Diffraction grating assisted self-cleaning material

• US 8,075,980 B2
• Filed: 05/14/2009
• Issued: 12/13/2011
• Est. Priority Date: 05/14/2009
• Status: Expired due to Fees

• Current Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Original Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Inventors: Eldering, Charles A., Ehrlacher, Edward A.
• Primary Examiner(s): Sample, David
• Assistant Examiner(s): ROSENBERG, NANCY D
• Application Number:
  US12/465,711
• Publication Number:
  US 20100291350A1
• Time in Patent Office: 943 Days
• Field of Search: 428/156, 428/167, 428/172, 362617-622, 359/558, 359/566, 359/569, 359/571
• US Class Current: 428/172
• CPC Class Codes: B32B 15/04 comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to a bituminous or tarry layer B32B11/08; next to a water-setting substance layer B32B13/06; next to a glass layer B32B17/061; next to a cellulosic plastic layer B32B23/042
• CPC Class Codes: B32B 2307/40 having particular optical properties
• CPC Class Codes: B32B 2307/412 Transparent
• CPC Class Codes: B32B 2307/728 Hydrophilic
• CPC Class Codes: B32B 2307/73 Hydrophobic
• CPC Class Codes: B32B 2307/754 Self-cleaning
• CPC Class Codes: B32B 2419/00 Buildings or parts thereof
• CPC Class Codes: B32B 3/30 characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs apertured layer B32B3/266; layer with cavities or internal voids B32B3/26
• CPC Class Codes: B32B 9/005 comprising one layer of ceramic material, e.g. porcelain, ceramic tile layered products with at least two ceramic layers composed mainly of ceramic B32B18/00
• CPC Class Codes: B32B 9/04 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to a glass layer B32B17/06; layered products with at least two ceramic layers composed mainly of ceramic B32B18/00
• CPC Class Codes: Y10T 428/24479 including variation in thickness
• CPC Class Codes: Y10T 428/2457 Parallel ribs and/or grooves
• CPC Class Codes: Y10T 428/24612 Composite web or sheet

Abstract

A self-cleaning material is generally described that may include a substrate having a first surface and a second surface. A self cleaning layer may be disposed on the first surface of the substrate. A diffraction grating may be formed in an exposed surface of the self cleaning layer, where absorption of light by the self cleaning layer incident on the exposed surface may be enhanced by the diffraction grating in accordance with a blaze condition corresponding to the diffraction grating.

Claims

1. A self-cleaning material that is responsive to exposure to light comprising:

a substrate having a first surface and a second surface;

a self cleaning layer disposed on the first surface of the substrate; and

a diffraction grating formed in an exposed surface of the self cleaning layer, wherein the diffraction grating includes a blaze condition that is arranged to enhance absorption of light incident on the exposed surface.

2. The self-cleaning material of claim 1, wherein the blaze condition of the diffraction grating corresponds to a most probable angle of incidence of the light related to an intended usage orientation of the self-cleaning material.

3. The self-cleaning material of claim 2, wherein the intended usage orientation is substantially vertical and the most probable angle of incidence of the light is nearly parallel to the first surface.

4. The self-cleaning material of claim 2, wherein the intended usage orientation is substantially horizontal and the most probable angle of incidence of the light is nearly perpendicular to the first surface.

5. The self-cleaning material of claim 1, wherein the diffraction grating is a phase grating.

6. The self-cleaning material of claim 1, wherein the self cleaning layer is either photocatalytic, hydrophobic, or hydrophilic in response to exposure to light.

7. The self-cleaning material of claim 6, wherein the light is ultraviolet light.

8. The self-cleaning material of claim 1, wherein the self cleaning layer at least partially comprises titanium dioxide.

9. The self-cleaning material of claim 1, wherein the blaze condition of the diffraction grating is arranged such that the self cleaning layer exhibits a photocatalytic property when illuminated using visible wavelengths of light via a two-photon absorption process.

10. A self-cleaning material that is responsive to exposure to light comprising:

a substrate having a first surface and a second surface;

a first self cleaning layer disposed on the first surface of the substrate, wherein a first diffraction grating having a first blaze condition is formed on a first exposed surface of the first self cleaning layer and arranged to enhance the absorption of light based at least in part on the first blaze condition; and

a second self cleaning layer disposed on the second surface of the substrate, wherein a second diffraction grating having a second blaze condition is formed on a second exposed surface of the second self cleaning layer and arranged to enhance the absorption of light based at least in part on the second blaze condition.

11. The self-cleaning material of claim 10, wherein the first and second self cleaning layers are different materials.

12. The self-cleaning material of claim 10, wherein the absorption of light by the first self cleaning layer and the second self cleaning layer causes the respective self cleaning layer to exhibit one of a photocatalytic property, a hydrophobic property, or a hydrophilic property.

13. The self-cleaning material of claim 12, wherein the second self cleaning layer exhibits a different self cleaning property than the first self cleaning layer.

14. The self-cleaning material of claim 10, wherein the first and second blaze conditions correspond to most probable angles of incidence of the light on the first and second exposed surfaces of the first and second self-cleaning layers, respectively.

15. The self-cleaning material of claim 10, wherein the first blaze condition is selected based on the first self cleaning layer being utilized in an uncontrolled environment and the second blaze condition is selected based on the second self cleaning layer being utilized in a controlled environment.

16. A self-cleaning material comprising:

a first blazed diffraction grating formed in a first surface of the self-cleaning material, wherein absorption of light by the self-cleaning material incident on the first surface is arranged to enter a first photo-induced self cleaning state on the first surface based on a first blaze condition corresponding to the first blazed diffraction grating and a first incident angle of the light with the first surface; and

a second blazed diffraction grating formed in a second surface of the self-cleaning material, wherein absorption of light by the self-cleaning material incident on the second surface is arranged to enter a second photo-induced self cleaning state on the second surface based on a second blaze condition corresponding to the second blazed diffraction grating and a second incident angle of the light with the second surface.

17. The self-cleaning material of claim 16, wherein the first or second blaze condition of the respective blazed diffraction grating corresponds to a most probable angle of incidence of the light related to an intended usage orientation of the self-cleaning material.

18. The self-cleaning material of claim 16, wherein the self cleaning material is either photocatalytic, hydrophobic, or hydrophilic in response to exposure to light.