Process for regenerating a spent sorbent
First Claim
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1. A method of regenerating a used activated carbon sorbent comprising:
- creating an activated carbon sorbent mixture containing used regenerated activated carbon sorbent and unused activated carbon sorbent;
exposing the activated carbon sorbent mixture to a solution to remove contaminants collected on at least the used activated carbon sorbent to restore mercury sorption effectiveness to the used activated carbon sorbent, the solution including a salt containing an associated cation;
dewatering the activated carbon sorbent mixture to remove used activated carbon sorbent and at least some contaminants from the solution forming used regenerated activated carbon sorbent and a liquid;
drying the dewatered regenerated activated carbon sorbent from the used regenerated activated carbon sorbent mixture;
treating at least some of the liquid to remove at least some compounds therefrom; and
mixing at least some of the liquid with at least one of used regenerated activated carbon sorbent and unused activated carbon sorbent.
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Abstract
A method and apparatus is provided for regenerating a sorbent that has been poisoned by components derived from flue gas. The sorbent is treated with an agent to remove the poisoning components and introduce a promoting agent into the sorbent. The method and apparatus can also be used to enhance the effectiveness of a new sorbent.
47 Citations
32 Claims
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1. A method of regenerating a used activated carbon sorbent comprising:
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creating an activated carbon sorbent mixture containing used regenerated activated carbon sorbent and unused activated carbon sorbent; exposing the activated carbon sorbent mixture to a solution to remove contaminants collected on at least the used activated carbon sorbent to restore mercury sorption effectiveness to the used activated carbon sorbent, the solution including a salt containing an associated cation; dewatering the activated carbon sorbent mixture to remove used activated carbon sorbent and at least some contaminants from the solution forming used regenerated activated carbon sorbent and a liquid; drying the dewatered regenerated activated carbon sorbent from the used regenerated activated carbon sorbent mixture; treating at least some of the liquid to remove at least some compounds therefrom; and mixing at least some of the liquid with at least one of used regenerated activated carbon sorbent and unused activated carbon sorbent. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13)
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14. A method of regenerating a used activated carbon sorbent comprising:
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exposing the used activated carbon sorbent to a solution to remove contaminants collected on the used activated carbon sorbent to restore mercury sorption effectiveness to the used activated carbon sorbent; dewatering the used activated carbon sorbent to remove used activated carbon sorbent and contaminants from the solution forming a liquid having contaminants; adding a promoter comprising at least one of bromine, a bromine compound, and combinations thereof to the activated carbon sorbent; drying the dewatered used activated carbon sorbent forming a regenerated used activated carbon sorbent; and treating at least some of the liquid to remove at least some contaminants therefrom.
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15. A method of regenerating a used sorbent and enhancing unused sorbent comprising:
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creating an activated carbon sorbent mixture containing used activated carbon sorbent and unused activated carbon sorbent, the activated carbon sorbent and unused carbon sorbent comprising at least one composition of granulated form and fibrous form; regenerating the used activated carbon sorbent by exposing the activated carbon sorbent mixture to a solution to remove contaminants collected on the used activated carbon sorbent to restore mercury sorption effectiveness to the activated carbon sorbent, the solution including a compound made up of at least one of bromine, bromine compounds, and combinations thereof for low-ash and fiber sorbent regeneration; and exposing the regenerated used activated carbon sorbent to a flue gas stream. - View Dependent Claims (16, 17, 18, 19)
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20. A method of enhancing the effectiveness of an activated carbon sorbent for capturing mercury comprising:
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exposing the activated carbon sorbent to at least one of bromine, bromine compounds, and combinations thereof; and modifying the carbon edge structure of the activated carbon sorbent to form carbocations so that the activated carbon sorbent accepts electrons from neutral mercury atoms of the mercury. - View Dependent Claims (21, 22)
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23. A method of enhancing the effectiveness of an activated carbon sorbent by modifying the structure of the activated carbon sorbent in a mixture of ash and activated carbon sorbent comprising:
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enhancing the activated carbon sorbent by exposing the activated carbon sorbent in a mixture of ash and activated carbon sorbent to one of an aqueous solution and a nonaqueous solution that increases sorbent effectiveness, the solution including one or more of bromine, bromine compounds, and combinations thereof, for the mixture of ash and activated carbon sorbent for the regeneration thereof; and exposing the regenerated enhanced activated carbon sorbent to a flue gas stream. - View Dependent Claims (24, 25, 26, 27, 28, 29)
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30. A method of removing mercury or other pollutants in a flue gas stream during the burning of fossil fuels, comprising:
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exposing an activated carbon sorbent mixture to the flue gas stream to remove at least mercury as a contaminant from the flue gas stream forming a used activated carbon sorbent; mixing the used activated carbon sorbent with fresh activated carbon sorbent and exposing the mixture of used activated carbon sorbent and fresh activated carbon sorbent to a solution including bromine, bromine compounds, and combinations thereof to remove contaminants collected on the used activated carbon sorbent to restore mercury sorption effectiveness to the used activated carbon sorbent and enhance sorption effectiveness of the fresh active carbon sorbent, the solution including an associated cation, such as ammonium, aluminum, boron, zinc, and iron; dewatering the solution to remove used activated carbon sorbent and any fresh activated carbon sorbent and contaminants from the solution; drying the used activated carbon and unused activated carbon sorbent particles; and exposing the dried used activated carbon sorbent and the fresh activated carbon sorbent to the flue gas stream to remove additional contaminants from the flue gas stream. - View Dependent Claims (31, 32)
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Specification