Controlled gas pore formers in extruded ware

• US 8,101,117 B2
• Filed: 05/30/2008
• Issued: 01/24/2012
• Est. Priority Date: 05/30/2008
• Status: Active Grant

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Addiego, William Peter, Glose, Christopher Raymond
• Primary Examiner(s): Daniels, Matthew
• Assistant Examiner(s): KEMMERLE III, RUSSELL J
• Application Number:
  US12/129,959
• Publication Number:
  US 20090298667A1
• Time in Patent Office: 1,334 Days
• Field of Search: 264/630, 264/631
• US Class Current: 264/630
• CPC Class Codes: C04B 2235/3463 Alumino-silicates other than clay, e.g. mullite
• CPC Class Codes: C04B 2235/3481 Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite
• CPC Class Codes: C04B 2235/6567 Treatment time
• CPC Class Codes: C04B 2235/77 Density
• CPC Class Codes: C04B 2235/80 Phases present in the sintered or melt-cast ceramic products other than the main phase
• CPC Class Codes: C04B 35/185 Mullite 3Al2O3-2SiO2
• CPC Class Codes: C04B 35/195 Alkaline earth aluminosilicates, e.g. cordierite or anorthite
• CPC Class Codes: C04B 35/632 Organic additives

Abstract

The present invention provides compositions and methods for producing porous ceramic articles. The compositions and methods comprise a ceramic precursor batch comprising an organic peroxide pore forming agent where the pore forming agent is an organo-adduct of hydrogen peroxide and an organic compound or an organic peroxide of the general formula R—O—O—R′. The organic peroxide pore forming agent is stable during extrusion and other methods for forming a green body and does not decompose until the green body is dried.

Claims

1. A method for producing a porous ceramic article, comprising the steps of:

providing inorganic ceramic-forming ingredients;

adding an organic binder, a solvent and a pore forming agent to the inorganic ceramic-forming ingredients, wherein the pore forming agent is t-butlyperoxytrimethylsilane, di(t-butylperoxy)dimethylsilane, di(t-butylperoxy)diphenylsilane or combinations thereof;

mixing the inorganic ceramic forming ingredients, the organic binder, the solvent and the pore forming agent to form a precursor batch;

forming the precursor batch into a green body;

firing the green body to produce a porous ceramic article; and

wherein the pore forming agent is stable during the step of forming the green body and decomposes after the forming of the green body but before firing the green body.

2. The method of claim 1 wherein the pore forming agent is from about 0.5 wt % to about 10 wt % wherein the weight % is based on 100% of the inorganic ceramic-forming ingredients.

3. The method of claim 1 wherein the inorganic ceramic-forming ingredients comprises cordierite forming ingredients or aluminum-titanate forming ingredients.

4. The method of claim 1 wherein the green body is formed by extrusion.

5. The method of claim 1 further comprising the step of adding up to 80 wt % of a conventional pore forming material to the inorganic ceramic-forming materials wherein the weight % is based on 100% of the inorganic ceramic-forming ingredients.

6. The method of claim 5 wherein the conventional pore forming material is a starch, graphite or combinations thereof.

7. The method of claim 1 further comprising the step of drying the green body at a temperature below approximately 400°

C. prior to firing the green body.

8. The method of claim 7 wherein the drying step accelerates an evolution of pore forming gas from the pore forming agent.

9. The method of claim 1 wherein the firing comprises heating the green body for a period of time sufficient to convert the green body into the ceramic article, wherein the ceramic article comprises a primary sintered phase composition.

10. The method of claim 9 wherein the green body is heated to a temperature in the range of from about 1300°

C. to about 1450°

C.

11. A method for manufacturing a porous ceramic honeycomb body comprising the steps of:

providing inorganic ceramic-forming ingredients;

adding an organic binder, a solvent and a pore forming agent to the inorganic ceramic-forming ingredients, wherein the pore forming agent is an organic peroxide of the general formula R—

O—

O—

R′

wherein R and R′

are each independently alkyl, substituted alkyl, phenyl, napthyl, substituted phenyl, substituted napthyl groups or combinations thereof;

mixing the inorganic ceramic forming ingredients, the organic binder, the solvent and the pore forming agent to form a precursor batch;

extruding the precursor batch to form a honeycomb green body;

at least substantially drying the honeycomb green body at a temperature below approximately 400°

C. prior to firing the green body; and

firing the green body to produce a porous ceramic article.

12. The method of claim 11 wherein the pore forming agent is from about 5 wt % to about 10 wt % wherein the weight % is based on 100% of the inorganic ceramic-forming ingredients.

13. The method of claim 11 wherein the inorganic ceramic-forming ingredients comprises cordierite or aluminum titanate forming ingredients.

14. The method of claim 11 further comprising the step of adding up to 80 wt % of a conventional pore forming material to the inorganic ceramic-forming materials wherein the weight % is based on 100% of the inorganic ceramic-forming ingredients.