Electrophotographic developer and image forming method

• US 8,110,331 B2
• Filed: 09/14/2009
• Issued: 02/07/2012
• Est. Priority Date: 09/17/2008
• Status: Expired due to Fees

• Current Assignee: Kabushiki Kaisha Toshiba (Toshiba Corporation), Toshiba Tec Corporation (Toshiba Corporation)
• Original Assignee: Kabushiki Kaisha Toshiba (Toshiba Corporation), Toshiba Tec Corporation (Toshiba Corporation)
• Inventors: Shimmura, Shoko
• Primary Examiner(s): CHAPMAN, MARK A
• Application Number:
  US12/558,743
• Publication Number:
  US 20100068641A1
• Time in Patent Office: 876 Days
• Field of Search: 430/110.4, 430/111.4, 430/111.41, 430/106.1
• US Class Current: 430/110.4
• CPC Class Codes: G03G 15/065 Arrangements for controlling the potential of the developing electrode
• CPC Class Codes: G03G 2215/0607 two-component
• CPC Class Codes: G03G 9/0808 by dry mixing the toner components in solid or softened state
• CPC Class Codes: G03G 9/0819 characterised by the dimensions of the particles
• CPC Class Codes: G03G 9/0821 characterised by physical parameters magnetic parameters G03G9/083
• CPC Class Codes: G03G 9/08755 Polyesters
• CPC Class Codes: G03G 9/09716 treated with organic compounds
• CPC Class Codes: G03G 9/09725 Silicon-oxides; Silicates

Abstract

An electrophotographic developer including: magnetic particles, and a toner containing toner particles charged with the magnetic particles and having a particle diameter distribution, wherein the toner exhibits cumulative toner weight distributions of both square of charge amount q² [C²] and attachment force F [N] per particle with respect to a representative toner particle diameter in the particle diameter distribution, giving a linear approximation of plots of the attachment force F [N] versus the square of charge amount q² [C²] per particle at a plurality of corresponding cumulative toner weight ratios, and the linear approximation satisfies a slope of the linear approximation of from 5×10²⁰ to 3×10²² and a squared multiple correlation coefficient (R²) of 0.6 or more. As a result, the developer allows good control of transferability under the control of an electric field and allows a reduction in transfer residual amount of the toner.

Claims

1. An electrophotographic developer, comprising:

magnetic particles, and a toner containing toner particles charged with the magnetic particles and having a particle diameter distribution, wherein the toner exhibits cumulative toner weight distributions of both square of charge amount q² [C²] and attachment force F [N] per particle with respect to a representative toner particle diameter in the particle diameter distribution, giving a linear approximation of plots of the attachment force F [N] versus the square of charge amount q² [C²] per particle at a plurality of corresponding cumulative toner weight ratios, and the linear approximation satisfies a slope of the linear approximation of from 5×

10²⁰ to 3×

10²² and a squared multiple correlation coefficient (R²) of 0.6 or more.

2. The developer according to claim 1, wherein the representative toner particle diameter is a cumulative 50% by number-average particle diameter.

3. The developer according to claim 1, wherein the representative toner particle diameter, three particle diameters including a cumulative 10% by number particle diameter, a cumulative 50% by number particle diameter (cumulative 50% by number-average particle diameter) and a cumulative 90% by number particle diameter as counted from the smaller particle diameter side, and the linear approximation of plots of the attachment force F [N] versus the square of charge amount q² [C²] for the respective particles having these three particle diameters is with respect to these three particle diameters so as to satisfy a slope of the linear approximation of from 5×

10²⁰ to 3×

10²² and a squared multiple correlation coefficient (R²) of 0.6 or more.

4. The developer according to claim 3, wherein the attachment force F [N] versus the square of charge amount q² [C²] per particle is plotted with respect to the representative three toner particle diameters at five cumulative toner weight ratios of 0.1, 0.3, 0.5, 0.7 and 0.9, respectively.

5. The developer according to claim 1, wherein the attachment force F [N] versus the square of charge amount q² [C²] per particle is plotted with respect to the representative toner particle diameter at five cumulative toner weight ratios of 0.1, 0.3, 0.5, 0.7 and 0.9.

6. The developer according to claim 1, including toner particles obtained by coating toner base particles with particles for improving fluidity by a wet process.

7. The developer according to claim 6, including toner base particles formed by a wet process.

8. An electrophotographic developer, comprising:

magnetic particles, and a toner containing toner particles charged with the magnetic particles and having a particle diameter distribution, wherein the toner exhibits cumulative toner weight distributions of both square of charge amount q² [C²] and attachment force F [N] per particle with respect to three representative particle diameters including a cumulative 10% by number particle diameter, a cumulative 50% by number particle diameter (cumulative 50% by number-average particle diameter) and a cumulative 90% by number particle diameter as counted from the smaller particle diameter side;

wherein the square of charge amount q² [C²] and attachment force F [N] give a linear approximation of a total of 15 plots of the attachment force F [N] versus the square of charge amount q² [C²] per particle at five cumulative toner weight ratios of 0.1, 0.3, 0.5, 0.7 and 0.9 is determined, and the linear approximation satisfies a slope of the linear approximation of from 5×

10²⁰ to 3×

10²² and a squared multiple correlation coefficient (R²) of 0.6 or more.

9. An image forming method, comprising:

developing an electrostatic latent image on an image carrier with a toner containing toner particles triboelectrically charged with magnetic particles and having a particle diameter distribution to form an image of the toner on the image carrier, and transferring the image of the toner onto an intermediate or a final transfer medium;

wherein the toner on the image carrier exhibits cumulative toner weight distributions of both square of charge amount q² [C²] and attachment force F [N] to the image carrier per particle with respect to a representative toner particle diameter in the particle diameter distribution, giving a linear approximation of plots of the attachment force F [N] versus the square of charge amount q² [C²] per particle at a plurality of corresponding cumulative toner weight ratios, and the linear approximation satisfies a slope of the linear approximation of from 5×

10²⁰ to 3×

10²² and a squared multiple correlation coefficient (R²) of 0.6 or more.