Smoothing method for layered deposition modeling

• US 8,123,999 B2
• Filed: 04/04/2003
• Issued: 02/28/2012
• Est. Priority Date: 04/17/2002
• Status: Active Grant

• Current Assignee: Dyemansion GMBH
• Original Assignee: Stratasys Incorporated
• Inventors: Priedeman, William R. Jr., Smith, David Thomas
• Primary Examiner(s): GOFF II, JOHN L
• Application Number:
  US10/511,784
• Publication Number:
  US 20050173838A1
• Time in Patent Office: 3,252 Days
• Field of Search: 156/244.11, 264/308, 264/341, 264/401, 700/119, 34/73, 34/72, 344/43
• US Class Current: 264/341
• CPC Class Codes: B29C 41/48 Compensating volume change, e.g. retraction
• CPC Class Codes: B29C 64/124 using layers of liquid which are selectively solidified
• CPC Class Codes: B29C 64/135 the energy source being concentrated, e.g. scanning lasers or focused light sources
• CPC Class Codes: B29C 71/0009 using liquids, e.g. solvents, swelling agents spectacle cases, e.g. for cleaning contact lenses A45C11/04; disinfecting or sterilising contact lenses A61L12/00, using liquid substances A61L2/20; cleaning involving the use of liquid in general B08B3/00; for hydrating contact lenses B29D11/00067
• CPC Class Codes: B29K 2995/0073 smooth
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 40/20 Post-treatment, e.g. curing, coating or polishing
• CPC Class Codes: B33Y 70/00 Materials specially adapted for additive manufacturing

Abstract

Disclosed is a method for smoothing the surface of an object built from a polymeric or wax material using a layered manufacturing rapid prototyping technique. After the object is built it is exposed to a vaporized solvent such as in a vaporizer for an exposure time sufficient to reflow the object surface. A solvent is chosen based on its ability to transiently soften the material which forms the object, and thereafter evaporate off the object. The object is removed from the solvent and allowed to dry, producing a smooth finished part.

Claims

1. A method for making a three-dimensional object comprising the steps of:

providing an object built from a modeling material using a fused deposition modeling technique, wherein the modeling material comprises a thermoplastic resin, wherein the built object has an object surface formed of the modeling material, the object surface having at least one surface effect due to the fused deposition modeling technique that extends substantially across an entirety of the object surface, wherein the at least one surface effect comprises a stair step effect, striation, or a combination thereof, and wherein the object exhibits porosity due to the fused deposition modeling technique;

placing the object in a vessel;

exposing substantially the entire object surface to vapors of a solvent that transiently softens the modeling material at the object surface while the object resides in the vessel in a solvent vapor zone present below cooling elements in the vessel;

reflowing the softened modeling material to reduce the at least one surface effect and to reduce the porosity of the object at the object surface;

observing condensation of the solvent vapors on the object surface while reflowing the softened modeling material;

discontinuing the exposure of the object surface to the solvent vapors after the condensation of the solvent vapors stops; and

drying the object after discontinuing the exposure, wherein the object surface of the dried object is substantially free of the at least one surface effect and is substantially free of the porosity.

2. The method of claim 1, wherein the thermoplastic resin comprises at least about 50 weight percent of an amorphous thermoplastic selected from the group consisting of ABS, polycarbonate, polyphenylsulfone, polysulfone, polystyrene, polyphenylene ether, amorphous polyamides, acrylics, poly(2-ethyl-2-oxazoline), and blends thereof.

3. The method of claim 2, wherein the solvent is selected from the group consisting of methylene chloride, an n-Propyl bromide solution, perchloroethylene, trichloroethylene, and a hydrofluorocarbon fluid.

4. The method of claim 1, and further comprising the step of:

masking selected portions of the object surface with a substance that will inhibit smoothing of the selected portions, prior to the step of exposing the object to the vapors of the solvent.

5. The method of claim 1, and further comprising building the object using the fused deposition modeling technique.

6. The method of claim 1, and further comprising the step of:

suspending the object in the vessel containing the vapors of the solvent in a manner that substantially allows the entirety of the object surface to be exposed to the vapors of the solvent.

7. The method of claim 1, and further comprising the steps of:

providing an initial object representation in a digital format, the initial object representation having a surface geometry; and

modifying the initial object representation to pre-distort certain features of the surface geometry, producing a modified object representation;

wherein the object built in the building step has a geometry defined according to the modified object representation; and

wherein the desired geometry attained following the exposing step approximately matches that of the initial object representation.

8. A method for making a three-dimensional object comprising the steps of:

providing an object built from a plurality of layers with a modeling material using a fused deposition modeling technique, wherein the modeling material comprises a thermoplastic resin, wherein the object has an object surface, and wherein the plurality of layers create at least one surface effect extending substantially across an entirety of the object surface, wherein the at least one surface effect comprises a stair step effect, striation, or a combination thereof, and wherein the object exhibits porosity due to the fused deposition modeling technique;

placing the object in a vessel;

exposing substantially the entire object surface to vapors of a solvent while the object resides in the vessel in a solvent vapor zone present below cooling elements in the vessel;

penetrating the object surface with the vapors of the solvent to soften the modeling material at the object surface;

reflowing the softened modeling material to reduce the at least one surface effect substantially across the entirety of the object surface and to reduce the porosity of the object at the object surface;

observing condensation of the solvent vapors on the object surface while reflowing the softened modeling material;

discontinuing the exposure of the object surface to the solvent vapors after the condensation of the solvent vapors stops; and

drying the object after discontinuing the exposure, wherein the object surface of the dried object is substantially free of the at least one surface effect and is substantially free of the porosity.

9. The method of claim 8, wherein the thermoplastic resin comprises at least about 50 weight percent of an amorphous thermoplastic selected from the group consisting of ABS, polycarbonate, polyphenylsulfone, polysulfone, polystyrene, polyphenylene ether, amorphous polyamide, methyl methacrylate, poly(2-ethyl-2-oxazoline), and blends thereof.

10. The method of claim 8, and further comprising the step of:

masking selected portions of the object surface with a substance that will inhibit smoothing of the selected portions, prior to the step of reflowing the surface.

11. The method of claim 10, wherein the masking substance is applied using an automatic process selected from the group consisting of a jetting process and a fused deposition modeling process.

12. The method of claim 8, wherein the solvent is selected from the group consisting of methylene chloride, an n-Propyl bromide solution, perchloroethylene, trichloroethylene, a hydrofluorocarbon fluid, and combinations thereof.

13. A method for treating a three-dimensional object, the method comprising:

providing the three-dimensional object, the three-dimensional object being previously built from a modeling material comprising a thermoplastic resin using a fused deposition modeling technique, wherein the three-dimensional object comprises an exterior surface having at least one surface effect caused by the fused deposition modeling technique that extends substantially across an entirety of the exterior surface, wherein the at least one surface effect comprises a stair-step effect created by layering of a plurality of layers of the modeling material, striation created by formation of roads of the modeling material, or a combination thereof, and wherein the three-dimensional object exhibits porosity due to the fused deposition modeling technique;

placing the three-dimensional object in a vessel configured to contain solvent vapors;

while the three-dimensional object resides in the vessel, exposing substantially the entire exterior surface of the three-dimensional object while the object is in a solvent vapor zone present below cooling elements in the vessel to the solvent vapors, wherein the solvent vapors transiently soften the modeling material across the entire exposed exterior surface of the three-dimensional object;

observing condensation of the solvent vapors on the exterior surface of the three-dimensional object while the exterior surface of the three-dimensional object is exposed to the solvent vapors;

removing the three-dimensional object from the vessel after the condensation of the solvent vapors on the exterior surface of the three-dimensional object stops; and

drying the three-dimensional object after removing the three-dimensional object from the vessel, wherein the entire exposed exterior surface of the dried three-dimensional object is substantially free of the at least one surface effect and is substantially free of the porosity.

14. The method of claim 13, wherein the vessel is configured to be maintained at or above a boiling point of a solvent of the solvent vapors.

15. The method of claim 13, wherein the thermoplastic resin is selected from the group consisting of ABS, polycarbonate, polyphenylsulfone, polysulfone, polystyrene, polyphenylene ether, amorphous polyamides, acrylics, poly(2-ethyl-2-oxazoline), and blends thereof.

16. The method of claim 13, wherein the solvent is selected from the group consisting of methylene chloride, an n-Propyl bromide solution, perchloroethylene, trichloroethylene, a hydrofluorocarbon fluid, and combinations thereof.

17. The method of claim 13, wherein placing the three-dimensional object in the vessel comprises suspending the three-dimensional object in the vessel.

18. The method of claim 13, and further comprising masking selected portions of the exterior surface with a substance that will inhibit smoothing of the selected portions.