Magnetic carrier, two-component developer and image forming method

• US 8,137,886 B2
• Filed: 01/21/2010
• Issued: 03/20/2012
• Est. Priority Date: 08/04/2008
• Status: Expired due to Fees

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Baba, Yoshinobu, Ishigami, Koh, Endo, Tomoko, Fujikawa, Hiroyuki, Nakamura, Kunihiko, Komatsu, Nozomu, Inoue, Chika, Itakura, Takayuki
• Primary Examiner(s): Dote, Janis L
• Application Number:
  US12/691,049
• Publication Number:
  US 20100143833A1
• Time in Patent Office: 789 Days
• Field of Search: 430/111.3, 430/111.31, 430/111.32, 430/111.33, 430/111.35, 430/111.41, 430/110.3
• US Class Current: 430/110.3
• CPC Class Codes: G03G 9/1075 Structural characteristics of the carrier particles, e.g. shape or crystallographic structure
• CPC Class Codes: G03G 9/1085 with non-ferrous metal oxide, e.g. MgO-Fe2O3
• CPC Class Codes: G03G 9/1131 Coating methods; Structure of coatings
• CPC Class Codes: G03G 9/1136 containing silicon atoms

Abstract

A magnetic carrier is provided which uses a toner having high coloring power and enables development to be performed at low electric field intensity and can form high quality images while keeping gradation characteristics. The magnetic carrier includes magnetic carrier particles including at least porous magnetic core particles and a resin. The electric field intensity just before the break-down of the magnetic carrier is 1,300 V/cm or more and 5,000 V/cm or less.

Claims

1. A magnetic carrier comprising resin-coated magnetic carrier particles, each of which comprises a porous magnetic core particle made from magnetic ferrite,

wherein the surface of the porous magnetic core particle is partially exposed, and

wherein the magnetic carrier has an electric field intensity just before break-down of 1,300 V/cm or more and 5,000 V/cm or less.

2. The magnetic carrier according to claim 1, wherein the magnetic carrier does not cause break-down at electric field intensity less than 1,300 V/cm and causes break-down at electric field intensity more than 5,000 V/cm.

3. The magnetic carrier according to claim 1, wherein the porous core particle has a resistivity of 1.0×

10⁶ Ω

·

cm or more and 5.0×

10⁷ Ω

·

cm or less at an electric field intensity of 300 V/cm.

4. The magnetic carrier according to claim 1, wherein the porous core particle has a pore size of 0.8 μ

m or more and 1.5 μ

m or less corresponding to a maximum differential pore volume in a pore size range of 0.1 μ

m or more and 3.0 μ

m or less as measured by a mercury intrusion method.

5. The magnetic carrier according to claim 1, wherein the pores of the porous magnetic core particle are filled with a silicone resin.

6. The magnetic carrier according to claim 1, wherein the porous core particle has an electric field intensity just before break-down of 400 V/cm or more and 1,000 V/cm or less.

7. The magnetic carrier according to claim 1, wherein the magnetic carrier has a resistivity of 1.0×

10⁶ Ω

·

cm or more and 5.0×

10^{1 0}Ω

·

cm or less at an electric field intensity of 2,000 V/cm.

8. A two-component developer comprising at least a magnetic carrier and a toner, wherein the magnetic carrier is a magnetic carrier according to claim 1.

9. The two-component developer according to claim 8, wherein an average circularity of the toner having a circle-equivalent diameter of 1.985 μ

m or more and less than 39.69 μ

m is 0.940 or more and 1.000 or less.

10. The two-component developer according to claim 8, wherein the toner comprises toner particles and inorganic particles having at least one local maximum in the range of 80 nm or more to 200 nm or less in number-based particle size distribution.

11. The two-component developer according to claim 8, wherein an absolute value of a frictional charge amount measured by applying a two-component method to a two-component developer comprising at least the toner and the magnetic carrier in which a toner concentration is set to be 8 mass % is 40.0 mC/kg or more and 80.0 mC/kg or less.