Co-feed of biomass as source of makeup catalysts for catalytic coal gasification

• US 8,114,177 B2
• Filed: 02/27/2009
• Issued: 02/14/2012
• Est. Priority Date: 02/29/2008
• Status: Active Grant

• Current Assignee: Sure Champion Investments Limited
• Original Assignee: GreatPoint Energy, Inc.
• Inventors: Hippo, Edwin J., Raman, Pattabhi K.
• Primary Examiner(s): Langel, Wayne
• Assistant Examiner(s): IQBAL, SYED TAHA
• Application Number:
  US12/395,372
• Publication Number:
  US 20090217588A1
• Time in Patent Office: 1,082 Days
• Field of Search: 481/271, 481/97.R, 482/04, 481/987, 48/61, 481/97.A, 482/00, 482/02, 482/09, 482/10, 482/11, 482/14.A, 423/650, 252/373
• US Class Current: 48/197.R
• CPC Class Codes: C10J 2300/09 Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
• CPC Class Codes: C10J 2300/0916 Biomass
• CPC Class Codes: C10J 2300/093 Coal
• CPC Class Codes: C10J 2300/0983 Additives
• CPC Class Codes: C10J 2300/0986 Catalysts
• CPC Class Codes: C10J 3/00 Production of combustible gases containing carbon monoxide from solid carbonaceous fuels destructive distillation processes C10B
• CPC Class Codes: Y02P 20/145 the feedstock being materials of biological origin

Abstract

Continuous processes are provided for converting a carbonaceous feedstock comprising biomass containing alkali metal, non-biomass components, and at least one gasification catalyst including an alkali metal recovered from solid char, into a plurality of gaseous products including methane and at least one or more of hydrogen, carbon monoxide, and other higher hydrocarbons.

Claims

1. A continuous process for converting a carbonaceous feedstock into a plurality of gaseous products, the process comprising the steps of:

(a) providing a biomass material comprising a first source of an alkali metal;

(b) providing a carbonaceous material other than the biomass material;

(c) providing a gasification catalyst comprising a second source of an alkali metal;

(d) preparing the carbonaceous feedstock by intimately mixing the biomass material, carbonaceous material and gasification catalyst;

(e) reacting the carbonaceous feedstock in a gasification reactor in the presence of steam under suitable temperature and pressure to form;

(i) a plurality of gaseous products comprising methane and at least one or more members selected from the group consisting of hydrogen, carbon monoxide, carbon dioxide, hydrogen sulfide, ammonia, and other higher hydrocarbons, and

(ii) a solid char comprising an alkali metal content from the gasification catalyst and the biomass material;

(f) at least partially separating the plurality of gaseous products to produce a gas stream comprising a predominant amount of one of the gaseous products; and

(g) recovering a substantial portion of the alkali metal content from the solid char, wherein;

(1) at least a portion of the alkali metal content is not recovered from the solid char;

(2) the gasification catalyst comprises the alkali metal content recovered from the solid char; and

(3) a makeup catalyst comprising the biomass material, a makeup catalyst material, or both is provided in the carbonaceous feedstock in an amount to maintain a steady-state operational molar ratio of alkali metal atoms to carbon atoms in the carbonaceous feedstock, the steady-state operational molar ratio ranging from about 0.01 to about 0.10.

2. The process according to claim 1, wherein the carbonaceous feedstock comprises anthracite, bituminous coal, sub-bituminous coal, lignite, petroleum coke, asphaltenes, liquid petroleum residues, or mixtures thereof.

3. The process according to claim 2, wherein the petroleum coke comprises petroleum coke derived from tar sands or petroleum coke derived from petroleum refining.

4. The process according to claim 1, wherein the carbonaceous feedstock has a particle size distribution suitable for gasification in a fluidized bed zone and a moisture content of less than about 6 wt % based on the weight of the carbonaceous feedstock.

5. The process according to claim 1, wherein the carbonaceous feedstock has a particle size distribution ranging from about 25 microns to about 2500 microns.

6. The process according to claim 1, wherein the makeup catalyst material comprises potassium hydroxide or potassium carbonate, or both.