High-efficiency water-softening process

• US 8,147,696 B1
• Filed: 09/19/2006
• Issued: 04/03/2012
• Est. Priority Date: 09/19/2006
• Status: Active Grant

• Current Assignee: AWTS, Inc.
• Original Assignee: AWTS, Inc.
• Inventors: Pandya, Ken V.
• Primary Examiner(s): Hruskoci, Peter A
• Application Number:
  US11/523,679
• Time in Patent Office: 2,023 Days
• Field of Search: 210/705
• US Class Current: 210/638
• CPC Class Codes: C02F 1/001 Processes for the treatment of water whereby the filtration technique is of importance C02F1/44 takes precedence; construction of filters in general B01D24/00 - B01D41/00
• CPC Class Codes: C02F 1/5236 using inorganic agents
• CPC Class Codes: C02F 1/56 Macromolecular compounds
• CPC Class Codes: C02F 1/66 by neutralisation; pH adjustment for degassing C02F1/20; using ion-exchange C02F1/42; for flocculation or precipitation of suspended impurities C02F1/52; for removing dissolved compounds C02F1/58
• CPC Class Codes: C02F 11/121 by mechanical de-watering
• CPC Class Codes: C02F 2001/007 Processes including a sedimentation step
• CPC Class Codes: C02F 2101/203 Iron or iron compound
• CPC Class Codes: C02F 2101/206 Manganese or manganese compounds
• CPC Class Codes: C02F 2101/32 Hydrocarbons, e.g. oil
• CPC Class Codes: C02F 2209/001 Upstream control, i.e. monitoring for predictive control
• CPC Class Codes: C02F 2209/10 Solids, e.g. total solids [TS], total suspended solids [TSS] or volatile solids [VS]
• CPC Class Codes: C02F 2209/20 Total organic carbon [TOC]
• CPC Class Codes: C02F 5/02 Softening water by precipitation of the hardness
• CPC Class Codes: C02F 5/06 using calcium compounds
• CPC Class Codes: Y10S 210/912 Heavy metal

Abstract

A method for purifying a water process stream whereby a precipitating agent is added to the water process stream to elevate the process stream pH to at least 10.5 to drop out precipitates which form separated solids comprising at least one of calcium precipitate, magnesium precipitate, barium precipitate, strontium precipitate, and silica precipitate. The separated solids are then coagulated and removed from the water process stream so as to yield a purified water process stream.

Claims

1. A process for removing at least some contaminants selected from the group consisting of Ca, Mg, Ba, Sr, Cu, Zn, iron, Mn, Al, SiO₂, TOC, oil, grease and TDS and TSS from a contaminated water stream, the process consisting essentially of:

a) collecting a quantity of the water stream containing said contaminants for treatment;

b) analyzing the water stream containing said contaminants for a composition and an amount of said contaminants in the water stream;

c) adding a calculated amount of at least one of carbonate or bicarbonate to the quantity of the water stream in an amount at least equivalent to said contaminants in the quantity of the water stream;

d) adjusting the pH of the quantity of the water stream to a value from about 10.5 to 14 with sodium hydroxide or potassium hydroxide;

e) adding a coagulation aid chemical to the quantity of the water stream;

f) adding at least one polyelectrolyte selected from the group consisting of positive or negative polyelectrolyte chemicals to the quantity of the water stream;

g) allowing solids formed including said contaminants and carbonate and hydroxide precipitates in the quantity of the water stream to settle or rise in the water;

h) separating the solids from the quantity of the water stream; and

,

i) recovering the water stream containing a reduced contaminant content.

2. The process of claim 1 wherein the quantity of the water stream is collected in a storage tank containing a separation system for removing precipitated contaminants from the storage tank.

3. The process of claim 1 wherein the coagulation chemical is selected from the group consisting of ferric chloride, alum, ferric sulfate and a waste caustic soda from an alumina plant.

4. The process of claim 1 wherein the formed solids settle in the quantity of the water stream.

5. The process of claim 1 wherein the formed solids remain in suspension or float in the quantity of the water stream.

6. The process of claim 1 wherein the formed solids are separated from the quantity of the water stream by a mechanical solid/liquid separator.

7. The process of claim 6 wherein the mechanical solids/liquid separator is selected from the group consisting of a rotary drum vacuum filter, a filter press, a media filter, a membrane filter, or an ultra-filter system or a micro-filter system.

8. The process of claim 1 wherein the calcium and magnesium contaminants in the quantity of the water stream are removed to a level less than 100 parts per million.

9. The process of claim 1 wherein the calcium and magnesium contaminants in the quantity of the water stream are reduced to less than 99 percent of the calcium and magnesium initially present.

10. The process of claim 1 wherein steps a), c), d), e), and f) may be carried out in the storage tank.

11. The process of claim 1 wherein the pH is adjusted to from about 12 to about 14.

12. The process of claim 1 wherein the calcium and magnesium contents, stated as CaCO₃, of the water is reduced to less than 100 ppm and the TOC content of the water is reduced by up to 84 percent.