower water section rises above said inlet.

26. Apparatus for oxidizing dissolved minerals, including iron, manganese, phosphorous and sulfur, that may be present in water to be purified, said apparatus comprising in combination:

a) a tank for receiving water to be purified through an inlet conduit and for discharging purified water through an outlet conduit, said tank including a lower water section under pressure and an upper air space under pressure commensurate in pressure with that present in the lower water section;

b) a pump for conveying water from the lower water section into the upper air section;

c) a nozzle for discharging the water from said pump into the upper air section to entrain air in the discharged water;

d) a tube extending from the upper air section into the lower water section for directing the air entrained water from said nozzle into the lower water section and for causing turbulent flow of water in the lower water section;

e) a UV lamp disposed in the lower water section;

f) said tube extending into the lower water section to a point in proximity with said UV lamp to discharge air entrained water in proximity to said UV lamp;

g) said UV lamp converting oxygen molecules in the air entrained water to ozone molecules; and

h) said UV lamp irradiating the water to provide a virucidal and germicidal effect on any micro organisms present in the water and for producing hydroxyl radicals in the water upon irradiation of the ozone molecules in the water, which, in combination, result in oxidation of at least some of the dissolved minerals that may be present.

27. The apparatus as set forth in claim 26, including further inlet conduit for introducing hydrogen peroxide into the water to enhance production of hydroxyl radicals in the presence of UV radiation and ozone.

28. The apparatus as set forth in claim 26 wherein said UV lamp provides radiation of ultraviolet light having a wavelength of about 185 nm and a wavelength of about 254 nm.

29. The apparatus as set forth in claim 26 including a shroud for enclosing said UV lamp.

30. Apparatus for oxidizing dissolved minerals, including iron, manganese, phosphorous and sulfur, that may be present in water to be purified, said apparatus comprising in combination:

a) a water tank having an inlet for receiving water to be purified and an outlet for discharging purified water;

b) a sleeve of ultraviolet light transmissive matter disposed in said water tank;

c) a first UV lamp disposed within said sleeve for irradiating the water surrounding said sleeve;

d) an annular space disposed between said first UV lamp and said sleeve;

e) a source of oxygen containing gas under pressure for conveying the gas through said annular space;

f) said first UV lamp irradiating the gas flowing through said annular space and converting oxygen molecules into ozone molecules;

g) a chamber having an inlet for receiving ozone enriched gas from said annular passageway and including an outlet for discharging the ozone enriched gas, said chamber having significantly greater cross sectional area than said annular space resulting in a much slower flow rate from said inlet to said outlet relative to the flow rate through said annular sleeve;

h) a second UV lamp disposed in said chamber for converting oxygen molecules into ozone molecules at a rate greater than the rate in said annular space due to the slower flow rate of the gas; and

i) a conduit for conveying the ozone enriched gas into the water flowing into said tank resulting in irradiation of the ozone molecules within said tank by said second UV lamp to produce hydroxyl radicals to oxidize at least some of the dissolved minerals that may be present.

31. The apparatus as set forth in claim 30 wherein said first and second UV lamps are embodied by a single UV lamp that extends from within said sleeve into said chamber.

32. The apparatus as set forth in claim 30, including a venturi for entraining the ozone enriched gas with the water flowing into said tank.

33. The apparatus as set forth in claim 30, including a source of hydrogen peroxide and a conduit for introducing the hydrogen peroxide into the water flowing into said tank.

34. The apparatus as set forth in claim 33 wherein said conduit for introducing hydrogen peroxide is down stream of the point of introduction of the ozone enriched gas into the water.

35. The apparatus as set forth in claim 32, including a source of hydrogen peroxide and a conduit for introducing the hydrogen peroxide into the water flowing into said tank.

36. The apparatus as set forth in claim 35 wherein said conduit for introducing hydrogen peroxide is down stream of said venturi.

37. The apparatus as set forth in claim 30 wherein the gas is air.

38. A method for oxidizing dissolved minerals, including iron, manganese, phosphorus and sulfur, that may be present, said method comprising the steps of:

a) irradiating the water flowing into a tank with UV from a first UV lamp;

b) conveying an oxygen containing gas through an annular space defined by the first UV lamp and a surrounding sleeve to convert oxygen molecules in the gas to ozone molecules;

c) discharging the ozone enriched gas into a chamber;

d) further irradiating the ozone enriched gas in the chamber with a second UV lamp to convert further oxygen molecules to ozone molecules;

e) reducing the flow rate of the ozone enriched gas through the chamber to increase the time of exposure of the ozone enriched gas to irradiation from the second UV lamp;

f) further conveying the ozone enriched gas from the chamber into the water flowing into the tank; and

g) producing hydroxyl radicals in the water within the tank by irradiating the ozone with UV to oxidize at least some of the dissolved minerals that may be present.

39. The method as set forth in claim 38, including entraining the ozone enriched gas with the water flowing into the tank.

40. The method as set forth in claim 39 wherein said step of entraining is carried out by a venturi.

41. The method as set forth in claim 38, including the step of injecting hydrogen peroxide into the water in the tank to enhance production of hydroxyl radicals.

42. The method as set forth in claim 39 wherein said steps of irradiating with the first UV lamp and further irradiating with the second UV lamp are carried out by a single UV lamp extending from within the sleeve into the chamber.