Fuel cell components including immobilized heteropolyacids

• US 8,129,069 B2
• Filed: 09/29/2006
• Issued: 03/06/2012
• Est. Priority Date: 09/30/2005
• Status: Active Grant

• Current Assignee: Battelle Memorial Institute
• Original Assignee: Battelle Memorial Institute
• Inventors: Lalgudi, Ramanathan S., Sayre, Jay R., Vijayendran, Bhima R.
• Primary Examiner(s): RHEE, JANE J
• Application Number:
  US11/992,826
• Publication Number:
  US 20110003231A1
• Time in Patent Office: 1,985 Days
• Field of Search: 429/479, 429/496, 429/532
• US Class Current: 429/479
• CPC Class Codes: H01B 1/122 Ionic conductors
• CPC Class Codes: H01M 2300/0082 Organic polymers
• CPC Class Codes: H01M 8/0221 Organic resins; Organic polymers
• CPC Class Codes: H01M 8/1011 Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
• CPC Class Codes: H01M 8/1027 having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
• CPC Class Codes: H01M 8/1032 having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
• CPC Class Codes: H01M 8/1048 Ion-conducting additives, e.g. ion-conducting particles, heteropolyacids, metal phosphate or polybenzimidazole with phosphoric acid
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A fuel cell component is made with a composite including a proton conducting polymer, a water insoluble proton conducting inorganic material, and a heteropolyacid immobilized by chemically bonding to the inorganic material. In another embodiment, the fuel cell component is made with a composite including a non-proton conducting polymer, a water insoluble inorganic material, and a heteropolyacid immobilized by chemically bonding to the inorganic material, the heteropolyacid causing the composite to show proton conductivity. In a further embodiment, the fuel cell component is made with a composite comprising a proton conducting polymer, a water insoluble proton conducting inorganic material, and a heteropolyacid immobilized by chemically bonding to the inorganic material, the composite having substantially identical structure of the unmodified heteropolyacid.

Claims

1. A fuel cell component made with a composite comprising a proton conducting polymer, a water insoluble proton conducting inorganic material, and a heteropolyacid immobilized by chemically bonding to the inorganic material, wherein the composite comprises particles having an average diameter less than about 30 nanometers.

2. The fuel cell component defined in claim 1 wherein the proton conducting polymer has functional groups causing the polymer to act as a steric stabilizer during production of the composite thereby stabilizing the growing particles.

3. The fuel cell component defined in claim 1 wherein the immobilization of heteropolyacid is carried out in polymer solution or in polymer film.

4. The fuel cell component defined in claim 1 wherein the heteropolyacid includes tungsten or molybdenum.

5. The fuel cell component defined in claim 1 wherein the inorganic material is a metal compound.

6. The fuel cell component defined in claim 1 wherein the heteropolyacid is immobilized on water insoluble metal phosphate or metal phosphonate.

7. The fuel cell component defined in claim 1 wherein the amount of immobilized HPA varies from 0.5 to 75 wt %.

8. The fuel cell component defined in claim 1 wherein the ratio of HPA to inorganic insoluble inorganic precursor ranges between 0.1 and 25.

9. The fuel cell component defined in claim 1 wherein the acidity of immobilized HPA and unmodified HPA are substantially identical.

10. The fuel cell component defined in claim 1 wherein the surface area of immobilized HPA is substantially identical to or greater than unmodified HPA.

11. The fuel cell component defined in claim 1 wherein the porosity of immobilized HPA is substantially identical to or greater than unmodified HPA.

12. The fuel cell component defined in claim 1 wherein the immobilized HPA is not substantially soluble and/or extractable by liquid water.

13. The fuel cell component defined in claim 1 wherein the immobilized HPA is not substantially soluble and/or extractable by 1.5 M sulfuric acid.

14. The fuel cell component defined in claim 1 wherein the immobilized HPA is not substantially soluble and/or extractable by liquid methanol, ethanol, butanol and higher alcohols.

15. The fuel cell component defined in claim 1 wherein the immobilized HPA is not substantially soluble and/or extractable by hydrogen peroxide.

16. The fuel cell component defined in claim 1 wherein the immobilized HPA is not substantially soluble and/or extractable by formic acid.

17. The fuel cell component defined in claim 1 wherein the fuel cell component is a membrane electrode assembly and the composite is used as a binder in the membrane electrode assembly.

18. The fuel cell component defined in claim 1 wherein the composite has substantially similar structure of the unmodified heteropolyacid.

19. The fuel cell component defined in claim 18 wherein the composite has a high acidity characterized by very high ion exchange capacity greater than 1.0 ineq/g.

20. The fuel cell component defined in claim 18 wherein the fuel cell component is a polymer electrolyte membrane having a conductivity of at least 0.01 S/cm at a humidity of 50%.

21. The fuel cell component defined in claim 18 wherein the heteropolyacid and the inorganic material do not include functional groups.

22. The fuel cell component defined in claim 1 wherein the composite has a conductivity of at least 0.0001 S/cm at a relative humidity of 50%.