Continuously cracking technology of waste rubber or plastics and its equipment

• US 8,168,839 B2
• Filed: 06/12/2006
• Issued: 05/01/2012
• Est. Priority Date: 04/07/2006
• Status: Active Grant

• Current Assignee: Niutech Environment Technology Corporation (Niutech Energy Ltd.)
• Original Assignee: Bin Niu
• Inventors: Niu, Bin
• Primary Examiner(s): Bhat, Nina
• Application Number:
  US12/296,181
• Publication Number:
  US 20100121121A1
• Time in Patent Office: 2,150 Days
• Field of Search: 585/241, 201/2.5, 201/25, 202/84, 202/89, 202/117, 202/118
• US Class Current: 585/241
• CPC Class Codes: B29B 17/04 Disintegrating plastics, e.g. by millingB29B9/02, B29B11/02, B29B13/10, B29B17/02 take precedence
• CPC Class Codes: B29B 2017/0496 Pyrolysing the materials
• CPC Class Codes: C10B 47/30 in rotary ovens or retorts
• CPC Class Codes: C10B 53/07 of solid raw materials consisting of synthetic polymeric materials, e.g. tyres waste in general, e.g. household waste C10B53/00; recovery or working-up of waste materials of organic macromolecular compounds or compositions based thereon by dry-heat treatment for obtaining partially depolymerised materials C08J11/10; production of liquid hydrocarbon mixtures from rubber or rubber waste C10G1/10
• CPC Class Codes: C10G 1/10 from rubber or rubber waste
• CPC Class Codes: C10G 2300/1003 Waste materials
• CPC Class Codes: Y02P 20/143 the feedstock being recycled material, e.g. plastics
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling

Abstract

Certain examples relate to methods of continuously cracking waste rubber or plastics and apparatuses related to the same, to produce oil from waste rubber or plastics. Raw materials comprising a catalyst and rubber or plastics may be extruded in order to separate the air or to prevent oxidization. The raw materials are transported into the cracking chamber, and moved from the inlet to the discharge hole. After the cracking process is finished, the products are discharged automatically through the discharge hole. The separation of air and oxygen in the inlet and discharge hole of the cracking chamber can avoid dangers caused by oxygen entering the cracking chamber, and realize industrial production with continuous feedings. The ratio of the oil can be raised from 19% to 45%-48%, and the loss of production equipment reduced. Production costs are reduced, safety measurements improved, and continuous production is realized.

Claims

1. A method of continuously cracking waste rubber and/or plastics, comprising:

at least partially extruding raw materials comprising waste rubber and/or plastics, with a catalyst, via an air-separating and/or oxidization-preventing material feeding unit comprising an extrusion unit and a feeding pipe connected to a cracking chamber, the extrusion unit further comprising a screw conveyor unit having a variable pitch and causing extrusion while propelling, wherein the screw conveyor unit includes a screw located in the feeding pipe, and the screw does not extend as deeply into a cracking chamber as does an end of the feeding pipe, such that there is a cavity formed by space between the end of the feeding pipe and an end of the screw;

transporting the at least partially extruded raw materials into the cracking chamber via the material feeding unit, wherein the screw conveyor unit and the cavity operate to reduce an amount of air and/or oxygen reaching an interior of the cracking chamber;

causing said raw materials to be moved from an inlet orifice of the cracking chamber to a discharge hole, during which cracking is performed; and

discharging the products through the discharge hole.

2. The method of claim 1, wherein the raw materials are heated after or simultaneously with the air separation and/or oxidization prevention.

3. The method of claim 2, wherein the heating of raw materials is achieved by heat radiation and/or heat conduction from the temperature within the cracking chamber when the raw materials are transported into said cracking chamber.

4. The method of claim 1, wherein the cracking chamber is hermetically sealed, and late stages of extrusion to separate air and/or prevent oxidization are carried out in the hermetically sealed cracking chamber.

5. The method of claim 4, wherein the discharge hole of the hermetically sealed cracking chamber is connected to a discharge pipe having an inlet end and an exit end, wherein the discharge pipe comprises a spiral propulsive unit, and wherein the exit end of the discharge pipe is at a higher elevation than the inlet end.

6. The method of claim 4, wherein the hermetically sealed cracking chamber comprises a hermetical revolving drum, wherein an angle of inclination of the hermetical revolving drum is greater than 0°

but less than or equal to 10°

with respect to a horizontal axis, such that the inlet orifice located at a first end of the revolving drum is set at a higher elevation than the solid discharge hole located at a second end of the revolving drum.

7. The method of claim 1, wherein the cracking chamber is heated by use of first and second of pipelines, located on opposite sides of the cracking chamber, wherein the first pipeline transfers heat from the discharge hole to the inlet orifice, and the second pipeline transfers heat from the inlet orifice to the discharge hole.

8. The method of claim 7, wherein at least one of the first or second pipelines comprises internal heating pipes that are installed and run proximate an inner portion of the cracking chamber.

9. The method of claim 1, wherein an exterior of the cracking chamber is covered by a thermal insulation unit and/or an external heating unit.

10. The method of claim 1, wherein a cracking temperature ranges from 350°

C. to 550°

C., and an average retention time of the raw materials in the cracking chamber is from 20 to 60 minutes.

18. The method of claim 1, wherein the catalyst is added to the raw materials via a catalyst import before the raw materials are transported into the cracking chamber.

11. An apparatus for continuously cracking waste rubber and/or plastics, the apparatus comprising:

a hermetically sealed cracking chamber with an inlet orifice and a discharge hole;

an air-separating and/or oxidization-preventing material feeding unit connected to the inlet orifice of the cracking chamber to transport raw materials comprising rubber and/or plastics into the cracking chamber, the material feeding unit comprising a feeding pipe, wherein an end of the feeding pipe is positioned in the cracking chamber, the material feeding unit also comprising an extrusion unit comprising a screw conveyor unit having a variable pitch to at least partially extrude the raw materials, wherein the screw conveyor unit includes a screw located in the feeding pipe, and the screw does not extend as deeply into the cracking chamber as does the feeding pipe such that there is a cavity formed by space between the end of the feeding pipe and an end of the screw; and

a transporting unit in the cracking chamber to transport the at least partially extruded raw materials from the inlet orifice to the discharge hole while cracking occurs, wherein the discharge hole is isolated from the outside air.

12. The apparatus of claim 11, wherein the discharge hole of the hermetically sealed cracking chamber is connected to a discharge pipe having an exit end and an inlet end, wherein the discharge pipe comprises a spiral propulsive unit, and wherein the exit end of the discharge pipe is at a higher elevation than the inlet end.

13. The method of claim 12, wherein the spiral propulsive unit comprises a working part with screw blades, and wherein there is a cavity formed by space between an end of the working part with screw blades in the spiral propulsive unit and a back-end of the discharge pipe.

14. The apparatus of claim 11, wherein the hermetically sealed cracking chamber comprises a revolving drum with a sealed heating unit, wherein an angle between the revolving drum and a horizontal axis is greater than 0°

but less than or equal to 10°

;

wherein first and second ends of the revolving drum are linked through the sealed heating unit to first and second end covers fixed at the supporting frame; and

the inlet orifice of the hermetically sealed cracking chamber is located at an upper portion of the first end cover and the discharge hole of the hermetically sealed cracking chamber is located at a lower portion of the second end cover.

15. The apparatus of claim 14, wherein the sealed heating unit in the hermetically sealed cracking chamber includes internal heating pipes each comprising first and second ends, wherein the first and second ends of the heating pipes are installed at the first and second end covers respectively and run through a cavity of the cracking chamber.

16. The apparatus of claim 14, wherein an exterior of the revolving drum is equipped with an external heating unit with thermal insulation.

17. The apparatus of claim 16, wherein said external heating unit comprises an outer cylinder with thermal insulation covering the revolving drum;

and between the revolving drum and the outer cylinder, a thermal medium cavity is formed;

a liquid inlet of the cavity and a liquid outlet of internal heating pipes are located at a first end of the cracking chamber; and

a liquid outlet of the cavity and a liquid inlet of the internal heating pipes are located at a second end of the cracking chamber.

19. An apparatus for continuously cracking waste rubber and/or plastics, the apparatus comprising:

a hermetically sealed cracking chamber with an inlet orifice and a discharge hole;

a material feeding unit connected to the inlet orifice of the cracking chamber to transport raw materials comprising rubber and/or plastics into the cracking chamber, the material feeding unit comprising at least a feeding pipe and a screw;

wherein the screw is located at least partially in the feeding pipe, and has a variable pitch; and

wherein an end of the feeding pipe is positioned at a first distance into the cracking chamber, and an end of the screw is positioned at a second distance into the cracking chamber, the first distance is greater than the second distance such that there is a cavity formed by space between the end of the feeding pipe and the end of the screw, and the variable pitch and the cavity operate to reduce an amount of air and/or oxygen reaching an interior of the cracking chamber; and

a transporting unit in the cracking chamber to transport the at least partially extruded raw materials from the inlet orifice to the discharge hole while cracking occurs, wherein the discharge hole is isolated from the outside air.