Surface covering which is hardened in several stages

• US 8,153,264 B2
• Filed: 04/07/2006
• Issued: 04/10/2012
• Est. Priority Date: 04/08/2005
• Status: Active Grant

• Current Assignee: Kleiberit SE & Company KG
• Original Assignee: Klebchemie MG Becker GmbH & Co. KG
• Inventors: Ehrmann, Elke, Fandrey, Jens, Becker-Weimann, Klaus, Fahrländer, Michael
• Primary Examiner(s): Tran, Thao T.
• Application Number:
  US11/918,074
• Publication Number:
  US 20090022984A1
• Time in Patent Office: 2,195 Days
• Field of Search: 428/425.1, 428/425.8, 428/457, 428/423.1, 427/487
• US Class Current: 428/425.1
• CPC Class Codes: B05D 3/0209 Multistage baking
• CPC Class Codes: B05D 3/067 Curing or cross-linking the coating
• CPC Class Codes: B05D 3/108 Curing
• CPC Class Codes: B05D 7/08 using synthetic lacquers or varnishes
• CPC Class Codes: C08G 18/48 Polyethers
• CPC Class Codes: C08G 18/672 Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
• CPC Class Codes: C09D 175/16 having terminal carbon-to-carbon unsaturated bonds
• CPC Class Codes: Y10T 428/269 including synthetic resin or polymer layer or component
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31591 Next to cellulosic
• CPC Class Codes: Y10T 428/31605 Next to free metal
• CPC Class Codes: Y10T 428/31678 Of metal

Abstract

The invention relates to a method of sealing at least part of the surface of an article, comprising the steps of

• • (a) applying a layer of a radiation-curable melt based on a moisture-crosslinking polyurethane to at least part of the surface of the article, and
  • (b) irradiating the melt layer.

The invention further relates to article surfaces sealed in this way, and also to the use of the abovementioned melt for surface sealing.

Claims

1. Method of sealing at least part of the surface of an article, comprising the steps of:

first, providing an article comprising a laminated or wood-block flooring element, a paneling element, a veneer, a furniture element, a piece of furniture, or a metal sheet, then

sealing at least part of an outer face surface of the article by

(a) applying a layer of a radiation-curable melt based on a moisture-crosslinking polyurethane to said at least part of the outer face surface of the article, and

(b) irradiating the melt layer.

2. Method according to claim 1, wherein the layer is applied using a roll, a doctor blade or a slot die or by spraying.

3. Method according to claim 1, wherein the surface of the melt layer is smoothed.

4. Method according to claim 1, wherein the melt layer is applied at a thickness in the range from 5 μ

m to 200 μ

m.

5. Method according to claim 1, wherein the melt layer is applied in a single ply.

6. Method according to claim 1, wherein the melt prior to curing contains not only at least one irradiation-polymerizable functional group but also NCO groups.

7. Method according to claim 1, wherein the melt prior to curing comprises acrylic acid derivatives, methacrylic acid derivatives or styrene derivatives.

8. Method according to claim 1, wherein the irradiation takes place prior to full curing of the melt layer through the moisture crosslinking of the polyurethane.

9. Method according to claim 1, wherein the irradiation takes place within 24 hours following application of the melt layer.

10. Method according to claim 1, wherein the melt prior to curing comprises:

one or more polyisocyanates containing an average of two up to about four isocyanate groups;

at least one polyol selected from the group consisting of polyesters, polyethers, polycarbonates, polyacetals, and mixtures of two or more thereof having a molecular weight of at least about 200 and having terminal hydroxyl groups; and

an irradiation-polymerizable component selected from the group consisting of derivatives of acrylic acid, methacrylic acid, crotonic acid and maleic acid, wherein the derivative contains an isocyanate-reactive group selected from the group consisting of hydroxyl, amino and mercapto groups;

methyl (meth)acrylate;

styrene;

phenoxyethyl acrylate;

polyester acrylates;

polyether acrylates; and

epoxy acrylates.

11. Method according to claim 10, wherein the article that is to be sealed is composed at least partly of wood or a wood-like material and is a laminated or wood-block flooring element, a paneling element or a veneer, a furniture element or piece of furniture, and

wherein at least 75% of an outer surface of the article is sealed to form an outer coated surface that is entirely exposed, and wherein the article is a laminated or wood-block flooring element, a paneling element or a veneer, a furniture element, piece of furniture, or a metal sheet.

12. Article having a sealing layer on at least part of its surface, comprising a layer of a radiation-curable melt based on a moisture-crosslinking polyurethane, wherein at least part of its surface is one outer face of the article and wherein the article is a laminated or wood-block flooring element, a paneling element or a veneer, a furniture element or a piece of furniture, or a metal sheet.

13. Article according to claim 12, wherein the melt layer has a thickness in the range from 5 μ

m to 200 μ

m.

14. Article according to claim 12, wherein the melt layer has been applied in a single ply.

15. Article according to claim 12, wherein the melt prior to curing contains not only at least one irradiation-polymerisable functional group but also NCO groups.

16. Article according to claim 12, wherein the melt prior to curing comprises acrylic acid derivatives, methacrylic acid derivatives or styrene derivatives.

17. Article according to claim 12, wherein the radiation curing of the melt layer has taken place prior to full curing of the reactive melt through the moisture crosslinking of the polyurethane.