Process for producing petroleum coke

• US 8,137,530 B2
• Filed: 04/15/2008
• Issued: 03/20/2012
• Est. Priority Date: 06/22/2007
• Status: Active Grant

• Current Assignee: JX Nippon Oil & Energy Corporation (ENEOS Holdings, Inc.)
• Original Assignee: Nippon Petroleum Refining Co. Ltd. (ENEOS Holdings, Inc.)
• Inventors: Tano, Tamotsu, Oyama, Takashi, Nakanishi, Kazuhisa, Oda, Toshiyuki, Higashi, Keiji
• Primary Examiner(s): MCAVOY, ELLEN M
• Application Number:
  US12/664,504
• Publication Number:
  US 20100181228A1
• Time in Patent Office: 1,435 Days
• Field of Search: 208/14, 208/50
• US Class Current: 208/14
• CPC Class Codes: C10B 57/045 containing mineral oils, bitumen, tar or the like or mixtures thereof
• CPC Class Codes: C10G 2300/202 Heteroatoms content, i.e. S, N, O, P
• CPC Class Codes: C10G 2300/206 Asphaltenes
• CPC Class Codes: C10G 2300/301 Boiling range
• CPC Class Codes: C10G 2300/4012 Pressure
• CPC Class Codes: C10G 9/005 Coking (in order to produce liquid products mainly)

Abstract

A process is provided for producing petroleum coke that is high in strength and sufficiently small in thermal expansion coefficient and sufficiently suppressed from puffing. The process includes coking a feedstock containing a first heavy oil having a sulfur content of 1.0 percent by mass or less, a nitrogen content of 0.5 percent by mass or less, and an aromatic index of 0.1 or greater, produced by hydrodesulfurizing a heavy oil with a sulfur content of 1 percent by mass or more under conditions (1) where the total pressure is 10 MPa or greater and less than 16 MPa and the hydrogen partial pressure is 5 MPa or greater and 16 MPa or less or conditions (2) where the total pressure is 20 MPa or greater and 25 MPa or less and the hydrogen partial pressure is greater than 20 MPa and 25 MPa or less, and a second heavy oil with an aromatic index of 0.3 or greater and an initial boiling point of 150° C. or higher.

Claims

1. A process of producing petroleum coke comprising:

coking a feedstock comprising a first heavy oil comprising 1 to 50 percent by mass and a second heavy oil comprising 50 to 99 percent by mass based on a total amount of the feedstock;

wherein the first heavy oil has a sulfur content of 1.0 percent by mass or less, a nitrogen content of 0.5 percent by mass or less, an aromatic index of 0.1 to 0.21, a saturate content of 53 percent by mass or more and a total of an asphaltene content and a resin content of 10 percent by mass or less, and is produced by hydrodesulfurizing an atmospheric distillation residue or a vacuum distillation residue with a sulfur content of 1 percent by mass or more under conditions (1) where the total pressure is 10 MPa or greater and less than 16 MPa and the hydrogen partial pressure is 5 MPa or greater and 16 MPa or less or conditions (2) where the total pressure is 20 MPa or greater and 25 MPa or less and the hydrogen partial pressure is greater than 20 MPa and 25 MPa or less, and

wherein the second heavy oil has an aromatic index of 0.4 to 0.9 and an initial boiling point of 150°

C. or higher, and is produced by catalytic fluidized cracking a vacuum gas oil or a desulfurized vacuum gas oil.

2. A petroleum coke produced by the process according to claim 1.

3. The petroleum coke according to claim 1 wherein it has a microstrength value of 34 percent or greater, a sulfur content of 0.5 percent by mass or less, and a nitrogen content of 0.3 percent by mass or less.