Detergent composition

• US 8,173,587 B2
• Filed: 08/03/2007
• Issued: 05/08/2012
• Est. Priority Date: 08/04/2006
• Status: Active Grant

• Current Assignee: Reckitt Benckiser Finish B.V. (Reckitt Benckiser Group PLC)
• Original Assignee: Reckitt Benckiser N.V. (Reckitt Benckiser Group PLC)
• Inventors: Preuschen, Judith
• Primary Examiner(s): DELCOTTO, GREGORY R
• Application Number:
  US12/375,771
• Publication Number:
  US 20090325840A1
• Time in Patent Office: 1,740 Days
• Field of Search: 510/238, 510/372, 510/375, 510/378, 510/499, 510/505, 510/220, 510/221, 510/224, 252/186.27, 252/186.43, 134/25.2
• US Class Current: 510/224
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 3/122 Sulfur-containing, e.g. sulfates, sulfites or gypsum
• CPC Class Codes: C11D 3/2075 Carboxylic acids-salts thereof
• CPC Class Codes: C11D 3/3917 Nitrogen-containing compounds

Abstract

A hard surface detergent composition is provided, said composition comprising a peroxygen bleach capable of exhibiting bleaching properties at a pH of below 9, and an amino ketone or derivative thereof bleach activator, and wherein a 1% wt solution in distilled water at 25° C. of the composition has a pH lower than 9. Potassium monopersulphate is the preferred bleach compound and diethyl amino acetone or derivative thereof is the preferred bleach activator. The compositions exhibit good bleaching performance at pHs of less than 9.

Claims

1. A method of bleaching dishware within an automatic dishwasher comprising contacting said dishware with an automatic dishwasher detergent composition comprising an amino ketone or derivative thereof bleach activator, a source of multivalent ions, and a peroxygen bleach.

2. A method according to claim 1, wherein the peroxygen bleach is capable of exhibiting bleaching properties at a pH in the range of from 6.5 to 8.5.

3. A method according to claim 1, wherein the peroxygen bleach is a persulphate bleach.

4. A method according to claim 3, wherein the persulphate bleach is a sodium or potassium salt of the persulphate bleach.

5. A method according to claim 4, wherein the persulphate bleach is potassium monopersulphate.

6. A method according to claim 1, wherein the composition comprises the amino ketone or derivative thereof bleach activator in an amount of from 0.01 to 10 wt %.

7. A method according to claim 1, wherein the amino ketone or derivative thereof bleach activator is a dialkyl-amino acetone.

8. A composition method according to claim 7 wherein the dialkyl-amino acetone has two different C₁-C₅ alkyl chains.

9. A composition method according to claim 8, wherein the dialkyl-amino acetone is diethyl amino acetone.

10. A composition method according to claim 1 wherein the amino ketone derivative is a hydrochloride salt.

11. A composition method according to claim 1, wherein the multivalent cation is selected from the group consisting of zinc, bismuth or manganese.

12. A composition method according to claim 1, wherein the source of multivalent cations is chosen from the group consisting of compounds of sulphates, carbonates, acetates, gluconates and metal-protein compounds.

13. A composition method according to claim 1, wherein the detergent composition has a pH in the range of from 6.5 to 8.5 as a 1% wt solution in demineralised water at 25°

C.

14. A composition method according to claim 1, where the detergent composition has a pH in the range of from 6.8 to 8.2 as a 1% wt solution in demineralised water at 25°

C.