Color-stable phosphor converted LED

• US 8,138,671 B2
• Filed: 04/26/2007
• Issued: 03/20/2012
• Est. Priority Date: 05/02/2006
• Status: Active Grant

• Current Assignee: Lumileds LLC (Apollo Global Management, Inc.)
• Original Assignee: Koninklijke Philips Electronics N.V. (Koninklijke Philips N.V.)
• Inventors: Hildenbrand, Volker Dirk, Mercier, Virginie, Hendriks, Rene Jan
• Primary Examiner(s): Williams, Joseph L
• Assistant Examiner(s): LEE, NATHANIEL J.
• Application Number:
  US12/298,966
• Publication Number:
  US 20090128028A1
• Time in Patent Office: 1,790 Days
• Field of Search: 313483-512, 427/219, 430/7
• US Class Current: 313/506
• CPC Class Codes: H01L 33/44 characterised by the coatings, e.g. passivation layer or anti-reflective coating
• CPC Class Codes: H01L 33/50 Wavelength conversion elements

Abstract

A light-emitting device is provided, comprising at least one light-emitting diode (100) for emitting light of a first color and a luminescent material (102) arranged on said at least one light-emitting diode to receive at least part of the light emitted by said light-emitting diode. The light-emitting device further comprises a filter (103) arranged to receive light emitted by said light-emitting diode (100) and transmitted through said luminescent material (102) and to absorb light of said first color. The filter comprises a pigment compound distributed in a matrix of silicon and oxygen atoms, in which matrix at least a portion of said silicon atoms are directly bonded to hydrocarbon groups.

Claims

1. A light-emitting device, comprising at least one light-emitting diode for emitting light of a first color and a luminescent material arranged on said at least one light-emitting diode to receive at least part of the light emitted by said light-emitting diode,

characterized in that said light-emitting device further comprises a filter arranged to receive light emitted by said light-emitting diode and transmitted through said luminescent material and to absorb light of said first color;

and

said filter comprises a pigment compound distributed in a matrix of silicon and oxygen atoms, in which matrix at least a portion of said silicon atoms are directly bonded to hydrocarbon groups

wherein at least part of the silicon atoms are bridged to another silicon atom via an oxygen atom forming bridged pairs and wherein at least part of the bridged pairs coordinates 3 oxygen atoms and 1 hydrocarbon atom with each of the bridged silicon atoms.

2. A light-emitting device according to claim 1, wherein at least 10% of said silicon atoms are directly bonded to hydrocarbon groups.

3. A light-emitting device according to claim 1, wherein at least 95% of said silicon atoms are directly bonded to hydrocarbon groups.

4. A light-emitting device according to claim 1, wherein said hydrocarbon groups are selected from among alkyls and aryls.

5. A light-emitting device according to claim 4, wherein said matrix is the result from polymerizing a composition comprising R1-trialkoxysilane, where R1 is selected from the group consisting of alkyl and aryls.

6. A light-emitting device according to claim 5, wherein R1 is selected from among methyl, ethyl, propyl and phenyl.

7. A light-emitting device according to claim 5, wherein said R1-trialkoxysilane is selected from the group consisting of R1-trimethoxysilane and R1-triethoxysilane.

8. A light-emitting device according to claim 4, wherein said composition further comprises tetraalkoxysilane.

9. A light-emitting device according to claim 1, wherein said pigment compound is essentially non-luminescent.

10. A light-emitting device according to claim 1, wherein said pigment compound is in the form of particles having a mean particle diameter of less than 250 nm.

11. A light-emitting device according to claim 1, wherein said pigment compound is selected from the group consisting of noble metal colloid particles, inorganic pigments, organic pigments, and any combinations of two or more thereof.

12. A light-emitting device according to claim 1, wherein said filter further comprises filler material particles.

13. A light-emitting device according to claim 1, wherein said filter is arranged on top of said luminescent material.

14. A light-emitting device according to claim 1, further comprising an optical element arranged to receive light emitted by said light-emitting diode, wherein said filter is arranged on said optical element.

15. A light-emitting device according to claim 1, wherein said first color is UV or blue.

16. A light-emitting device according to claim 1, wherein said luminescent material absorbs light of said first color and emits green, amber or red light.

17. A method for the manufacture of a light-emitting device, comprising:

providing at least one light-emitting diode for emitting light of a first color, on which light-emitting diode a luminescent material is arranged to receive at least part of the light emitted by said light-emitting diode;

arranging, on said luminescent material, a filter by arranging and polymerizing a polymerizable composition on said luminescent material, which polymerizable composition comprises at least an organically modified silane having the general formula R1-trialkoxysilane and a pigment compound in a liquid medium, wherein R1 is selected from the group consisting of aryls and alkyls,

wherein at least part of the silicon atoms are bridged to another silicon atom via an oxygen atom forming bridged pairs and wherein at least part of the bridged pairs coordinates 3 oxygen atoms and 1 hydrocarbon atom with each of the bridged silicon atoms, and wherein said pigment compound absorbs light of said first color.

18. A method according to claim 17, wherein said filter further comprises filler material particles.

20. A method according to claim 17, wherein said composition further comprises a tetraalkoxysilane, where the molar ratio R1-trialkoxysilane:

tetraalkoxysilane is in the range of from 1;

9 to 10;

0.

21. A method according to claim 17, wherein said R1-trialkoxysilane is selected from the group consisting of methyl-, ethyl-, propyl and phenyl-trimethoxysilane and -triethoxysilane, and any combination of two or more thereof.

22. A method according to claim 17, wherein said pigment compound is essentially non-luminescent.

23. A method according to claim 17, wherein said pigment compound is in the form of particles having a mean particle diameter of less than 250 nm.

24. A method according to claim 17, wherein said pigment compound is selected from the group consisting of noble metal colloid particles, inorganic pigments, organic pigments, and any combinations of two or more thereof.

19. A method for the manufacture of a light-emitting device, comprising:

providing at least one light-emitting diode for emitting light of a first color, on which light-emitting diode a luminescent material is arranged to receive at least part of the light emitted by said light-emitting diode;

providing an optical element;

arranging, on said optical element, a filter by arranging and polymerizing a composition on said optical element, which composition comprises at least an organically modified silane having the general formula R1-trialkoxysilane and a pigment compound in a liquid medium,

wherein at least part of the silicon atoms are bridged to another silicon atom via an oxygen atom forming bridged pairs and wherein at least part of the bridged pairs coordinates 3 oxygen atoms and 1 hydrocarbon atom with each of the bridged silicon atoms, wherein R1 is selected from the group consisting of aryls and alkyls, and wherein said pigment compound absorbs light of said first color; and

arranging said optical element such that said filter receives light emitted by said light-emitting diode and transmitted through said luminescent material.