High-tensile steel plate, welded steel pipe or tube, and methods of manufacturing thereof

• US 8,177,925 B2
• Filed: 03/08/2006
• Issued: 05/15/2012
• Est. Priority Date: 03/17/2005
• Status: Active Grant

• Current Assignee: Nippon Steel Corporation
• Original Assignee: Sumitomo Metal Industries Limited (Nippon Steel Corporation)
• Inventors: Takahashi, Nobuaki, Yamanaka, Akihiro, Hamada, Masahiko, Okaguchi, Shuji, Seta, Ichirou
• Primary Examiner(s): Yee, Deborah
• Application Number:
  US11/886,423
• Publication Number:
  US 20090297872A1
• Time in Patent Office: 2,260 Days
• Field of Search: 148/320, 148330-336, 148/908, 148/541, 148/547, 148/593, 148/654, 164/467, 164/468, 164/499
• US Class Current: 148/336
• CPC Class Codes: B21B 3/02 Rolling special iron alloys , e.g. stainless steel
• CPC Class Codes: B21C 37/08 Making tubes with welded or soldered seams with helically arranged seams B21C37/122
• CPC Class Codes: C21D 2211/002 Bainite
• CPC Class Codes: C21D 2211/005 Ferrite
• CPC Class Codes: C21D 8/0226 Hot rolling
• CPC Class Codes: C21D 8/10 during manufacturing of tubular bodies
• CPC Class Codes: C21D 9/08 for tubular bodies or pipes
• CPC Class Codes: C21D 9/50 for welded joints
• CPC Class Codes: C22C 38/002 containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
• CPC Class Codes: C22C 38/005 containing rare earths, i.e. Sc, Y, Lanthanides
• CPC Class Codes: C22C 38/02 containing silicon
• CPC Class Codes: C22C 38/04 containing manganese
• CPC Class Codes: C22C 38/08 containing nickel C22C38/105 takes precedence
• CPC Class Codes: C22C 38/12 containing tungsten, tantalum, molybdenum, vanadium, or niobium
• CPC Class Codes: C22C 38/14 containing titanium or zirconium
• CPC Class Codes: C22C 38/40 with nickel
• CPC Class Codes: C22C 38/42 with copper
• CPC Class Codes: C22C 38/44 with molybdenum or tungsten
• CPC Class Codes: C22C 38/46 with vanadium
• CPC Class Codes: C22C 38/50 with titanium or zirconium
• CPC Class Codes: C22C 38/58 : with more than 1.5% by weight of manganese
• CPC Class Codes: Y10S 148/908 : Spring
• CPC Class Codes: Y10T 428/12292 : Workpiece with longitudinal passageway or stopweld material [e.g., for tubular stock, etc.]

Abstract

In a high-tensile steel plate according to the invention, the carbon equivalent Pcm represented in Expression (1) is from 0.180% to 0.220%, the surface hardness is a Vicker'"'"'s hardness of 285 or less, the ratio of a Martensite Austenite constituent in the surface layer is not more than 10%, the ratio of a mixed structure of ferrite and bainite inside beyond the surface layer is not less than 90%, the ratio of the bainite in the mixed structure is not less than 10%, the thickness of the lath of bainite is not more than 1 μm, the length of the lath is not more than 20 μm, and the segregation ratio as the ratio of the Mn concentration in the center segregation part relative to the Mn concentration at a part in a depth equal to ¼ of the thickness of the plate from the surface is not more than 1.3. Pcm=C+Si/30+(Mn+Cu+Cr)/20+Ni/60+Mo/15+V/10+5B . . . (1) where the element symbols in Expression (1) represent the % by mass of the respective elements. In this way, the high-tensile steel plate according to the invention has a yield strength of at least 551 MPa and a tensile strength of at least 620 MPa as well as high toughness, high propagating shear fracture and high weldability.

Claims

1. A high-tensile steel plate comprising 0.02% to 0. 1% C, at most 0.6% Si, 1.6% to 2.5% Mn, 0.1% to 0.7% Ni, 0.01% to 0.1% Nb, 0.005% to 0.03% Ti, at most 0.1% sol. Al, 0.001% to 0.006% N, 0% to 0.0025% B, 0% to 0.6% Cu, 0% to 0.8% Cr, 0% to 0.6% Mo, 0% to 0.1% V, 0% to 0.006% Ca, 0% to 0.006% Mg, 0% to 0.03% a rare earth element, at most 0.015% P, and at most 0.003% S, the balance consisting of Fe and impurities, said high-tensile steel plate having:

a carbon equivalent Pcm in Expression (1) in the range from 0.180% to 0.220%;

a surface hardness of at most Vickers hardness of 285;

a ratio of a martensite austenite constituent in the surface layer of at most 10%;

a ratio of a mixed structure of ferrite and bainite on the inner side beyond the surface layer of at least 90%;

a ratio of the bainite in the mixed structure of at least 10%, a lath of the bainite having a thickness of at most 1 μ

m and a length of at most 20 μ

m; and

a segregation ratio as the ratio of the Mn concentration of a center segregation part to the Mn concentration of a part in a depth equal to ¼

of the thickness of the plate from the surface of at most 1.3.

Pcm=C+Si/30+(Mn+Cu+Cr)/20+Ni/60+Mo/15+V/10+5B 

 

(1)

 

where the element symbols represent the % by mass of the respective elements.

2. A high-tensile steel plate comprising 0.02% to 0.1% C, at most 0.6% Si, 1.6% to 2.5% Mn, 0.1% to 0.7% Ni, 0.01% to 0.1% Nb, 0.005% to 0.03% Ti, at most 0.1% sol. Al, 0.001% to 0.006% N, 0% to 0.0025% B, 0% to 0.6% Cu, 0% to 0.8% Cr, 0% to 0.6% Mo, 0% to 0.1% V, 0% to 0.006% Ca, 0% to 0.006% Mg, 0% to 0.03% a rare earth element, at most 0.015% P, and at most 0.003% S, the balance consisting of Fe and impurities, said high-tensile steel plate having:

a carbon equivalent Pcm in Expression (1) in the range from 0.180% to 0.220%;

a surface hardness of at most Vickers hardness of 285;

a ratio of a martensite austenite constituent in the surface layer of at most 10%;

a ratio of a mixed structure of ferrite and bainite on the inner side beyond said surface layer of at least 90%;

a ratio of the bainite in the mixed structure of at least 10%, a length of the major axis of cementite precipitate grains in a lath of said bainite of at most 0.5 μ

m; and

a segregation ratio as the ratio of the Mn concentration of the center segregation part to a Mn concentration of a part in a depth equal to ¼

of the thickness of the plate from the surface of at most 1.3.

Pcm=C+Si/30+(Mn+Cu+Cr)/20+Ni/60+Mo/15+V/10+5B 

 

(1)

 

where the element symbols represent the % by mass of the respective elements.

3. The high-tensile steel plate according to claim 2, wherein a thickness of the lath is at most 1 μ

m and a length of the lath is at most 20 μ

m.

4. A welded steel pipe or tube produced using a high-tensile steel plate, said high-tensile steel plate comprising 0.02% to 0.1% C, at most 0.6% Si, 1.6% to 2.5% Mn, 0.1% to 0.7% Ni, 0.01% to 0.1% Nb, 0.005% to 0.03% Ti, at most 0.1% sol. Al, 0.001% to 0.006% N, 0% to 0.0025% B, 0% to 0.6% Cu, 0% to 0.8% Cr, 0% to 0.6% Mo, 0% to 0.1% V, 0% to 0.006% Ca, 0% to 0.006% Mg, 0% to 0.03% a rare earth element, at most 0.015% P, and at most 0.003% S, the balance consisting of Fe and impurities, said high-tensile steel plate having:

a carbon equivalent Pcm in Expression (1) in the range from 0.180% to 0.220%;

a surface hardness of at most Vickers hardness of 285;

a ratio of a martensite austenite constituent in the surface layer of at most 10%;

a ratio of a mixed structure of ferrite and bainite on the inner side beyond the surface layer of at least 90%;

a ratio of the bainite in the mixed structure of at least 10%, a lath of the bainite having a thickness of at most 1 μ

m and a length of at most 20 μ

m; and

a segregation ratio as the ratio of the Mn concentration of a center segregation part to the Mn concentration of a part in a depth equal to ¼

of the thickness of the plate from the surface of at most 1.3.

Pcm=C+Si/30+(Mn+Cu+Cr)/20+Ni/60+Mo/15+V/10+5B 

 

(1)

 

where the element symbols represent the % by mass of the respective elements.

5. A welded steel pipe or tube produced using a high-tensile steel plate, said high-tensile steel plate comprising 0.02% to 0.1% C, at most 0.6% Si, 1.6% to 2.5% Mn, 0.1% to 0.7% Ni, 0.01% to 0.1% Nb, 0.005% to 0.03% Ti, at most 0.1% sol. Al, 0.001% to 0.006% N, 0% to 0.0025% B, 0% to 0.6% Cu, 0% to 0.8% Cr, 0% to 0.6% Mo, 0% to 0.1% V, 0% to 0.006% Ca, 0% to 0.006% Mg, 0% to 0.03% a rare earth element, at most 0.015% P, and at most 0. 003% S, the balance consisting of Fe and impurities, said high-tensile steel plate having:

a carbon equivalent Pcm in Expression (1) in the range from 0.180% to 0.220%;

a surface hardness of at most Vickers hardness of 285;

a ratio of a martensite austenite constituent in the surface layer of at most 10%;

a ratio of a mixed structure of ferrite and bainite on the inner side beyond said surface layer of at least 90%;

a ratio of the bainite in the mixed structure of at least 10%, a length of the major axis of cementite precipitate grains in a lath of said bainite of at most 0.5 μ

m; and

a segregation ratio as the ratio of the Mn concentration of the center segregation part to a Mn concentration of a part in a depth equal to ¼

of the thickness of the plate from the surface of at most 1.3.

Pcm=C+Si/30+(Mn+Cu+Cr)/20+Ni/60+Mo/15+V/10+5B 

 

(1)

 

where the element symbols represent the % by mass of the respective elements.

6. The welded steel pipe or tube according to claim 5, wherein a thickness of the lath is at most 1 μ

m and a length of the lath is at most 20 μ

m.

7. A method of manufacturing a high-tensile steel plate, comprising the steps of:

continuously casting molten steel into a slab, said molten steel comprising;

0. 02% to 0.1% C, at most 0.6% Si, 1.6% to 2.5% Mn, 0.1% to 0.7% Ni, 0.01% to 0.1% Nb, 0.005% to 0.03% Ti, at most 0.1% sol. Al, 0.001% to 0.006% N, 0% to 0.0025% B, 0% to 0.6% Cu, 0% to 0.8% Cr, 0% to 0.6% Mo, 0% to 0.1% V, 0% to 0.006% Ca, 0% to 0.006% Mg, 0% to 0.03% a rare earth element, at most 0.015% P, and at most 0.003% S, the balance consisting of Fe and impurities, said molten steel having a carbon equivalent Pcm in Expression (1) in the range from 0.180% to 0.220%; and

rolling said slab into said high-tensile steel plate,

said step of casting including the steps of;

injecting said molten steel into a cooled cast and forming said slab having a solidified shell on the surface and unsolidified molten steel inside,

drawing said slab downwardly from said cast;

reducing said slab by at least 30 mm in the thickness-wise direction in a position upstream of the final solidifying position of said slab where the center solid phase ratio of said slab is more than 0 and less than 0.2; and

carrying out electromagnetic stirring to said slab so that said unsolidified molten steel is let to flow in the width-wise direction of said slab in a position at least 2 m upstream of said reducing position,

said step of rolling including the steps of;

heating said slab in the range from 900°

C. to 1200°

C.;

rolling said heated slab into said steel plate so that the cumulative rolling reduction in an austenite no-recrystallization temperature range is in the range from 50% to 90%; and

cooling said steel plate at a cooling rate in the range from 10°

C./sec to 45°

C./sec from a temperature of at least A_r3-50°

C.

Pcm=C+Si/30+(Mn+Cu+Cr)/20+Ni/60+Mo/15+V/10+5B 

 

(1)

 

where the element symbols represent the % by mass of the respective elements.

8. The method of manufacturing a high-tensile steel plate according to claim 7, further comprising the step of tempering said steel plate after the cooling at a temperature less than point A_c1.

9. A method of producing a slab for a high-tensile steel plate using a continuous casting device, comprising the steps of:

injecting molten steel into a cooled cast and forming a slab having a solidified shell on the surface and unsolidified molten steel inside, said molten steel comprising 0.02% to 0.1% C, at most 0.6% Si, 1.6% to 2.5% Mn, 0.1% to 0.7% Ni, 0.01% to 0.1% Nb, 0.005% to 0.03% Ti, at most 0.1% sol. Al, 0.001% to 0.006% N, 0% to 0.0025% B, 0% to 0.6% Cu, 0% to 0.8% Cr, 0% to 0.6% Mo, 0% to 0.1% V, 0% to 0.006% Ca, 0% to 0.006% Mg, 0% to 0.03% a rare earth element, at most 0.015% P, and at most 0.003% S, the balance consisting of Fe and impurities, the carbon equivalent Pcm in Expression (1) being from 0.180% to 0.220%;

drawing said slab downwardly from said cast;

reducing said slab by at least 30 mm in the thickness-wise direction in a position upstream of the final solidifying position of said slab where the center solid phase ratio of said slab is more than 0 and less than 0.2; and

carrying out electromagnetic stirring to said slab so that said unsolidified molten steel is let to flow in the width-wise direction of said slab in a position at least 2 m upstream of said reducing position,

Pcm=C+Si/30+(Mn+Cu+Cr)/20+Ni/60+Mo/15+V/10+5B 

 

(1)

 

where the element symbols represent the % by mass of the respective elements.