Melt planarization of solar cell bus bars

• US 8,080,729 B2
• Filed: 11/24/2008
• Issued: 12/20/2011
• Est. Priority Date: 11/24/2008
• Status: Expired due to Fees

• Current Assignee: Palo Alto Research Center, Inc. (Xerox Holdings Corp.)
• Original Assignee: Palo Alto Research Center, Inc. (Xerox Holdings Corp.)
• Inventors: Fork, David K., Kalio, Andre, Rao, Ranjeet
• Primary Examiner(s): Hendricks, Keith D.
• Assistant Examiner(s): Gardner, Shannon
• Application Number:
  US12/277,201
• Publication Number:
  US 20100126574A1
• Time in Patent Office: 1,121 Days
• Field of Search: 136/256, 136/252
• US Class Current: 136/256
• CPC Class Codes: H01L 31/022425 for solar cells
• CPC Class Codes: Y02E 10/50 Photovoltaic [PV] energy

Abstract

Solar cells include bus bars and high aspect-ratio gridlines that are printed on a substrate, and localized melting is induced to slump or flatten the gridline “vertex” portions that are disposed on the bus bars, while maintaining the high aspect-ratio of gridlines portions disposed on the substrate between the bus bars. The localized melting process is induced using one of several disclosed methods, such as rheological melting in which the two printed inks produce a compound that is relatively liquid. Localized melting is also induced using a deliquescing material (e.g., a flux or a solvent film) that is applied to the bus bar or gridline material. Also, eutectic melting is induced using a processing temperature that is between a melting point of the combined gridline/bus bar inks and the individual melting points of the inks alone. Laser-based melting and the use of copolymers is also disclosed.

Claims

1. A method for producing a solar cell, the method comprising:

disposing a first ink onto a substrate such that the printed first ink forms an elongated bus bar on the substrate;

printing a second ink onto the substrate such that the second ink forms an elongated gridline including a first gridline portion contacting the substrate and a second gridline portion disposed on the bus bar, and such that each of said first and second gridline portions include an initial cross-section having a first aspect ratio; and

inducing localized melting of the second gridline portion such that said second gridline portion assumes a melted cross-section having a second aspect ratio that is lower than said first aspect ratio, and such that said first gridline portion retains said initial cross-section having said first aspect ratio.

2. The method according to claim 1,

wherein printing said first ink comprises printing a bus bar ink having at least one of a first viscosity and a first finite yield stress, and having a first chemical composition,

wherein printing said second ink comprises printing a gridline ink having at least one of a second viscosity and a second finite yield stress, and having a second chemical composition,

wherein the first and second inks are selected such that contact between said second gridline portions and said one or more bus bars produces a third chemical composition having at least one of a third viscosity and a third finite yield stress that is less than said at least one of said first and second viscosities and said first and second finite yield stresses.

3. The method according to claim 2,

wherein printing said first ink comprises printing a first colloidal gel having a first pH level,

wherein printing said second ink comprises printing a second colloidal gel having a second pH level, and

wherein the first and second inks are selected such that contact between said second gridline portions and said one or more bus bars produces a third pH level that causes at least one of the first and second colloidal gel to melt.

4. The method according to claim 2, wherein printing said first and second inks comprises extruding at least one colloidal gel.

5. The method according to claim 2, wherein inducing said localized melting comprises applying one of ultraviolet (UV) rays and heat to said first and second inks.

6. The method according to claim 2, further comprising drying said first and second inks after inducing said localized melting.

7. The method according to claim 1, wherein inducing said localized melting comprises applying a deliquescing material to one of said second gridline portions and portions of said at least one bus bar contacted by said second gridline portions.

8. The method according to claim 7, wherein applying said deliquescing material to said second gridline portions comprises applying one of a solvent film and a flux onto said one or more bus bars prior to printing said second ink.

9. The method according to claim 7, wherein applying said deliquescing material to said second gridline portions comprises co-extruding silver (Ag) and a flux during printing of said first ink such that, when said second ink is subsequently printed, the second gridlines portions contact portions of said flux, thereby inducing a chemical reaction between said flux and said second ink such that said second gridline portions slump onto said bus bars.

10. The method according to claim 7, wherein applying said deliquescing material to said second gridline portions comprises applying a flux onto said second gridline portions after printing said second ink, and inducing a chemical reaction between said flux and said second gridline portions such that said second gridline portions slump onto said bus bars.

11. The method according to claim 7, wherein applying said deliquescing material comprises one of jet printing and microdispensing said deliquescing material.

12. The method according to claim 1,

wherein printing said first ink comprises printing a bus bar ink having a first melting point temperature,

wherein each of said plurality of parallel gridlines consisting essentially of a second ink having a second melting point temperature,

wherein the first and second inks are selected such that contact between said second gridline portions and said one or more bus bars produces a combined material having a third melting point that is lower that said first and second melting points, and

wherein including localized melting comprises heating said substrate to a processing temperature that is between the third melting point temperature and the first and second melting point temperatures.

13. The method according to claim 12, wherein printing the first ink comprises printing silver-copper alloy, and wherein printing the second ink comprises printing an ink consisting essentially of silver.

14. The method according to claim 12, wherein heating said substrate comprises placing said substrate in a furnace maintained in the range of 780°

C. and 962°

C.

15. The method according to claim 1, wherein inducing localized melting comprises one of directing a laser beam and applying a mechanical force onto said second gridline portions.

16. The method according to claim 1,

wherein printing said second ink comprises printing a gridline ink comprising a gel including a copolymer in a non-aqueous suspension,

wherein inducing localized melting comprises heating said second gridline portion such that said copolymer causes said gel to liquefy and flow over said bus bar.