Quantum dot white and colored light-emitting devices

• US 8,174,181 B2
• Filed: 08/11/2011
• Issued: 05/08/2012
• Est. Priority Date: 04/01/1998
• Status: Expired due to Fees

• Current Assignee: Philips Lumileds Lighting Company LLC (Apollo Global Management, Inc.), Massachusetts Institute of Technology
• Original Assignee: Philips Lumileds Lighting Company LLC (Apollo Global Management, Inc.), Massachusetts Institute of Technology
• Inventors: Bawendi, Moungi G., Heine, Jason, Jensen, Klavs F., Miller, Jeffrey N., Moon, Ronald L.
• Primary Examiner(s): HINES, ANNE M
• Application Number:
  US13/208,169
• Publication Number:
  US 20120012877A1
• Time in Patent Office: 271 Days
• Field of Search: 313498-512, 445/24, 445/22
• US Class Current: 313/503
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: C09K 11/02 Use of particular materials as binders, particle coatings or suspension media therefor
• CPC Class Codes: C09K 11/565 with zinc cadmium
• CPC Class Codes: C09K 11/883 with zinc or cadmium
• CPC Class Codes: H01L 33/06 within the light emitting region, e.g. quantum confinement structure or tunnel barrier
• CPC Class Codes: H01L 33/502 Wavelength conversion materials
• CPC Class Codes: H01L 33/504 Elements with two or more wavelength conversion materials
• CPC Class Codes: H01S 3/169 Nanoparticles, e.g. doped nanoparticles acting as a gain material
• CPC Class Codes: Y02B 20/00 Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
• CPC Class Codes: Y10S 977/95 Electromagnetic energy

Abstract

A light-emitting device comprising a population of quantum dots (QDs) embedded in a host matrix and a primary light source which causes the QDs to emit secondary light and a method of making such a device. The size distribution of the QDs is chosen to allow light of a particular color to be emitted therefrom. The light emitted from the device may be of either a pure (monochromatic) color, or a mixed (polychromatic) color, and may consist solely of light emitted from the QDs themselves, or of a mixture of light emitted from the QDs and light emitted from the primary source. The QDs desirably are composed of an undoped semiconductor such as CdSe, and may optionally be overcoated to increase photoluminescence.

Claims

1. A light emitting device comprising:

a primary light source; and

at least one layer in optical communication with the primary light source, wherein the at least one layer comprises a matrix including a plurality of quantum dots having a polydisperse size distribution and adapted to convert primary light emitted by the primary light source to secondary light, wherein the secondary light comprises a mixed color of light or white light.

2. The light emitting device of claim 1, wherein the at least one layer is physically separated from the primary light source.

3. The light emitting device of claim 2, further comprising a medium interposed between the at least one layer and the primary light source.

4. The light emitting device of claim 3, wherein the medium is transparent or translucent to at least a portion of light emitted by the primary light source.

5. The light emitting device of claim 3, wherein the medium comprises air, a vacuum, a polymer, a glass, or a liquid.

6. The light emitting device of claim 5, wherein the medium comprises a glass.

7. The light emitting device of claim 1 or 3, further comprising an overcoating layer disposed over the at least one layer comprising the matrix and the plurality of quantum dots.

8. The light emitting device of claim 5, wherein the medium comprises a polymer.

9. The light emitting device of claim 2, wherein the plurality of quantum dots comprises:

a first population of quantum dots adapted to convert at least a portion of the primary light to green secondary light; and

a second population of quantum dots adapted to convert at least a portion of the primary light to red secondary light.

10. The light emitting device of claim 9, wherein the at least one layer comprises at least a first layer comprising a mixture of the first population of quantum dots and the second population of quantum dots.

11. The light emitting device of claim 9, wherein the at least one layer comprises:

a first layer comprising the first population of quantum dots; and

a second layer comprising the second population of quantum dots.

12. The light emitting device of claim 10 or 11, wherein the primary light source emits blue primary light, and the device emits white light comprising a mixture of the blue primary light emitted by the primary light source, the green secondary light emitted by the first population of quantum dots, and the red secondary light emitted by the second population of quantum dots.

13. The light emitting device of claim 2, wherein the plurality of quantum dots comprises:

a first population of quantum dots; and

at least a second population of quantum dots;

wherein the quantum dots of the first population have a different size, size distribution, and/or composition than the quantum dots of the second population.

14. The light emitting device of claim 13, wherein the at least one layer comprises:

a first layer comprising the first population of quantum dots; and

a second layer comprising the second population of quantum dots.

15. The light emitting device of claim 13, wherein the first and second populations of quantum dots are disposed in the same layer.

16. The light emitting device of claim 2, wherein the matrix comprises a polystyrene.

17. The light emitting device of claim 2, wherein the matrix comprises an amine-terminated polystyrene.

18. The light emitting device of claim 2, wherein the matrix comprises a polyimide.

19. The light emitting device of claim 2, wherein the matrix comprises an epoxy.

20. The light emitting device of claim 7, wherein the overcoating layer comprises a polymer.

21. The light emitting device of claim 1, wherein the primary light source emits primary light having a first color, and the plurality of quantum dots having a polydisperse size distribution comprises:

a first population of quantum dots adapted to convert the primary light to secondary light having a second color which is different than the first color; and

a second population of quantum dots adapted to convert the primary light to secondary light having a third color which is different than the first color and the second color.

22. The light emitting device of claim 1, wherein the secondary light comprises a mixed color of light, and wherein the light emitting device emits white light comprising a mixture of the primary light and the secondary light.

23. The light emitting device of claim 1, wherein the at least one layer comprises at least one layer which does not contain quantum dots.

24. A method of producing light of a selected color, comprising:

providing a primary light source which emits primary light;

providing at least one layer comprising a matrix including a plurality of quantum dots having a polydisperse size distribution; and

disposing the at least one layer in optical communication with and physically separated from the primary light source, whereby the plurality of quantum dots are capable of converting primary light emitted by the primary light source to secondary light, wherein the secondary light comprises a mixed color of light or white light.

25. The method of claim 24, further comprising:

interposing a medium between the at least one layer and the primary light source.

26. The method of claim 25, wherein the medium comprises air, a vacuum, a polymer, a glass, or a liquid.

27. The method of claim 25, wherein the medium comprises a glass.

28. The method of claim 25, wherein the medium comprises a polymer.

29. The method of claim 24, wherein the providing at least one layer comprises:

providing a first layer comprising a first population of quantum dots adapted to convert primary light emitted by the primary light source to green light;

providing a second layer comprising a second population of quantum dots adapted to convert primary light emitted by the primary light source to red light.

30. The method of claim 24, further comprising:

adjusting the thickness of the at least one layer and the density of quantum dots in the at least one layer to control the color of light emitted from the at least one layer.

31. The method of claim 24, wherein the providing at least one layer comprises:

providing a first population of quantum dots capable of converting the primary light to green secondary light and a second population of quantum dots capable of converting the primary light to red secondary light; and

mixing a selected proportion of the first and second populations of quantum dots to control the color of light emitted from the at least one layer.

32. The method of claim 24, further comprising:

providing an overcoating layer over the at least one layer comprising the matrix and the plurality of quantum dots.