Process, plant and biofuel for integrated biofuel production

• US 8,152,867 B2
• Filed: 12/17/2008
• Issued: 04/10/2012
• Est. Priority Date: 12/17/2008
• Status: Expired due to Fees

• Current Assignee: BP Biofuels UK Ltd. (BP PLC)
• Original Assignee: BP Biofuels UK Ltd. (BP PLC)
• Inventors: Dumenil, Jean-Charles
• Primary Examiner(s): Toomer, Cephia D
• Application Number:
  US12/336,719
• Publication Number:
  US 20100146843A1
• Time in Patent Office: 1,210 Days
• Field of Search: 435/160, 435/289.1, 435/170, 568/840, 422/600
• US Class Current: 44/307
• CPC Class Codes: C10L 1/02 essentially based on components consisting of carbon, hydrogen, and oxygen only
• CPC Class Codes: C10L 1/04 essentially based on blends of hydrocarbons
• CPC Class Codes: C10L 1/18 containing oxygen
• CPC Class Codes: C12P 7/16 Butanols
• CPC Class Codes: C12P 7/6458 by transesterification, e.g. interesterification, ester interchange, alcoholysis or acidolysis
• CPC Class Codes: C12P 7/649 Biodiesel, i.e. fatty acid alkyl esters
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02P 20/10 Process efficiency

Abstract

This invention relates to a process, a plant, and a biofuel for integrated biofuel production, such as with butanol, biodiesel, and/or sugar product. The integrated process includes the step of removing hexose from a feedstock to form a lignocellulosic material. The process also includes the step of converting the hexose to butanol and/or a biodiesel material, and the step of depolymerizing lignocellulosic material to form pentose and a residue. The process also includes the step of converting the pentose to butanol and/or a biodiesel material.

Claims

1. An integrated process of coproducing butanol and biodiesel, the process comprising:

removing hexose from a feedstock to form a lignocellulosic material;

converting the hexose to butanol;

depolymerizing the lignocellulosic material to form pentose and a residue; and

converting the pentose to a biodiesel material.

2. The process of claim 1, further comprising a mass ratio of biodiesel to butanol of at least about 0.2 kilotons of biodiesel to 1.0 kiloton of butanol.

3. The process of claim 1, wherein the feedstock comprises sugarcane, energy cane, corn, maize, sorghum, sweet sorghum, sugar beet, or combinations thereof.

4. The process of claim 1, wherein the depolymerizing the lignocellulosic material to form pentose comprises an acidic process, a basic process, an enzymatic process, a solvent process, or combinations thereof.

5. The process of claim 1, wherein the converting the pentose to the biodiesel material comprises a microorganism process.

6. The process of claim 1, wherein the converting the pentose to the biodiesel material comprises an algae process, a bacterial process, a fungal process, a free enzyme process, or combinations thereof.

7. The process of claim 1, wherein the removing hexose from the feedstock comprises crushing, milling, or diffusion.

8. The process of claim 1, wherein the converting the hexose to the butanol comprises butanol fermentation.

9. The process of claim 1, further comprising consuming the residue to produce energy comprising:

burning the residue in a fired heater or a boiler unit; and

generating steam.

10. The process of claim 1, wherein the lignocellulosic material comprises bagasse, rice straw, corn stover, miscanthus, switchgrass, wheat straw, wood, wood waste, paper, paper waste, agricultural waste, municipal waste, or combinations thereof.

11. The process of claim 1, wherein the residue comprises cellulose or lignin.

12. The process of claim 1, wherein the biodiesel material comprises polyunsaturated fatty acids, esters, triglycerides, alkanes, or combinations thereof.

13. The process of claim 1, wherein:

the hexose comprises glucose, sucrose, or fructose; and

the pentose comprises xylose.

14. The process of claim 1, further comprising:

reacting the biodiesel material with an alcohol-based material to form a biodiesel product and glycerin; and

optionally converting the glycerin to additional biodiesel material.

15. The process of claim 14, wherein the alcohol-based material comprises ethanol or methanol.

16. The process of claim 14, wherein the alcohol-based material comprises the butanol derived from converting hexose.

17. One or more biofuels made by the process of claim 1.

18. An integrated process of coproducing butanol and biodiesel, the process comprising:

removing hexose from sugarcane to form a lignocellulosic material;

converting the hexose to butanol;

depolymerizing the lignocellulosic material to form pentose and a residue;

converting the pentose to a biodiesel material;

consuming the residue to produce energy;

reacting the biodiesel material with methanol to form a biodiesel product and glycerin; and

converting the glycerin to additional biodiesel material;

wherein the process produces a mass ratio of biodiesel to butanol of at least about 0.2 kilotons of biodiesel to 1.0 kiloton of butanol.

19. An integrated butanol and biodiesel plant, the plant comprising:

a hexose removal unit adapted for removing hexose from a feedstock to form a lignocellulosic material;

a hexose conversion unit adapted for converting hexose to butanol;

a pentose depolymerization unit adapted for removing pentose from the lignocellulosic material to form a residue; and

a pentose conversion unit adapted for converting pentose to a biodiesel material.

20. The plant of claim 19, further comprising:

an esterification unit adapted to react the biodiesel material with an alcohol-based material to form a biodiesel product and glycerin; and

a line adapted for supplying the glycerin to the pentose conversion unit.

21. The plant of claim 19, wherein the pentose depolymerization unit uses an acidic process, a basic process, an enzymatic process, a solvent process, or combinations thereof.

22. The plant of claim 19, wherein the pentose conversion unit uses a microorganism.

23. The plant of claim 19, wherein the pentose conversion unit uses an algae process, a bacterial process, a fungal process, a free enzyme process, or combinations thereof.

24. The plant of claim 19, further comprising a mass ratio of biodiesel to butanol of at least about 0.2 kilotons of biodiesel to 1.0 kiloton of butanol.

25. An integrated process of coproducing biofuels, the process comprising:

removing hexose from a feedstock and to form a lignocellulosic material;

converting the hexose to butanol or a biodiesel material;

depolymerizing the lignocellulosic material to form pentose and a residue; and

converting the pentose to butanol or a biodiesel material.