Fabric color rejuvenation composition

• US 8,097,047 B2
• Filed: 02/06/2009
• Issued: 01/17/2012
• Est. Priority Date: 04/02/2008
• Status: Active Grant

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Sivik, Mark Robert, Gerdes, Allison Lynn, Frankenbach, Gayle Marie, Waning, Gregory T., Ganapathysundaram, Ramanan Venkata, Creedon, Michael Timothy
• Primary Examiner(s): Douyon, Lorna M
• Assistant Examiner(s): KHAN, AMINA S
• Application Number:
  US12/322,796
• Publication Number:
  US 20090249562A1
• Time in Patent Office: 1,075 Days
• Field of Search: 252/8.91, 811/56, 811/551, 868/1, 840/1, 844/1, 854/3, 859/4, 861/4, 866/9
• US Class Current: 8/441
• CPC Class Codes: C09B 67/0072 Preparations with anionic dyes or reactive dyes
• CPC Class Codes: C11D 17/042 Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
• CPC Class Codes: C11D 3/044 Hydroxides or bases
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/08 Silicates
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 3/386 Preparations containing enzymes , e.g. protease or amylase
• CPC Class Codes: C11D 3/40 Dyes ; Pigments
• CPC Class Codes: C11D 7/06 Hydroxides
• CPC Class Codes: C11D 7/10 Salts
• CPC Class Codes: C11D 7/12 Carbonates bicarbonates
• CPC Class Codes: C11D 7/14 Silicates
• CPC Class Codes: D06P 1/0016 Dye baths containing a dyeing agent in a special form such as for instance in melted or solid form, as a floating film or gel, spray or aerosol, or atomised dyes
• CPC Class Codes: D06P 1/38 using reactive dyes
• CPC Class Codes: D06P 1/382 reactive group directly attached to heterocyclic group
• CPC Class Codes: D06P 1/384 reactive group not directly attached to heterocyclic group
• CPC Class Codes: D06P 5/12 Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means

Abstract

Rejuvenation compositions including a reactive dye are disclosed for the one-shot rejuvenation of the color for dark-colored textile fabrics and garments formed therefrom. The rejuvenation compositions return faded black or dark colored garments to a like-new look. Methods of rejuvenating the faded color of garments by using the dye compositions are also disclosed.

Claims

1. A textile rejuvenation composition comprising:

from about 5.0% to about 30.0% by weight of a reactive dye composition;

from about 35.0% to about 90.0% by weight of a water soluble salt;

from about 5.0% to about 40.0% by weight of an alkali base;

from 0% to about 10% by weight of a surfactant; and

from 0% to about 1.0% by weight of an enzyme,

wherein the composition is substantially free of phosphates and wherein the water soluble salt is a sodium salt selected from the group consisting of sodium chloride, sodium acetate, a sodium carboxylate, sodium formate and combinations of any thereof.

2. The composition of claim 1, wherein the reactive dye composition comprises a reactive black dye.

3. The composition of claim 2, wherein the reactive dye composition further comprises at least one dye selected from the group consisting of a reactive yellow dye, a reactive orange dye, a reactive red dye, a reactive green dye, and combinations thereof.

4. The composition of claim 2, wherein the reactive dye composition has an extinction coefficient ranging from 40,000 to 45,000 at λ

_max of 595 nm for Reactive Black 5 and an absorbance percentage of at least 77% with respect to the absorbance value at 595 nm for species absorbing in the range of 465-480 nm and an absorbance percentage of at least 70% with respect to the absorbance value at 595 nm for species absorbing in the range of 420-435 nm.

5. The composition of claim 1, wherein the alkali base is selected from the group consisting of sodium hydroxide, sodium carbonate, sodium silicate, sodium bicarbonate, sodium metasilicate, and combinations of any thereof.

6. The composition of claim 1, wherein an aqueous solution of the composition has a pH ranging from about 9 to about 13.5.

7. The composition of claim 1, wherein the enzyme is selected from the group consisting of an amylase, a protease, a lipase, a cellulase, a hemicellulase, a peroxidase, a xylanase, a phospholipase, an esterase, a cutinase, a pectinase, a keratanase, a reductase, an oxidase, a phenoloxidase, a lipoxygenase, a ligninase, a pullulanase, a tannase, a pentosanase, a malanase, a β

-glucanase, an arabinosidase, a hyaluronidase, a chondroitinase, a laccase, and combinations of any thereof.

8. The composition of claim 1, wherein the composition is provided in a water-miscible film pouch.

9. The composition of claim 1, wherein the composition has a total weight ranging from about 50 g to about 500 g per unit dosage for a front loader-type washing machine.

10. The composition of claim 1, wherein the composition has a total weight ranging from about 100 g to about 1000 g per unit dosage for a top loader-type washing machine.