Thermoplastic holographic media

• US 8,071,260 B1
• Filed: 06/15/2004
• Issued: 12/06/2011
• Est. Priority Date: 06/15/2004
• Status: Active Grant

• Current Assignee: Akonia Holographics, LLC (Apple Inc.)
• Original Assignee: InPhase Technologies Incorporated (hVault, Inc.)
• Inventors: Cole, Michael C., Trentler, Timothy J.
• Primary Examiner(s): ANGEBRANNDT, MARTIN J
• Application Number:
  US10/866,823
• Time in Patent Office: 2,730 Days
• Field of Search: None
• US Class Current: 430/1
• CPC Class Codes: G03H 1/02 Details of features involved during the holographic process; Replication of holograms without interference recording
• CPC Class Codes: G03H 2001/0264 Organic recording material
• CPC Class Codes: G03H 2260/12 Photopolymer
• CPC Class Codes: G11B 7/0065 Recording, reproducing or erasing by using optical interference patterns, e.g. holograms
• CPC Class Codes: G11B 7/24044 for storing optical interference patterns, e.g. holograms; for storing data in three dimensions, e.g. volume storage G11B7/24038 takes precedence
• CPC Class Codes: G11B 7/245 containing a polymeric component
• CPC Class Codes: G11B 7/253 of substrates
• CPC Class Codes: G11B 7/2531 comprising glass
• CPC Class Codes: G11B 7/2533 comprising resins
• CPC Class Codes: G11C 13/042 using information stored in the form of interference pattern

Abstract

The present invention provides an article comprising: a binder component, a polymerizable component; and a photoinitiator component comprising at least one photoinitiator that causes the polymerizable component to form a polymer or co-polymer when a portion of the polymerizable component is exposed to a light source. The present invention also provides a method for making such an article, and a method and a system for holographically recording a spatial light distribution to such an article. The present invention also provides an article comprising: a binder component and a photoactive component, a method of making such an article, a method of recording to such an article and a system for recording to such an article.

Claims

1. An article comprising a holographic recording medium comprising:

a binder component comprising at least one thermoplastic;

a polymerizable component comprising at least one photoactive monomer that is soluble in said binder component, wherein the at least one photoactive monomer is dissolved in said binder component;

a photoinitiator component comprising at least one photoinitiator that causes said polymerizable component to form a polymer or co-polymer when a portion of said polymerizable component is exposed to a light source; and

a photoactive component and photobinding receptors

wherein said holographic recording medium is capable of recording spatial light distribution via a spatial refractive index change to provide recorded data pages in said holographic recording medium;

wherein said article behaves as a thermoplastic;

wherein said article is volatile compound free;

wherein said article has a melting point at least 10°

C. greater than room temperature; and

wherein said article has a thickness greater than 150 μ

m.

2. The article of claim 1, wherein said at least one thermoplastic comprises poly(methyl vinyl ether-alt-maleic anhydride).

3. The article of claim 1, wherein said at least one thermoplastic comprises poly(vinyl acetate).

4. The article of claim 1, wherein said photoactive monomer is an acrylate.

5. The article of claim 4, wherein said photoactive monomer is tribromophenyl acrylate.

6. The article of claim 4, wherein said monomer is bisphenol A glycerolate (1 glycerol/phenol) diacrylate.

7. The article of claim 1, wherein said monomer is monofunctional.

8. The article of claim 1, wherein said monomer is difunctional.

9. The article of claim 1, wherein said monomer is multifunctional.

10. The article of claim 1, wherein when a portion of said article is exposed to radiation to which said photoinitiator component is sensitive, said monomer forms a polymer that is soluble and dissolved in said binder component.

11. The article of claim 1, wherein said polymerizable component comprises a mixture of at least two monomers.

12. The article of claim 11, wherein at least one of said at least two monomers is monofunctional.

13. The article of claim 11, wherein at least one of said at least two monomers is difunctional.

14. The article of claim 11, wherein at least one of said at least two monomers is multifunctional.

15. The article of claim 11, wherein when a portion of said article is exposed to radiation to which said photoinitiator component is sensitive, said at least two monomers form a co-polymer that is soluble and dissolved in said binder component.

16. The article of claim 1, wherein said polymerizable component comprises a mixture of at least one monomer and at least one oligomer.

17. The article of claim 16, wherein at least one member selected from the group consisting of said at least one monomer and said at least one oligomer is monofunctional.

18. The article of claim 16, wherein at least one member selected from the group consisting of said at least one monomer and said at least one oligomer is difunctional.

19. The article of claim 16, wherein at least one member selected from the group consisting of said at least one monomer and said at least one oligomer is multifunctional.

20. The article of claim 16, wherein when a portion of said article is exposed to radiation to which said photoinitiator component is sensitive, said at least one monomer and said at least one oligomer form a co-polymer that is soluble and dissolved in said binder component.

21. The article of claim 1, wherein said photoinitiator component comprises two photoinitiators.

22. The article of claim 21, wherein said photoinitiator further comprises at least one member selected from the group consisting of:

thionin perchlorate with tetraphenyl borate salt (tetrabutyl amine cation) as a coinitiator, triphenylphosphine oxide, and bis(η

-5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanium.

23. The article of claim 1, wherein said at least one photoinitiator is activated by radiation having a wavelength between about 200 nm and about 800 nm.

24. The article of claim 1, wherein said article includes at least one plasticizer.

25. The article of claim 24, wherein said plasticizer is glycerol propoxylate.

26. The article of claim 24, wherein said plasticizer is hydroxypropyl acrylate.

27. The article of claim 1, wherein said article is substantially optically flat.

28. The article of claim 1, wherein said article comprise film on a substrate.

29. The article of claim 1, wherein said article is a free flexible film.

30. The article of claim 1, wherein said article is a stiff sheet.

36. The article of claim 1, wherein said article has a holographic grating formed therein.

37. The article of claim 1, wherein said polymerizable component comprises less than about 20 volume % of said article.

38. The article of claim 1, wherein said polymerizable component comprises less than about 10 volume % of said article.

39. The article of claim 1, wherein said polymerizable component comprises less than about 5 volume % of said article.

40. The article of claim 1, wherein part or all of said photoactive component is photoreversible.

41. The article of claim 40, wherein said photoreversible component is an anthracene derivative or an acenaphthylene derivative.

42. The article of claim 41, wherein said acenaphthylene derivative is multifunctional.

43. The article of claim 1, wherein said article includes one or more additives selected from the group consisting of the following additives:

pigments, fillers, nonphotoinitiating dyes, antioxidants, inhibitors, bleaching agents, mold releasing agents, antifoaming agents, surfactants, infrared/microwave absorbers, and inert diffusing agents.

44. The article of claim 1, wherein said article comprises wrapping paper.

45. The article of claim 1, wherein said article comprises a cardboard box.

46. The article of claim 1, wherein said article comprises a label.

47. The article of claim 46, wherein said article comprises a security means for said label.

48. The article of claim 1, wherein said article comprises a billboard.

49. The article of claim 1, wherein said article comprises a piece of furniture.

50. The article of claim 1, wherein said article comprises a window.

51. The article of claim 1, wherein said article comprises a data storage device.

52. The article of claim 51, wherein said article has an antireflective coating thereon.

53. The article of claim 1, wherein said article is formed without using a solvent.

31. An article comprising a holographic recording medium comprising:

a porous substrate;

a binder component comprising at least one thermoplastic;

a polymerizable component comprising at least one photoactive monomer that is soluble in said binder component, wherein the at least one photoactive monomer is dissolved in said binder component;

a photoinitiator component comprising at least one photoinitiator that causes said polymerizable component to form a polymer or co-polymer when a portion of said polymerizable component is exposed to a light source; and

a photoactive component and photobinding receptors

wherein said holographic recording medium is capable of recording spatial light distribution via a spatial refractive index change to provide recorded data pages in said holographic recording medium;

wherein said article behaves as a thermoplastic;

wherein said article is volatile compound free;

wherein said article has a melting point at least 10°

C. greater than room temperature;

wherein said article has a thickness greater than 150 μ

m;

wherein said porous substrate is infused with said binder component, said polymerizable component and said photoinitiator.

32. The article of claim 31, wherein said porous substrate comprises glass.

33. The article of claim 31, wherein said porous substrate comprises paper.

34. The article of claim 31, wherein said porous substrate comprises plastic.

35. The article of claim 31, wherein said porous substrate comprises cloth.

54. An article comprising a holographic recording medium comprising:

a binder component comprising at least one thermoplastic;

a polymerizable component comprising at least one photoactive monomer that is soluble in said binder component, wherein the at least one photoactive monomer is dissolved in said binder component; and

a photoinitiator component comprising at least one photoinitiator that causes said polymerizable component to form a polymer or co-polymer when a portion of said polymerizable component is exposed to a light source;

wherein said holographic recording medium is capable of recording spatial light distribution via a spatial refractive index change to provide recorded data pages in said holographic recording medium;

wherein said article behaves as a thermoplastic;

wherein said article is volatile compound free;

wherein said article has a melting point at least 10°

C. greater than room temperature;

wherein said article has a thickness greater than 150 μ

m; and

wherein when a portion of said polymerizable component forms a polymer or copolymer due to being exposed to said light source said binder component becomes covalently crosslinked with said polymer or copolymer.

55. An article comprising a holographic recording medium comprising:

a binder component comprising at least one thermoplastic;

a polymerizable component comprising at least one photoactive monomer that is soluble in said binder component, wherein the at least one photoactive monomer is dissolved in said binder component; and

a photoinitiator component comprising at least one photoinitiator that causes said polymerizable component to form a polymer or co-polymer when a portion of said polymerizable component is exposed to a light source;

wherein said holographic recording medium is capable of recording spatial light distribution via a spatial refractive index change to provide recorded data pages in said holographic recording medium;

wherein said article behaves as a thermoplastic;

wherein said article is volatile compound free;

wherein said article has a melting point at least 10°

C. greater than room temperature;

wherein said article has a thickness greater than 150 μ

m; and

wherein when a portion of said polymerizable component forms a polymer or copolymer due to being exposed to said light source said binder component becomes non-covalently crosslinked with said polymer or copolymer.

56. An article comprising a holographic recording medium comprising:

a binder component comprising at least one thermoplastic;

a polymerizable component comprising at least one photoactive monomer that is soluble in said binder component, wherein the at least one photoactive monomer is dissolved in said binder component; and

a photoinitiator component comprising at least one photoinitiator that causes said polymerizable component to form a polymer or co-polymer when a portion of said polymerizable component is exposed to a light source, wherein said holographic recording medium is capable of recording spatial light distribution via a spatial refractive index change to provide recorded data pages in said holographic recording medium;

wherein said holographic recording medium is capable of recording spatial light distribution via a spatial refractive index change to provide recorded data pages in said holographic recording medium;

wherein said article includes a slow thermosetting agent, wherein the thermosetting agent causes one or more thermoplastics in the binder component to eventually thermoset, but does not cause any of the thermoplastics in the binder component to become thermoset in fewer than 10 minutes when the article is cooled back to room temperature after the article has been heated to be in a flowable state;

wherein said article behaves as a thermoplastic prior to the thermosetting agent causing one or more thermoplastics in the binder component to thermoset;

wherein said article is volatile compound free;

wherein said article has a melting point at least 10°

C. greater than room temperature; and

wherein said article has a thickness greater than 150 μ

m.

57. The article of claim 56, wherein said slow thermosetting agent is a slow thermosetting agent selected from the group consisting of one or more of the following thermosetting agents:

a multifunctional alcohol, a multifunctional epoxide, a multifunctional cyclic anhydride, a multifunctional secondary and/or tertiary isocyanate, and a multifunctional strained cyclic lactone.

58. The article of claim 56, wherein said article is formed without using a solvent.

59. An article comprising a holographic recording medium comprising:

a binder component comprising at least one thermoplastic;

a polymerizable component comprising at least one photoactive monomer that is soluble in said binder component, wherein the at least one photoactive monomer is dissolved in said binder component; and

a photoinitiator component comprising at least one photoinitiator that causes said polymerizable component to form a polymer or co-polymer when a portion of said polymerizable component is exposed to a light source;

wherein said holographic recording medium is capable of recording spatial light distribution via a spatial refractive index change to provide recorded data pages in said holographic recording medium;

wherein said article behaves as a thermoplastic;

wherein said article is volatile compound free;

wherein said article has a melting point at least 10°

C. greater than room temperature;

wherein said article has a thickness greater than 150 μ

m; and

wherein vinyl ether functionalities are attached to said at least one thermoplastic.

60. An article comprising a holographic recording medium comprising:

a binder component comprising at least one thermoplastic;

a polymerizable component comprising at least one photoactive monomer that is soluble in said binder component, wherein the at least one photoactive monomer is dissolved in said binder component; and

a photoinitiator component comprising at least one photoinitiator that causes said polymerizable component to form a polymer or co-polymer when a portion of said polymerizable component is exposed to a light source;

wherein said holographic recording medium is capable of recording spatial light distribution via a spatial refractive index change to provide recorded data pages in said holographic recording medium;

wherein said article behaves as a thermoplastic;

wherein said article is volatile compound free;

wherein said article has a melting point at least 10°

C. greater than room temperature;

wherein said article has a thickness greater than 150 μ

m; and

wherein said binder component comprises a plurality of thermoplastics and wherein vinyl ether functionalities are attached to at least one of said thermoplastics.

61. A solid article comprising a holographic recording medium comprising:

a binder component comprising at least one thermoplastic; and

a photoactive component comprising at least one photoactive molecule that is soluble and dissolved in said binder component, wherein said article has a melting point at least 10°

C. greater than room temperature and wherein said holographic recording medium is capable of recording spatial light distribution via a spatial refractive index change to provide recorded data pages in said holographic recording medium;

wherein part or all of said photoactive component is photoreversible and wherein said binder component contains photobinding receptor

wherein said article behaves as a thermoplastic, and

wherein said article is volatile compound free; and

wherein said article has a thickness greater than 150 μ

m.

62. The article of claim 61, wherein said spatial refractive index change is caused primarily by mass diffusion.

63. The article of claim 61, wherein said article is formed without using a solvent.

64. An article comprising:

a binder component comprising at least one thermoplastic;

a polymerizable component comprising at least one photoactive monomer that is soluble in said binder component, wherein the at least one photoactive monomer is dissolved in said binder component; and

a photoinitiator component comprising at least one photoinitiator that causes said polymerizable component to form a polymer or co-polymer when a portion of said polymerizable component is exposed to a light source,

wherein said article is capable of recording spatial light distribution via a spatial refractive index change;

wherein said article has a 90°

light scattering Rayleigh ratio of less than 7×

10−

3 cm−

1;

wherein said article behaves as a thermoplastic;

wherein said article is volatile compound free;

wherein said article has a melting point at least 10°

C. greater than room temperature; and

wherein said article has a thickness greater than 150 μ

m.

65. The article of claim 64, wherein said article is formed without using a solvent.