Carbon dioxide capture

• US 8,119,091 B2
• Filed: 06/19/2009
• Issued: 02/21/2012
• Est. Priority Date: 06/20/2008
• Status: Active Grant

• Current Assignee: 1446881 Alberta Limited, Carbon Engineering ULC (Occidental Petroleum Corporation)
• Original Assignee: Carbon Engineering Limited Partnership
• Inventors: Keith, David, Mahmoudkhani, Maryam
• Primary Examiner(s): Hendrickson, Stuart
• Assistant Examiner(s): BERNS, DANIEL J
• Application Number:
  US12/488,230
• Publication Number:
  US 20100034724A1
• Time in Patent Office: 977 Days
• Field of Search: 423/220, 423/225, 423/230, 423/419.1, 423/421, 423/437.1, 423/438, 423/598, 951/49, 952/05, 952/30, 952/36
• US Class Current: 423/421
• CPC Class Codes: B01D 2251/304 of sodium
• CPC Class Codes: B01D 2251/604 Hydroxides
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/77 Liquid phase processes
• CPC Class Codes: B01D 53/78 with gas-liquid contact
• CPC Class Codes: B01D 53/96 Regeneration, reactivation or recycling of reactants
• CPC Class Codes: C01D 1/04 Hydroxides
• CPC Class Codes: C01D 7/07 Preparation from the hydroxides
• CPC Class Codes: C01D 7/37 Densifying sodium carbonate
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02P 20/151 Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Abstract

A method of carbon dioxide capture is disclosed. In a step (a) anhydrous sodium carbonate is separated from a first aqueous solution formed by reacting carbon dioxide and an aqueous solution of sodium hydroxide. In step (b) the anhydrous sodium carbonate is treated by causticization to generate carbon dioxide and sodium hydroxide. The first aqueous solution of step (a) is formed by scrubbing a gas containing carbon dioxide with an aqueous solution of sodium hydroxide.

Claims

1. A method, comprising:

separating a hydrate of sodium carbonate from a first aqueous solution formed by reacting carbon dioxide and sodium hydroxide, wherein the first aqueous solution includes sodium hydroxide and sodium carbonate;

dissolving the hydrate of sodium carbonate in a second aqueous solution that includes sodium hydroxide and sodium carbonate, wherein the dissolving occurs in the presence of sodium penta-titanate added to the second aqueous solution;

heating the second aqueous solution to at least a transition temperature of monohydrate sodium carbonate and anhydrous sodium carbonate precipitation to produce anhydrous sodium carbonate, wherein the transition temperature is less than the boiling point of water at standard atmospheric pressure and wherein the sodium penta-titanate hydrolyzes to form sodium tri-titanate and sodium hydroxide; and

causticizing the produced anhydrous sodium carbonate to generate carbon dioxide and sodium hydroxide.

2. A method of claim 1, wherein the causticizing comprises:

reacting the anhydrous sodium carbonate with sodium tri-titanate to produce carbon dioxide gas and sodium penta-titanate; and

regenerating sodium hydroxide and sodium tri-titanate from the sodium penta-titanate.

3. A method of claim 2, in which reacting with sodium tri-titanate is carried out at temperatures at or above the melting point of anhydrous sodium carbonate.

4. A method of claim 1, in which the first aqueous solution is formed by scrubbing a gas containing carbon dioxide with an aqueous solution of sodium hydroxide.

5. A method of claim 2, further comprising:

separating additional anhydrous sodium carbonate solution formed by reacting additional carbon dioxide with the sodium hydroxide remaining in the first aqueous solution after the first separation of anhydrous sodium carbonate; and

causticizing the additional anhydrous sodium carbonate to generate carbon dioxide and sodium hydroxide.

6. A method of claim 5, further comprising hydrolyzing the sodium penta-titanate.

7. A method of claim 1, in which the concentration of sodium carbonate in the first aqueous solution is lower than the concentration of sodium carbonate in the second aqueous solution.

8. A method of any claim 1, in which separating further comprises cooling the first aqueous solution to separate the hydrate of sodium carbonate from the first aqueous solution.

9. A method of claim 1, in which the anhydrous sodium carbonate is produced at elevated pressure.

10. A method of claim 1, in which the hydrate of sodium carbonate comprises sodium carbonate decahydrate.

11. A method of claim 1, in which the pH of the first aqueous solution is high enough during causticizing to reduce co-crystallization of sodium bicarbonate.

12. A method of claim 1, in which the causticizing occurs in the presence of at least 10% carbon dioxide.

13. A method of claim 1 in which the causticizing occurs in the presence of steam.

14. A method comprising:

(a) scrubbing a gas that includes carbon dioxide with an aqueous solution of sodium hydroxide to react the carbon dioxide to form a first aqueous solution that includes sodium hydroxide and sodium carbonate;

(b) separating anhydrous sodium carbonate from the first aqueous solution, the separating comprising;

separating a hydrate of sodium carbonate from the first aqueous solution;

dissolving the hydrate of sodium carbonate in a second aqueous solution that includes sodium hydroxide and sodium carbonate, wherein the dissolving occurs in the presence of sodium penta-titanate added to the second aqueous solution;

heating the second aqueous solution to at least a transition temperature of monohydrate sodium carbonate and anhydrous sodium carbonate precipitation to produce anhydrous sodium carbonate, wherein the transition temperature is less than the boiling point of water at standard atmospheric pressure and wherein the sodium penta-titanate hydrolyzes to form sodium tri-titanate and sodium hydroxide; and

(c) treating the anhydrous sodium carbonate by causticization to generate carbon dioxide and sodium hydroxide.

15. A method of claim 14 further comprising:

treating the anhydrous sodium carbonate by causticization with sodium tri-titanate to generate carbon dioxide and sodium hydroxide.

16. A method comprising:

(a) scrubbing a gas that includes carbon dioxide with an aqueous solution of alkali metal hydroxide resulting in a first aqueous solution that includes alkali metal carbonate and the alkali metal hydroxide;

(b) separating anhydrous alkali metal carbonate from the first aqueous solution, the separating comprising;

separating a hydrate of alkali metal carbonate from the first aqueous solution;

dissolving the hydrate of alkali metal carbonate in a second aqueous solution that includes alkali metal hydroxide and alkali metal carbonate, wherein the dissolving occurs in the presence of sodium penta-titanate added to the second aqueous solution;

heating the second aqueous solution to at least a transition temperature of monohydrate alkali metal carbonate and anhydrous alkali metal carbonate precipitation to produce anhydrous alkali metal carbonate, wherein the transition temperature is less than the boiling point of water at standard atmospheric pressure and wherein the sodium penta-titanate hydrolyzes to form sodium tri-titanate and alkali metal hydroxide; and

(c) treating the anhydrous alkali metal carbonate by causticization to generate carbon dioxide and alkali metal hydroxide.

17. A method comprising:

(a) scrubbing a gas that includes carbon dioxide with an aqueous solution of sodium hydroxide to react the carbon dioxide to form a first aqueous solution that includes sodium hydroxide and sodium carbonate;

(b) separating anhydrous sodium carbonate from the first aqueous solution, the separating comprising;

separating a hydrate of sodium carbonate from the first aqueous solution;

dissolving the hydrate of sodium carbonate in a second aqueous solution that includes sodium hydroxide and sodium carbonate, wherein the dissolving occurs in the presence of sodium penta-titanate added to the second aqueous solution;

heating the second aqueous solution to at least a transition temperature of monohydrate sodium carbonate and anhydrous sodium carbonate precipitation to produce anhydrous sodium carbonate, wherein the transition temperature is less than the boiling point of water at standard atmospheric pressure and wherein the sodium penta-titanate hydrolyzes to form sodium tri-titanate and sodium hydroxide; and

(c) treating the anhydrous sodium carbonate by causticization to generate carbon dioxide and sodium hydroxide, wherein the carbon dioxide that is formed exclusively comes from the scrubbed gas.