Reformed alcohol power systems

• US 8,100,093 B2
• Filed: 06/28/2010
• Issued: 01/24/2012
• Est. Priority Date: 06/13/2006
• Status: Active Grant

• Current Assignee: Monsanto Technology LLC (Bayer AG)
• Original Assignee: Monsanto Technology LLC (Bayer AG)
• Inventors: Morgenstern, David A.
• Primary Examiner(s): KAMEN, NOAH P
• Application Number:
  US12/824,555
• Publication Number:
  US 20100319635A1
• Time in Patent Office: 575 Days
• Field of Search: 123/1.A, 123/3
• US Class Current: 123/3
• CPC Class Codes: C01B 2203/0227 containing a catalytic reforming step
• CPC Class Codes: C01B 2203/1029 Catalysts in the form of a foam
• CPC Class Codes: C01B 2203/1217 Alcohols
• CPC Class Codes: C01B 2203/1229 Ethanol
• CPC Class Codes: C01B 2203/1235 Hydrocarbons
• CPC Class Codes: C01B 3/323 Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
• CPC Class Codes: C01B 3/326 characterised by the catalyst
• CPC Class Codes: C01B 3/384 the catalyst being continuously externally heated
• CPC Class Codes: C01B 3/48 followed by reaction of water vapour with carbon monoxide
• CPC Class Codes: F02M 25/12 the apparatus having means for generating such gases using rays and simultaneously generating ozone F02M27/06
• CPC Class Codes: F02M 27/02 by catalysts
• CPC Class Codes: Y02P 20/52 using catalysts, e.g. selective catalysts
• CPC Class Codes: Y02T 10/12 Improving ICE efficiencies

Abstract

Improved alcohol reforming processes and reformed alcohol power systems utilizing those processes are disclosed. In preferred embodiments, the alcohol reforming processes utilize a thermally conductive reforming catalyst that allows efficient, low-temperature reforming of an alcohol fuel to produce a reformate gas mixture comprising hydrogen. The present invention makes possible the efficient utilization of alcohol fuels in an internal combustion engine to generate electrical or mechanical power such as in vehicular applications.

Claims

1. A process for producing mechanical or electrical power from a fuel comprising alcohol, the process comprising:

contacting a feed gas mixture comprising the alcohol fuel with a reforming catalyst in a reforming reaction zone to produce a product reformate gas mixture comprising hydrogen, wherein the reforming catalyst comprises a metal sponge supporting structure and a copper coating at least partially covering the surface of the metal sponge supporting structure;

combining the product reformate gas mixture with an oxygen-containing gas to form an intake gas mixture;

introducing the intake gas mixture comprising oxygen and the product reformate gas mixture into a combustion chamber of an internal combustion engine and combusting the intake gas mixture to produce an exhaust gas mixture, the intake gas mixture introduced into the combustion chamber of the internal combustion engine containing at least about 80% of the hydrogen and other components obtained in the product reformate gas mixture;

discharging an exhaust gas effluent comprising the exhaust gas mixture from the combustion chamber;

utilizing the energy of combustion for the generation of mechanical or electrical power; and

bringing the exhaust gas effluent into thermal contact with the reforming reaction zone to heat the reforming catalyst therein.

2. The process as set forth in claim 1 wherein the feed gas mixture comprises an alcohol selected from the group consisting of methanol, ethanol and mixtures thereof.

3. The process as set forth in claim 2 wherein the feed gas mixture comprises ethanol and the product reformate gas mixture comprises hydrogen, methane and a carbon oxide component selected from the group consisting of carbon monoxide, carbon dioxide and mixtures thereof.

4. A process for producing mechanical or electrical power from a fuel comprising ethanol, the process comprising:

contacting a feed gas mixture comprising the ethanol fuel with a reforming catalyst in a reforming reaction zone to produce a product reformate gas mixture comprising hydrogen and methane, wherein the reforming catalyst comprises copper at the surface of a metal supporting structure;

combining the product reformate gas mixture with an oxygen-containing gas to form an intake gas mixture;

introducing the intake gas mixture comprising oxygen and the product reformate gas mixture into a combustion chamber of an internal combustion engine and combusting the intake gas mixture to produce an exhaust gas mixture, the intake gas mixture introduced into the combustion chamber of the internal combustion engine containing at least about 80% of the hydrogen and methane obtained in the product reformate gas mixture;

discharging an exhaust gas effluent comprising the exhaust gas mixture from the combustion chamber;

utilizing the energy of combustion for the generation of mechanical or electrical power; and

bringing the exhaust gas effluent into thermal contact with the reforming reaction zone to heat the reforming catalyst therein.

5. A process for producing mechanical or electrical power from a fuel comprising ethanol, the process comprising:

contacting a feed gas mixture comprising the ethanol fuel with a reforming catalyst comprising copper in a reforming reaction zone to produce a product reformate gas mixture comprising hydrogen, methane and a carbon oxide component selected from the group consisting of carbon monoxide, carbon dioxide and mixtures thereof, wherein the molar ratio of methane to the carbon oxide component in the product reformate gas mixture is from about 0.9 to about 1.25 and the rate at which methane is produced in the reformate gas mixture is at least about 50% of the rate of ethanol introduced into the reforming reaction zone on a molar basis;

combining the product reformate gas mixture with an oxygen-containing gas to form an intake gas mixture; and

introducing the intake gas mixture comprising oxygen and the product reformate gas mixture into a combustion chamber of an internal combustion engine and combusting the intake gas mixture to produce an exhaust gas mixture, the intake gas mixture introduced into the combustion chamber of the internal combustion engine containing at least about 80% of the hydrogen, methane and carbon oxide component obtained in the product reformate gas mixture; and

utilizing the energy of combustion for the generation of mechanical or electrical power.

6. The process as set forth in claim 5 wherein the reforming catalyst comprises copper at the surface of a metal supporting structure.

7. The process as set forth in claim 6 wherein the metal supporting structure comprises a metal sponge.

8. The process as set forth in claim 7 wherein the catalyst comprises a copper coating at least partially covering the surface of the metal sponge supporting structure.

9. The process as set forth in claim 8 wherein preparation of the reforming catalyst comprises depositing copper onto the metal sponge supporting structure.

10. The process as set forth in claim 7 wherein the metal sponge supporting structure is prepared by a process comprising leaching aluminum from an alloy comprising aluminum and a base metal.

11. The process as set forth in claim 7 wherein the metal sponge supporting structure comprises copper and/or a non-copper metal selected from the group consisting of nickel, cobalt, zinc, silver, palladium, gold, tin, iron and mixtures thereof.

12. The process as set forth in claim 11 wherein the metal sponge supporting structure comprises copper and/or a non-copper metal selected from the group consisting of nickel, cobalt, iron and mixtures thereof.

13. The process as set forth in claim 11 wherein the metal sponge supporting structure comprises at least about 50% by weight nickel.

14. The process as set forth in claim 11 wherein the reforming catalyst comprises from about 20% to about 45% by weight copper.

15. The process as set forth in claim 5 wherein the reforming catalyst is in the form of a powder or granule and the reforming catalyst is disposed within a fixed bed within the reforming reaction zone through which the feed gas mixture passes.

16. The process as set forth in claim 5 wherein the reforming catalyst is disposed on a monolithic substrate within the reforming reaction zone.

17. The process as set forth in claim 5 wherein carbon monoxide is produced in the reforming reaction zone and reacted with water present in the feed gas mixture in a water-gas shift reaction to increase the hydrogen content of the product reformate gas mixture.

18. The process as set forth in claim 5 wherein the feed gas mixture is contacted with the reforming catalyst in the reforming reaction zone at a temperature less than about 400°

C. to produce the product reformate gas mixture.

19. The process as set forth in claim 5 wherein the feed gas mixture is contacted with the reforming catalyst in the reforming reaction zone at a temperature of from about 220°

C. to about 350°

C. to produce the product reformate gas mixture.

20. The process as set forth in claim 5 wherein the rate at which methane is produced in the product reformate gas mixture is at least about 95% of the rate of ethanol introduced into the reforming reaction zone on a molar basis.

21. The process as set forth in claim 5 wherein the product reformate gas mixture comprises not more than about 10 mole % acetaldehyde and not more than about 20 mole % ethanol.

22. The process as set forth in claim 5 wherein the intake gas mixture further comprises ethanol fuel.

23. The process as set forth in claim 5 wherein a portion of the product reformate gas mixture is stored for subsequent combustion in the combustion chamber during a start-up condition of the internal combustion engine.

24. The process as set forth in claim 5 wherein exhaust gas effluent comprising the exhaust gas mixture is discharged from the combustion zone and at least a portion of the exhaust gas effluent is recycled and combined with the intake gas mixture introduced into the combustion chamber of the internal combustion engine.

25. The process as set forth in claim 24 further comprising bringing the exhaust gas effluent into thermal contact with the reforming reaction zone to heat the reforming catalyst therein and cool the exhaust gas effluent and wherein the exhaust gas effluent that is recycled and combined with the intake gas mixture is at least a portion of the cooled exhaust gas effluent.

26. The process as set forth in claim 25 wherein at least about 50% of the exhaust gas effluent is recycled and combined with the intake gas mixture introduced into the combustion chamber of the internal combustion engine.