Hydrogen generator

• US 8,100,993 B2
• Filed: 07/13/2009
• Issued: 01/24/2012
• Est. Priority Date: 08/11/2005
• Status: Active Grant

• Current Assignee: Ardica Technologies Incorporated
• Original Assignee: Ardica Technologies Incorporated
• Inventors: Thomas, Jesse, Fisher, Tobin Joseph
• Primary Examiner(s): MERKLING, MATTHEW J
• Application Number:
  US12/501,675
• Publication Number:
  US 20090274595A1
• Time in Patent Office: 925 Days
• Field of Search: 48/61, 481/97.R, 423/644, 423/648.1
• US Class Current: 48/61
• CPC Class Codes: B01J 7/02 by wet methods
• CPC Class Codes: C01B 3/065 from a hydride
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

A hydrogen gas generator generates hydrogen gas by mixing two reactants. The generator has a reaction chamber for receiving a solid reactant. The chamber has a reaction product separator impermeable to the solid reactant and a biasing means for biasing reactant products against the separator. The generator also has a liquid reactant dispenser for storing a liquid reactant and is fluidly coupled to the reaction chamber, such that dispensed liquid reactant reacts with the solid reactant in the reaction chamber to produce hydrogen gas and a waste product that are substantially permeable through the separator. The generator also has a product collector coupled to the reaction chamber for collecting hydrogen gas and waste product that have passed through the separator.

Claims

1. A hydrogen gas generator comprising:

a reaction chamber that receives a solid reactant, the chamber including a biasing mechanism, wherein the solid reactant reacts to produce reactant products;

a reaction product separator, wherein the biasing mechanism biases the reactant products against the separator;

a liquid reactant dispenser that is fluidly coupled to the reaction chamber and stores a liquid reactant that reacts with the solid reactant to produce hydrogen gas and a waste product that are substantially permeable through the separator;

a diaphragm, in fluid communication with the liquid reactant dispenser and the reaction chamber, that pumps the liquid reactant from the liquid reactant dispenser into the reaction chamber;

a product collector coupled to the reaction chamber for collecting the hydrogen gas and waste product that have passed through the separator; and

,

a flexible barrier that fluidly separates the liquid reactant dispenser from the product collector.

2. A hydrogen gas generator as claimed in claim 1 further comprising a hydrogen gas separator located in the product collector, wherein the hydrogen gas separator is a gas separation membrane.

3. A hydrogen gas generator as claimed in claim 1 wherein the biasing mechanism is a spring.

4. A hydrogen gas generator as claimed in claim 1 wherein the solid reactant is sodium borohydride powder.

5. A hydrogen gas generator as claimed in claim 4 wherein the sodium borohydride powder is compacted into a pill form.

6. A hydrogen gas generator as claimed in claim 5 wherein the separator is a screen having a mesh size that is smaller than the sodium borohydride grain size.

7. A hydrogen gas generator as claimed in claim 4 wherein the liquid reactant is an acidic solution.

8. A hydrogen gas generator as claimed in claim 7 wherein the acid solution has a pH of 2 or less.

9. A hydrogen gas generator as claimed in claim 1 wherein the liquid reactant is citric acid solution.

10. A hydrogen gas generator as claimed in claim 1 further comprising an outer shell enclosing the reaction chamber, liquid reactant dispenser and product collector, wherein at least part of the shell is sufficiently transparent to view the amount of solid reactant remaining in the generator.

11. A hydrogen gas generator as claimed in claim 1, wherein the liquid reactant dispenser is a bag, and the flexible barrier is an inner bag enclosing the reaction chamber and product collector, the inner bag being located within the liquid reactant dispenser.

12. A hydrogen gas generator as claimed in claim 1, wherein the liquid reactant dispenser is the flexible barrier, and wherein the liquid reactant dispenser is a bag.

13. A hydrogen gas generator as claimed in claim 1, wherein the reaction chamber is flexible.

14. A hydrogen gas generator as claimed in claim 13, wherein the reaction chamber is a bag.

15. A hydrogen gas generator as claimed in claim 1, wherein the reaction chamber includes the reaction product separator.

16. A hydrogen gas generator as claimed in claim 1, wherein the liquid reagent is sprayed across the face of the solid reactant proximal the reaction product separator.

17. A hydrogen gas generator as claimed in claim 1, wherein the reaction product separator is fluidly coupled to a hydrogen gas separator.

18. A hydrogen gas generator as claimed in claim 17, wherein the hydrogen gas separator substantially occupies the product collector.

19. A hydrogen gas generator comprising:

a reaction chamber that receives a solid reactant, the chamber including a biasing mechanism, wherein the solid reactant reacts to produce reaction products;

a reaction product separator impermeable to the solid reactant, wherein the biasing mechanism biases the solid reactant and reaction products against the separator;

a diaphragm in fluid communication with the liquid reactant dispenser and the reaction chamber that pumps the liquid reactant from the liquid reactant dispenser into the reaction chamber;

a flexible liquid reactant dispenser fluidly coupled to the reaction chamber that stores a liquid reactant, wherein the liquid reactant is pumped into the interface between the solid reactant and the reaction product separator, such that the liquid reactant substantially reacts with the solid reactant in the reaction chamber to produce hydrogen gas and a waste product; and

,

a product collector coupled to the reaction chamber for collecting the hydrogen gas and waste product that have passed through the separator.