Method for increasing the concentration of xylose in lignocellulosic hydrolysate

• US 8,080,128 B2
• Filed: 12/31/2009
• Issued: 12/20/2011
• Est. Priority Date: 12/31/2009
• Status: Expired due to Fees

• Current Assignee: Atomic Energy Council-Institute Of Nuclear Research
• Original Assignee: Atomic Energy Council-Institute Of Nuclear Research
• Inventors: Wang, Jia-Baau, Chen, Wen-Hua, Chen, Sheng-Shieh, Hwang, Wen-Song, Men, Lee-Chung
• Primary Examiner(s): Halpern, Mark
• Application Number:
  US12/651,123
• Publication Number:
  US 20110155336A1
• Time in Patent Office: 719 Days
• Field of Search: 162/60, 162/43, 162/17, 162/181.1, 162/14, 162/18, 162/233, 162/238
• US Class Current: 162/19
• CPC Class Codes: C08H 8/00 Macromolecular compounds derived from lignocellulosic materials pretreatment thereof B27N
• CPC Class Codes: D21C 1/04 with acid reacting compounds
• CPC Class Codes: D21C 3/04 with acids, acid salts or acid anhydrides D21C3/003 and D21C3/222 take precedence
• CPC Class Codes: D21C 9/005 organic compounds

Abstract

Disclosed is a method for increasing the concentration of xylose in lignocellulosic hydrolysate. The method includes the step of extruding lignocellulosic material and mixing the lignocellulosic material with diluted acid and the step of conducting hot-water extraction on the mixture. Hence, the concentration of the xylose in the lignocellulosic hydrolysate can achieve a high concentration of 60 g/L, and the yield of the xylose can reach to 90%.

Claims

1. A method for increasing the concentration of xylose in lignocellulosic hydrolysate comprising the steps of:

extruding lignocellulosic material and mixing the lignocellulosic material with diluted acid at a feed rate of between about 6 and 7 kg/hr and a flow rate of between about 12 and 14 kg/hr, wherein the speed of a rotational screw is between about 30 and 150 rpm at the barrel temperature of 80-160°

C., creating a mixture;

feeding the resulting mixture into a hot-water extraction tank and cooking the mixture at an average temperature of 130-160°

C. for 10-30 minutes; and

separating the liquids from the solids using a solid separating device to produce a lignocellulosic hydrolysate;

wherein the concentration of the xylose in the lignocellulosic hydrolysate is 40 to 60 g/L and wherein the yield of the xylose is 70% to 90%.

2. The method according to claim 1, wherein the lignocellulosic material is selected from a group consisting of rice straw, bagasse, silvergrass, napiergrass, switchgrass, corn stover, wood, bamboo and algae.

3. The method according to claim 1 comprising the step of using a twin-screw extruder to extrude the lignocellulosic material and mix the lignocellulosic material with the diluted acid.

4. The method according to claim 3, wherein the step of hot-water extraction lasts for 10 to 30 minutes, and the temperature therein is 130°

C. to 145°

C.

5. The method according to claim 1, wherein the feed rate of the lignocellulosic material is 6.5 kg/h.

6. The method according to claim 1, wherein the flow rate of the diluted acid is 13 kg/h.

7. The method according to claim 1, wherein the concentration of the diluted acid is 3%.

8. The method according to claim 1, wherein the rotational speed of the screw is 40 rpm.

9. The method according to claim 1, wherein the barrel temperature of the extruder is 120°

C.

10. The method according to claim 1, wherein the cooking temperature is 130°

C.

11. The method according to claim 1, wherein the cooking time is 20 min.